Improving the Dielectric Properties of Polymers by Incorporating Nano-particles.

The paper presents a brief review of the promise of nanotechnology applied to polymeric insulation materials and discusses the electrical properties found. For a variety of nanocomposites, the dielectric behaviour has shown that the interface between the embedded particles and host matrix holds the key to the understanding of the bulk phenomena being observed. Dielectric spectroscopy verified the motion of carriers through the interaction zones that surround the particles. The obvious improvements in endurance and breakdown strength of nanocomposites may be due to a reduction of charge accumulation. PEA space charge tests confirm this charge dissipation. By examining the onset field of space charge accumulation, it may be possible to determine whether a system is likely to be useful

The Influence of Water on Dielectric Behavior of Silica-filled Epoxy Nano-composites and Percolation Phenomenon

The dielectric properties of epoxy resin were studied as a function of hydration by dielectric spectroscopy. The dielectric spectroscopy measurements show different conduction and quasi-DC behaviors at very low frequencies (<10-2 Hz) with activation energies dependent on the hydration. These observations lead to the development of a model in which a “water shell” is formed around the nano-particles. The multiple shell model, originally proposed by Lewis and developed by Tanaka, has been further developed to explain low frequency dielectric spectroscopy results in which percolation of charge carriers through overlapping water shells was shown to occur. At 100% relative humidity, water is believed to surround the nanoparticles to a depth of approximately 10 monolayers as the first layer. A second layer of water is proposed that is dispersed by sufficiently concentrated to be conductive. If all the water had existed in a single layer surrounding a nanoparticle, this layer would have been approximately 5 nm thick at 100% RH. Filler particles that have surfaces that are functionalized to be hydrophobic considerably reduce the amount of water absorbed in nanocomposites under the same conditions of humidity. PEA results show that the wetted epoxy specimens have a higher threshold field of space charge accumulation than such dry specimens since water enhances charge decay

Mechanism for current saturation and energy dissipation in graphene transistors

From a combination of careful and detailed theoretical and experimental studies, we demonstrate that the Boltzmann theory including all scattering mechanisms gives an excellent account, with no adjustable parameters, of high electric field transport in single as well as double-oxide graphene transistors. We further show unambiguously that scattering from the substrate and superstrate surface optical (SO) phonons governs the high field transport and heat dissipation over a wide range of experimentally relevant parameters. Models that neglect SO phonons altogether or treat them in a simple phenomenological manner are inadequate. We outline possible strategies for achieving higher current and complete saturation in graphene devices.Comment: revtex, 5 pages, 3 figures, to appear in Phys. Rev. Lett

Influence of absorbed water on the dielectric properties and glass-transition temperature of silica-filled epoxy nanocomposites

Work on dielectric spectroscopy of epoxy resin filled with nano-SiO2 at different relative humidities and temperatures is reported. Above the glass-transition temperature (Tg), dc-like imperfect charge transport (QDC or LFD) dominates the low frequency dielectric spectrum. Another mid-frequency relaxation process was found in the non-dried composites. Water also induces glass-transition temperature decreases, which can be measured both by dielectric spectroscopy and DSC. Both theory and experiment demonstrated that a higher water content could exist in nanocomposites than unfilled epoxy suggesting a bigger free volume when nanostructured. In our system, the hydrophilic surface of silica is likely to cause water to surround and lead to delamination of the epoxy from SiO2. This is a potential mechanical and dielectric weakness in the nanocomposites, which may lead to an ageing phenomenon. Hydrophobic surface group may reduce the water adsorption in nanocomposites

Myelin figures: the buckling and flow of wet soap

Myelin figures are interfacial structures formed when certain surfactants swell in excess water. Here, I present data and model calculations suggesting myelin formation and growth is due to the fluid flow of surfactant, driven by the hydration gradient at the dry surfactant/water interface; a simple model based on this idea qualitatively reproduces the various myelin growth behaviors observed in different experiments. From a detailed experimental observation of how myelins develop from a planar precursor structure, I identify a mechanical instability that may underlie myelin formation. These results indicate the mixed mechanical character of the surfactant lamellar structure, where fluid and elastic properties coexist, is what enables the formation and growth of myelins.Comment: 11 pages, 10 figures, to appear in Phys. Rev. E. Corrected figures/typo

Poisson noise induced switching in driven micromechanical resonators

We study Poisson-noise induced switching between coexisting vibrational states in driven nonlinear micromechanical resonators. In contrast to Gaussian noise induced switching, the measured logarithm of the switching rate is proportional not to the reciprocal noise intensity, but to its logarithm, for fixed pulse area. We also find that the switching rate logarithm varies as a square root of the distance to the bifurcation point, instead of the conventional scaling with exponent 3/2.Comment: accepted by PR

Directive emission of red conjugated polymer embedded within zero index metamaterials

Abstract: We numerically demonstrate an impedance-matched multilayer stacked fishnet metamaterial that has zero index with flat high transmittance from 600nm to 620nm. The effective refractive index

Role of the N∗N^*(1535) in the J/ψ→pˉηpJ/\psi\to \bar{p}\eta p and J/ψ→pˉK+ΛJ/\psi\to \bar{p}K^+\Lambda reactions

We study the $J/\psi\to \bar{p}\eta p$ and $J/\psi\to \bar{p}K^+\Lambda$ reactions with a unitary chiral approach. We find that the unitary chiral approach, which generates the $N^*(1535)$ dynamically, can describe the data reasonably well, particularly the ratio of the integrated cross sections. This study provides further support for the unitary chiral description of the $N^*(1535)$. We also discuss some subtle differences between the coupling constants determined from the unitary chiral approach and those determined from phenomenological studies.Comment: version to appear in PRC; certain features of the approach clarifie

Environmental Sensing by Wearable Device for Indoor Activity and Location Estimation

We present results from a set of experiments in this pilot study to investigate the causal influence of user activity on various environmental parameters monitored by occupant carried multi-purpose sensors. Hypotheses with respect to each type of measurements are verified, including temperature, humidity, and light level collected during eight typical activities: sitting in lab / cubicle, indoor walking / running, resting after physical activity, climbing stairs, taking elevators, and outdoor walking. Our main contribution is the development of features for activity and location recognition based on environmental measurements, which exploit location- and activity-specific characteristics and capture the trends resulted from the underlying physiological process. The features are statistically shown to have good separability and are also information-rich. Fusing environmental sensing together with acceleration is shown to achieve classification accuracy as high as 99.13%. For building applications, this study motivates a sensor fusion paradigm for learning individualized activity, location, and environmental preferences for energy management and user comfort.Comment: submitted to the 40th Annual Conference of the IEEE Industrial Electronics Society (IECON