34,066 research outputs found
Improving the Dielectric Properties of Polymers by Incorporating Nano-particles.
The paper presents a brief review of the promise of nanotechnology applied to polymeric insulation materials and discusses the electrical properties found. For a variety of nanocomposites, the dielectric behaviour has shown that the interface between the embedded particles and host matrix holds the key to the understanding of the bulk phenomena being observed. Dielectric spectroscopy verified the motion of carriers through the interaction zones that surround the particles. The obvious improvements in endurance and breakdown strength of nanocomposites may be due to a reduction of charge accumulation. PEA space charge tests confirm this charge dissipation. By examining the onset field of space charge accumulation, it may be possible to determine whether a system is likely to be useful
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The Influence of Water on Dielectric Behavior of Silica-filled Epoxy Nano-composites and Percolation Phenomenon
The dielectric properties of epoxy resin were studied as a function of hydration by dielectric spectroscopy. The dielectric spectroscopy measurements show different conduction and quasi-DC behaviors at very low frequencies (<10-2 Hz) with activation energies dependent on the hydration. These observations lead to the development of a model in which a “water shell” is formed around the nano-particles. The multiple shell model, originally proposed by Lewis and developed by Tanaka, has been further developed to explain low frequency dielectric spectroscopy results in which percolation of charge carriers through overlapping water shells was shown to occur. At 100% relative humidity, water is believed to surround the nanoparticles to a depth of approximately 10 monolayers as the first layer. A second layer of water is proposed that is dispersed by sufficiently concentrated to be conductive. If all the water had existed in a single layer surrounding a nanoparticle, this layer would have been approximately 5 nm thick at 100% RH. Filler particles that have surfaces that are functionalized to be hydrophobic considerably reduce the amount of water absorbed in nanocomposites under the same conditions of humidity. PEA results show that the wetted epoxy specimens have a higher threshold field of space charge accumulation than such dry specimens since water enhances charge decay
Mechanism for current saturation and energy dissipation in graphene transistors
From a combination of careful and detailed theoretical and experimental
studies, we demonstrate that the Boltzmann theory including all scattering
mechanisms gives an excellent account, with no adjustable parameters, of high
electric field transport in single as well as double-oxide graphene
transistors. We further show unambiguously that scattering from the substrate
and superstrate surface optical (SO) phonons governs the high field transport
and heat dissipation over a wide range of experimentally relevant parameters.
Models that neglect SO phonons altogether or treat them in a simple
phenomenological manner are inadequate. We outline possible strategies for
achieving higher current and complete saturation in graphene devices.Comment: revtex, 5 pages, 3 figures, to appear in Phys. Rev. Lett
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Influence of absorbed water on the dielectric properties and glass-transition temperature of silica-filled epoxy nanocomposites
Work on dielectric spectroscopy of epoxy resin filled with nano-SiO2 at different relative humidities and temperatures is reported. Above the glass-transition temperature (Tg), dc-like imperfect charge transport (QDC or LFD) dominates the low frequency dielectric spectrum. Another mid-frequency relaxation process was found in the non-dried composites. Water also induces glass-transition temperature decreases, which can be measured both by dielectric spectroscopy and DSC. Both theory and experiment demonstrated that a higher water content could exist in nanocomposites than unfilled epoxy suggesting a bigger free volume when nanostructured. In our system, the hydrophilic surface of silica is likely to cause water to surround and lead to delamination of the epoxy from SiO2. This is a potential mechanical and dielectric weakness in the nanocomposites, which may lead to an ageing phenomenon. Hydrophobic surface group may reduce the water adsorption in nanocomposites
Myelin figures: the buckling and flow of wet soap
Myelin figures are interfacial structures formed when certain surfactants
swell in excess water. Here, I present data and model calculations suggesting
myelin formation and growth is due to the fluid flow of surfactant, driven by
the hydration gradient at the dry surfactant/water interface; a simple model
based on this idea qualitatively reproduces the various myelin growth behaviors
observed in different experiments. From a detailed experimental observation of
how myelins develop from a planar precursor structure, I identify a mechanical
instability that may underlie myelin formation. These results indicate the
mixed mechanical character of the surfactant lamellar structure, where fluid
and elastic properties coexist, is what enables the formation and growth of
myelins.Comment: 11 pages, 10 figures, to appear in Phys. Rev. E. Corrected
figures/typo
Poisson noise induced switching in driven micromechanical resonators
We study Poisson-noise induced switching between coexisting vibrational
states in driven nonlinear micromechanical resonators. In contrast to Gaussian
noise induced switching, the measured logarithm of the switching rate is
proportional not to the reciprocal noise intensity, but to its logarithm, for
fixed pulse area. We also find that the switching rate logarithm varies as a
square root of the distance to the bifurcation point, instead of the
conventional scaling with exponent 3/2.Comment: accepted by PR
Directive emission of red conjugated polymer embedded within zero index metamaterials
Abstract: We numerically demonstrate an impedance-matched multilayer stacked fishnet metamaterial that has zero index with flat high transmittance from 600nm to 620nm. The effective refractive index
Role of the (1535) in the and reactions
We study the and
reactions with a unitary chiral approach. We find that the unitary chiral
approach, which generates the dynamically, can describe the data
reasonably well, particularly the ratio of the integrated cross sections. This
study provides further support for the unitary chiral description of the
. We also discuss some subtle differences between the coupling
constants determined from the unitary chiral approach and those determined from
phenomenological studies.Comment: version to appear in PRC; certain features of the approach clarifie
Environmental Sensing by Wearable Device for Indoor Activity and Location Estimation
We present results from a set of experiments in this pilot study to
investigate the causal influence of user activity on various environmental
parameters monitored by occupant carried multi-purpose sensors. Hypotheses with
respect to each type of measurements are verified, including temperature,
humidity, and light level collected during eight typical activities: sitting in
lab / cubicle, indoor walking / running, resting after physical activity,
climbing stairs, taking elevators, and outdoor walking. Our main contribution
is the development of features for activity and location recognition based on
environmental measurements, which exploit location- and activity-specific
characteristics and capture the trends resulted from the underlying
physiological process. The features are statistically shown to have good
separability and are also information-rich. Fusing environmental sensing
together with acceleration is shown to achieve classification accuracy as high
as 99.13%. For building applications, this study motivates a sensor fusion
paradigm for learning individualized activity, location, and environmental
preferences for energy management and user comfort.Comment: submitted to the 40th Annual Conference of the IEEE Industrial
Electronics Society (IECON
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