106 research outputs found
Fibrolipoma gigante de la mejilla: a propósito de un caso
El fibrolipoma es una neoplasia de origen mesenquimal, rara en la cavidad oral, representando el 1% de todos los tumores benignos orales. Es una variante histológica del lipoma simple, que normalmente se manifiesta a nivel de la mucosa oral, suelo de la boca, lengua y labios. La etiologÃa suele ser traumática cuando afecta localizaciones extraorales, mientras se considera idiopática al manifestarse a nivel bucal. En este artÃculo se presenta un raro caso de fibrolipoma de mejilla, y se discuten los aspectos diagnósticos, histo-patológicos y de tratamiento de acuerdo a la literatura. Lipomas are common soft tissue mesenchymal neoplasms, rare in the oral cavity, representing 1% of all benign oral tumors. Fibrolipoma is a histological variant of the classic lipoma which normally affects buccal mucosa, floor of the mouth, tongue and lips. In this article is presented a rare case of fibrolipoma of the cheek and are discussed all the aspects of diagnosis, histology and surgical treatment, according to literature data
Tectonic evolution of the Neoproterozoic Tandilia sedimentary cover, Argentina: New evidence of contraction and extensional events in the southwest Gondwana margin
At the northwestern portion of the Tandilia System, a detailed structural analysis on the Precambrian sedimentary units exposed in the quarries of the OlavarrÃa-Sierras Bayas area was carried out. These units exhibit deformational structures of several scales, from centimeters to hundreds of meters. The hundreds of meters scale involves E-W- and NW-SE-trending normal faults and NW-SE- and NE-SW-trending contractional folds. The centimeters to meters scale involves veins, joints, normal faults, shear fractures and stylolites, with a prevailing ∼ E-W to NW-SE trend. All these structures were formed by two major tectonic events. The first was the folding event at ∼580 Ma, with NNE-SSW to NE-SW and NW-SE direction of contraction. The second was the extensional faulting event, given by the widespread NNE-SSW-directed extension event during the Atlantic Ocean opening (Jurassic-Cretaceous). Both major events would have been controlled by the reactivation of basement anisotropies. These major tectonic events controlled the deformation of the Precambrian sedimentary cover of the Tandilia system, leading to an economically important aspect in the mining development of the OlavarrÃa-Sierras Bayas area.Facultad de Ciencias Naturales y MuseoCentro de Investigaciones Geológica
Reversible spin storage in metal oxide—fullerene heterojunctions
We show that hybrid MnOx/C60 heterojunctions can be used to design a storage device for spin-polarized charge: a spin capacitor. Hybridization at the carbon-metal oxide interface leads to spin-polarized charge trapping after an applied voltage or photocurrent. Strong electronic structure changes, including a 1-eV energy shift and spin polarization in the C60 lowest unoccupied molecular orbital, are then revealed by x-ray absorption spectroscopy, in agreement with density functional theory simulations. Muon spin spectroscopy measurements give further independent evidence of local spin ordering and magnetic moments optically/electronically stored at the heterojunctions. These spin-polarized states dissipate when shorting the electrodes. The spin storage decay time is controlled by magnetic ordering at the interface, leading to coherence times of seconds to hours even at room temperature
Clinical management and microscopic characterisation of fatique-induced failure of a dental implant. Case report
BACKGROUND: Osseointegrated endosseous implants are widely used for the rehabilitation of completely and partially edentulous patients, being the final prosthodontic treatment more predictable and the failures extremely infrequent. A case of fracture of an endosseous dental implant, replacing the maxillary first molar, occurring in a middle-age woman, 5 years after placement is reported. MATERIALS AND METHODS: The difficult management of this rare complication of implant dentistry together with the following rehabilitation is described. Additionally, the authors performed an accurate analysis of the removed fractured implant both by the stereomicroscope and by the confocal laser scanning microscope. RESULTS AND DISCUSSION: The fractured impant showed the typical signs of a fatigue-induced fracture in the coronal portion of the implant together with numerous micro-fractures in the apical one. Three dimensional imaging performed by confocal laser scanning microscope led easily to a diagnosis of "fatigue fracture" of the implant. The biomechanical mechanism of implant fractures when overstress of the implant components due to bending overload is discussed. CONCLUSION: When a fatigue-induced fracture of an dental implant occurs in presence of bending overload, the whole implant suffers a deformation that is confirmed by the alterations (micro-fractures) of the implant observable also in the osseointegrated portion that is easily appraisable by the use of stereomicroscope and confocal laser scanning microscope without preparation of the sample
Understanding resonant charge transport through weakly coupled single-molecule junctions
Off-resonant charge transport through molecular junctions has been
extensively studied since the advent of single-molecule electronics and it is
now well understood within the framework of the non-interacting Landauer
approach. Conversely, gaining a qualitative and quantitative understanding of
the resonant transport regime has proven more elusive. Here, we study resonant
charge transport through graphene-based zinc-porphyrin junctions. We
experimentally demonstrate an inadequacy of the non-interacting Landauer theory
as well as the conventional single-mode Franck-Condon model. Instead, we model
the overall charge transport as a sequence of non-adiabatic electron transfers,
the rates of which depend on both outer and inner-sphere vibrational
interactions. We show that the transport properties of our molecular junctions
are determined by a combination of electron-electron and electron-vibrational
coupling, and are sensitive to the interactions with the wider local
environment. Furthermore, we assess the importance of nuclear tunnelling and
examine the suitability of semi-classical Marcus theory as a description of
charge transport in molecular devices.Comment: version accepted in Nature Communications; SI available at
https://researchportal.hw.ac.uk/en/publications/understanding-resonant-charge-transport-through-weakly-coupled-s
Understanding resonant charge transport through weakly coupled single-molecule junctions
Off-resonant charge transport through molecular junctions has been
extensively studied since the advent of single-molecule electronics and it is
now well understood within the framework of the non-interacting Landauer
approach. Conversely, gaining a qualitative and quantitative understanding of
the resonant transport regime has proven more elusive. Here, we study resonant
charge transport through graphene-based zinc-porphyrin junctions. We
experimentally demonstrate an inadequacy of the non-interacting Landauer theory
as well as the conventional single-mode Franck-Condon model. Instead, we model
the overall charge transport as a sequence of non-adiabatic electron transfers,
the rates of which depend on both outer and inner-sphere vibrational
interactions. We show that the transport properties of our molecular junctions
are determined by a combination of electron-electron and electron-vibrational
coupling, and are sensitive to the interactions with the wider local
environment. Furthermore, we assess the importance of nuclear tunnelling and
examine the suitability of semi-classical Marcus theory as a description of
charge transport in molecular devices.Comment: version accepted in Nature Communications; SI available at
https://researchportal.hw.ac.uk/en/publications/understanding-resonant-charge-transport-through-weakly-coupled-s
Frontier molecular orbitals of a single molecule adsorbed on thin insulating films supported by a metal substrate: electron and hole attachment energies
Lateral ridge augmentation using an equine flex bone block infused with recombinant human platelet-derived growth factor BB: A clinical and histologic study
This paper reports on a patient who underwent horizontal ridge augmentation using recombinant human platelet-derived growth factor BB (rhPDGF-BB) in combination with a collagenate equine block. Ninety days after the first surgery, 8 mm of new bone was noted on a computed tomography scan, and three 5-mm implants were placed. Histology, performed using confocal laser scanning microscopy, showed a large amount of newly formed bone well characterized with osteon and resorption lacunae, which demonstrated the intense bone remodeling. This study supports the use of rhPDGF-BB in combination with allograft blocks. © 2011 by Quintessence Publishing Co Inc
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