Precision constraints on radiative neutrino decay with CMB spectral distortion

We investigate the radiative decay of the cosmic neutrino background, and its impact on the spectrum of the cosmic microwave background (CMB) that is known to be a nearly perfect black body. We derive exact formulae for the decay of a heavier neutrino into a lighter neutrino and a photon, $\nu_j \to \nu_i + \gamma$, and of absorption as its inverse, $\nu_i + \gamma \to \nu_j$, by accounting for the precise form of the neutrino momentum distribution. Our calculations show that if the neutrinos are heavier than $\mathcal O(0.1)$ eV, the exact formulae give results that differ by $\sim$50%, compared with approximate ones where neutrinos are assumed to be at rest. We also find that spectral distortion due to absorption is more important for heavy neutrino masses (by a factor of $\sim$10 going from a neutrino mass of 0.01 eV to 0.1 eV). By analyzing the CMB spectral data measured with COBE-FIRAS, we obtain lower limits on the neutrino lifetime of $\tau_{12} \gtrsim 4 \times 10^{21}$ s (95% C.L.) for the smaller mass splitting and $\tau_{13} \sim \tau_{23} \gtrsim 10^{19}$ s for the larger mass splitting. These represent up to one order of magnitude improvement over previous CMB constraints. With future CMB experiments such as PIXIE, these limits will improve by roughly 4 orders of magnitude. This translates to a projected upper limit on the neutrino magnetic moment (for certain neutrino masses and decay modes) of $\mu_\nu < 3 \times 10^{-11}\, \mu_B$, where $\mu_B$ is the Bohr magneton. Such constraints would make future precision CMB measurements competitive with lab-based constraints on neutrino magnetic moments.Comment: 14 pages, 9 figures. v2: Added a number of references and clarifications. Matches version published in PR

Quantification of carbon monoxide emissions from African cities using TROPOMI

Carbon monoxide (CO) is an air pollutant that plays an important role in atmospheric chemistry and is mostly emitted by forest fires and incomplete combustion in, for example, road transport, residential heating, and industry. As CO is co-emitted with fossil fuel CO2 combustion emissions, it can be used as a proxy for CO2. Following the Paris Agreement, there is a need for independent verification of reported activity-based bottom-up CO2 emissions through atmospheric measurements. CO can be observed daily at a global scale with the TROPOspheric Monitoring Instrument (TROPOMI) satellite instrument with daily global coverage at a resolution down to 5.5 × 7 km2. To take advantage of this unique TROPOMI dataset, we develop a cross-sectional flux-based emission quantification method that can be applied to quantify emissions from a large number of cities, without relying on computationally expensive inversions. We focus on Africa as a region with quickly growing cities and large uncertainties in current emission estimates. We use a full year of high-resolution Weather Research and Forecasting (WRF) simulations over three cities to evaluate and optimize the performance of our cross-sectional flux emission quantification method and show its reliability down to emission rates of 0.1 Tg CO yr−1. Comparison of the TROPOMI-based emission estimates to the Dynamics–Aerosol–Chemistry–Cloud Interactions in West Africa (DACCIWA) and Emissions Database for Global Atmospheric Research (EDGAR) bottom-up inventories shows that CO emission rates in northern Africa are underestimated in EDGAR, suggesting overestimated combustion efficiencies. We see the opposite when comparing TROPOMI to the DACCIWA inventory in South Africa and Côte d'Ivoire, where CO emission factors appear to be overestimated. Over Lagos and Kano (Nigeria) we find that potential errors in the spatial disaggregation of national emissions cause errors in DACCIWA and EDGAR respectively. Finally, we show that our computationally efficient quantification method combined with the daily TROPOMI observations can identify a weekend effect in the road-transport-dominated CO emissions from Cairo and Algiers.</p

Bistability of Mitochondrial Respiration Underlies Paradoxical Reactive Oxygen Species Generation Induced by Anoxia

Increased production of reactive oxygen species (ROS) in mitochondria underlies major systemic diseases, and this clinical problem stimulates a great scientific interest in the mechanism of ROS generation. However, the mechanism of hypoxia-induced change in ROS production is not fully understood. To mathematically analyze this mechanism in details, taking into consideration all the possible redox states formed in the process of electron transport, even for respiratory complex III, a system of hundreds of differential equations must be constructed. Aimed to facilitate such tasks, we developed a new methodology of modeling, which resides in the automated construction of large sets of differential equations. The detailed modeling of electron transport in mitochondria allowed for the identification of two steady state modes of operation (bistability) of respiratory complex III at the same microenvironmental conditions. Various perturbations could induce the transition of respiratory chain from one steady state to another. While normally complex III is in a low ROS producing mode, temporal anoxia could switch it to a high ROS producing state, which persists after the return to normal oxygen supply. This prediction, which we qualitatively validated experimentally, explains the mechanism of anoxia-induced cell damage. Recognition of bistability of complex III operation may enable novel therapeutic strategies for oxidative stress and our method of modeling could be widely used in systems biology studies

Low-Temperature Atmospheric Pressure Plasma Processes for “Green” Third Generation Photovoltaics

Special Issue: Plasma Processing of Materials for Energy Conversion and Storage.International audienceAtmospheric pressure plasmas (APPs) have achieved great scientific and technological advances for a wide range of applications. The synthesis and treatment of materials by APPs have always attracted great attention due to potential economic benefits if compared to low-pressure plasma processes. Nonetheless, APPs present very distinctive features that suggest atmospheric pressure operation could bring other benefits for emerging new technologies. In particular, materials synthesized by APPs which are suitable candidates for third generation photovoltaics are reviewed here