Slow crack growth in polycarbonate films

We study experimentally the slow growth of a single crack in polycarbonate films submitted to uniaxial and constant imposed stress. The specificity of fracture in polycarbonate films is the appearance of flame shaped macroscopic process zones at the tips of the crack. Supported by an experimental study of the mechanical properties of polycarbonate films, an analysis of the stress dependence of the mean ratio between the process zone and crack lengths, during the crack growth, show a quantitative agreement with the Dugdale-Barenblatt model of the plastic process zone. We find that the fracture growth curves obey strong scaling properties that lead to a well defined growth master curve

Fracture Surfaces as Multiscaling Graphs

Fracture paths in quasi-two-dimenisonal (2D) media (e.g thin layers of materials, paper) are analyzed as self-affine graphs $h(x)$ of height $h$ as a function of length $x$. We show that these are multiscaling, in the sense that $n^{th}$ order moments of the height fluctuations across any distance $\ell$ scale with a characteristic exponent that depends nonlinearly on the order of the moment. Having demonstrated this, one rules out a widely held conjecture that fracture in 2D belongs to the universality class of directed polymers in random media. In fact, 2D fracture does not belong to any of the known kinetic roughening models. The presence of multiscaling offers a stringent test for any theoretical model; we show that a recently introduced model of quasi-static fracture passes this test.Comment: 4 pages, 5 figure

Discrepancy between sub-critical and fast rupture roughness: a cumulant analysis

We study the roughness of a crack interface in a sheet of paper. We distinguish between slow (sub-critical) and fast crack growth regimes. We show that the fracture roughness is different in the two regimes using a new method based on a multifractal formalism recently developed in the turbulence literature. Deviations from monofractality also appear to be different in both regimes

Discriminating between competing models for the allosteric regulation of oncogenic phosphatase SHP2 by characterizing its active state

The Src-homology 2 domain containing phosphatase 2 (SHP2) plays a critical role in crucial signaling pathways and is involved in oncogenesis and in developmental disorders. Its structure includes two SH2 domains (N-SH2 and C-SH2), and a protein tyrosine phosphatase (PTP) domain. Under basal conditions, SHP2 is auto-inhibited, with the N-SH2 domain blocking the PTP active site. Activation involves a rearrangement of the domains that makes the catalytic site accessible, coupled to the association between the SH2 domains and cognate proteins containing phosphotyrosines. Several aspects of this transition are debated and competing mechanistic models have been proposed. A crystallographic structure of SHP2 in an active state has been reported (PDB code 6crf), but several lines of evidence suggests that it is not fully representative of the conformations populated in solution. To clarify the structural rearrangements involved in SHP2 activation, enhanced sampling simulations of the autoinhibited and active states have been performed, for wild type SHP2 and its pathogenic E76K variant. Our results demonstrate that the crystallographic conformation of the active state is unstable in solution, and multiple interdomain arrangements are populated, thus allowing association to bisphosphorylated sequences. Contrary to a recent proposal, activation is coupled to the conformational changes of the N-SH2 binding site, which is significantly more accessible in the active sate, rather than to the structure of the central β-sheet of the domain. In this coupling, a previously undescribed role for the N-SH2 BG loop emerged

Field emission from single multi-wall carbon nanotubes

Electron field emission characteristics of individual multiwalled carbon nanotubes have been investigated by a piezoelectric nanomanipulation system operating inside a scanning electron microscopy chamber. The experimental setup ensures a high control capability on the geometric parameters of the field emission system (CNT length, diameter and anode-cathode distance). For several multiwalled carbon nanotubes, reproducible and quite stable emission current behaviour has been obtained with a dependence on the applied voltage well described by a series resistance modified Fowler-Nordheim model. A turn-on field of about 30 V/um and a field enhancement factor of around 100 at a cathode-anode distance of the order of 1 um have been evaluated. Finally, the effect of selective electron beam irradiation on the nanotube field emission capabilities has been extensively investigated.Comment: 16 pages, 5 figure

Roughness and multiscaling of planar crack fronts

We consider numerically the roughness of a planar crack front within the long-range elastic string model, with a tunable disorder correlation length $\xi$. The problem is shown to have two important length scales, $\xi$ and the Larkin length $L_c$. Multiscaling of the crack front is observed for scales below $\xi$, provided that the disorder is strong enough. The asymptotic scaling with a roughness exponent $\zeta \approx 0.39$ is recovered for scales larger than both $\xi$ and $L_c$. If $L_c > \xi$, these regimes are separated by a third regime characterized by the Larkin exponent $\zeta_L \approx 0.5$. We discuss the experimental implications of our results.Comment: 8 pages, two figure

Sound and light from fractures in scintillators

Prompted by intriguing events observed in certain particle-physics searches for rare events, we study light and acoustic emission simultaneously in some inorganic scintillators subject to mechanical stress. We observe mechanoluminescence in ${Bi}_4{Ge}_{3}{O}_{12}$, ${CdWO}_{4}$ and ${ZnWO}_{4}$, in various mechanical configurations at room temperature and ambient pressure. We analyze how the light emission is correlated to acoustic emission during fracture. For ${Bi}_4{Ge}_{3}{O}_{12}$, we set a lower bound on the energy of the emitted light, and deduce that the fraction of elastic energy converted to light is at least $3 \times 10^{-5}$

Subcritical crack growth in fibrous materials

We present experiments on the slow growth of a single crack in a fax paper sheet submitted to a constant force $F$. We find that statistically averaged crack growth curves can be described by only two parameters : the mean rupture time $\tau$ and a characteristic growth length $\zeta$. We propose a model based on a thermally activated rupture process that takes into account the microstructure of cellulose fibers. The model is able to reproduce the shape of the growth curve, the dependence of $\zeta$ on $F$ as well as the effect of temperature on the rupture time $\tau$. We find that the length scale at which rupture occurs in this model is consistently close to the diameter of cellulose microfibrils

Intrawell stochastic resonance versus interwell stochastic resonance in underdamped bistable systems

We show that, for periodically driven noisy underdamped bistable systems, an intrawell stochastic resonance can exist, together with the conventional interwell stochastic resonance, resulting in a double maximum in the power spectral amplitude at the forcing frequency as a function of the noise intensity. The locations of the maxima correspond to matchings of deterministic and stochastic time scales in the system. In this paper we present experimental evidence of these phenomena and a phemonological nonadiabatic description in terms of a noise-controlled nonlinear dynamic resonance