Why We Demolish: Assessing Heritage Loss in Philadelphia as a Catalyst for Policy Innovation in Historic Preservation

Demolition of listed historic resources through policy provisions such as economic hardship and public interest has, in recent years, led to increased controversy and tension in the preservation community. As approvals to demolish such heritage anchors as the Sidney Hillman Medical Center, the Church of the Assumption, the Levy-Leas Mansion, the Episcopal Cathedral\u27s Parish House, and the Boyd Theater interior continue to place the Philadelphia Historical Commission and developers at odds with preservation advocates, it is important to review the policy documents at the core of the issue. This thesis proposes that it is not the Commission but the policies that are complicating the Commission\u27s ability to best protect heritage assets. By examining how and why historically designated properties are demolished in Philadelphia (through a review of policy precedents and local case studies), this work proposes policy recommendations to stimulate innovation in preservation and reduce prolonged demolition cases in the future

Surrogate measures: A proposed alternative in human factors assessment of operational measures of performance

Surrogate measures are proposed as an alternative to direct assessment of operational performance for purposes of screening agents who may have to work under unusual stresses or in exotic environments. Such measures are particularly proposed when the surrogate can be empirically validated against the operational criterion. The focus is on cognitive (or throughput) performances in humans as opposed to sensory (input) or motor (output) measures, but the methods should be applicable for development of batteries which will tap input/output functions. A menu of performance tasks is under development for implementation on a battery-operated portable microcomputer, with 21 tests currently available. The tasks are reliable and become stable in minimum amounts of time; appear sensitive to some agents; comprise constructs related to actual job tasks; and are easily administered in most environments. Implications for human factors engineering studies in environmental stress are discussed

Fragmentation Phase Transition in Atomic Clusters II - Coulomb Explosion of Metal Clusters -

We discuss the role and the treatment of polarization effects in many-body systems of charged conducting clusters and apply this to the statistical fragmentation of Na-clusters. We see a first order microcanonical phase transition in the fragmentation of $Na^{Z+}_{70}$ for Z=0 to 8. We can distinguish two fragmentation phases, namely evaporation of large particles from a large residue and a complete decay into small fragments only. Charging the cluster shifts the transition to lower excitation energies and forces the transition to disappear for charges higher than Z=8. At very high charges the fragmentation phase transition no longer occurs because the cluster Coulomb-explodes into small fragments even at excitation energy $\epsilon^* = 0$.Comment: 19 text pages +18 *.eps figures, my e-mail adress: [email protected] submitted to Z. Phys.

The Local Leo Cold Cloud and New Limits on a Local Hot Bubble

We present a multi-wavelength study of the local Leo cold cloud (LLCC), a very nearby, very cold cloud in the interstellar medium. Through stellar absorption studies we find that the LLCC is between 11.3 pc and 24.3 pc away, making it the closest known cold neutral medium cloud and well within the boundaries of the local cavity. Observations of the cloud in the 21-cm HI line reveal that the LLCC is very cold, with temperatures ranging from 15 K to 30 K, and is best fit with a model composed of two colliding components. The cloud has associated 100 micron thermal dust emission, pointing to a somewhat low dust-to-gas ratio of 48 x 10^-22 MJy sr^-1 cm^2. We find that the LLCC is too far away to be generated by the collision among the nearby complex of local interstellar clouds, but that the small relative velocities indicate that the LLCC is somehow related to these clouds. We use the LLCC to conduct a shadowing experiment in 1/4 keV X-rays, allowing us to differentiate between different possible origins for the observed soft X-ray background. We find that a local hot bubble model alone cannot account for the low-latitude soft X-ray background, but that isotropic emission from solar wind charge exchange does reproduce our data. In a combined local hot bubble and solar wind charge exchange scenario, we rule out emission from a local hot bubble with an 1/4 keV emissivity greater than 1.1 Snowdens / pc at 3 sigma, 4 times lower than previous estimates. This result dramatically changes our perspective on our local interstellar medium.Comment: 13 pages, 12 figures. Accepted for publication in the Astrophysical Journal. Vector figure version available at http://www.astro.columbia.edu/~jpeek

Crackling Noise, Power Spectra and Disorder Induced Critical Scaling

Crackling noise is observed in many disordered non-equilibrium systems in response to slowly changing external conditions. Examples range from Barkhausen noise in magnets to acoustic emission in martensites to earthquakes. Using the non-equilibrium random field Ising model, we derive universal scaling predictions for the dependence of the associated power spectra on the disorder and field sweep rate, near an underlying disorder-induced non-equilibrium critical point. Our theory applies to certain systems in which the crackling noise results from avalanche-like response to a (slowly) increasing external driving force, and is characterized by a broad power law scaling regime of the power spectra. We compute the critical exponents and discuss the relevance of the results to experiments.Comment: 27 Latex Pages, 14 eps figure

Coupling of Liquid and Surface Chemistry in Urea SCR Systems

Close-coupled selective catalytic reduction (SCR) systems are one method to deal with tightening emission legislation for NO$_x$ in internal combustion engines. Due to smaller mixing sections and at unfavourable boundary conditions, however, urea-water solution (UWS) droplets can impact on the SCR catalyst itself. To investigate this phenomenon further, this work develops a modeling capability of this process. Established mechanism for NH$_3$-SCR and HNCO hydrolysis from literature is integrated into DETCHEM$^{CHANNEL}$ and a 2D COMSOL model to simulate the influence in the SCR Channel. Simulations are validated against end-of-pipe experiments from literature and spatially resolved concentration profiles from a hot gas test rig with very good agreement. Finally, a channel simulation is coupled with a model to describe the catalytic decomposition of an urea droplet. The coupled simulation is able to simulate the influence of UWS droplet impact onto a catalyst channel. Fast droplet decomposition causes a peak in NH$_3$ and HNCO in the single channel and thus increases NO$_x$ conversion. However, the overall uniformity and efficiency are decreased, which is why droplet impact on the catalyst should be strictly avoided