Effects of Cold Deformation and Electron Irradiations on Deuterium Desorption Temperature Range from Zr – 1 %Nb Alloy

The explored warm-up ranges of desorption ion-implanted deuterium from Zr – 1 %Nb alloy, with different structure: after crystallization from melt, plastic deformation and irradiations electron. Cool deformation under 300 K Zr – 1 %Nb alloy with degree 3.9 has allowed to reach the nanostructure conditions in alloy with average size crystallite d 61 nm, high three-dimensional concentration of the borders (~ 3,4 %) and significant level microstrain that in spectrum of thermodesorption ion-implanted deuterium was shown as additional low temperature area thermodesorption deuterium within the range of the temperature 770-1000 K. Irradiation electron to energy 10 MeV by fluence ~ 6 × 1017 cm – 2 has brought about active development of the revocable processes in nanostructure alloy: reduction of the average grain size d 58 nm, increase to concentrations of the borders (~ 8,8 %) and appearance additional peaks in spectrum of thermodesorption deuterium with the temperature 700 and 800 K and, accordingly, increase the warmup range desorption deuterium toward reduction of the temperature. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3512

Effects of Concentration Titanium on Threshold Character of Deuterium Desorption Temperature Range from Mg-based Composites

The plasma evaporation-sputtering method was applied to make composite materials of the Mg-Ti system. The ion-implanted deuterium desorption temperature variations as a function of the component concentration were studied. It has been established that, by introducing titanium into magnesium, the deuterium desorption temperature can be appreciably decreased (to 400-450 K) in comparison with the case of deuterium desorption from magnesium ( 800 K). A step-like shape of the curve of deuterium desorption temperature evidences on the presence of two different structure states of the Mg-Ti system depending on the ratio of components. The deuterium temperature decrease can be caused by filamentary inclusions of insoluble component (titanium) atoms formed in the process of composite making and annealing, providing the deuterium diffusion from the sample at a lower temperature (channels for deuterium diffusion through the surface barrier). The deuterium desorption data obtained on the example of Mg-Ti, Mg-V and Mg-Zr composites provide support for further research into hydrogen storage materials containing low-soluble chemical elements in the alloy component. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3550

Hierarchies of Spin Models related to Calogero-Moser Models

The universal formulation of spin exchange models related to Calogero-Moser models implies the existence of integrable hierarchies, which have not been explored. We show the general structures and features of the spin exchange model hierarchies by taking as examples the well-known Heisenberg spin chain with the nearest neighbour interactions. The energy spectra of the second member of the hierarchy belonging to the models based on the $A_r$ root systems $(r=3,4,5)$ are explicitly and {\em exactly} evaluated. They show many many interesting features and in particular, much higher degree of degeneracy than the original Heisenberg model, as expected from the integrability.Comment: 12pages, LaTeX2e, packages used: pstricks, pst-node, pstcol, if these are not available, an eps file will be sent upon reques

Національна доповідь про стан і перспективи розвитку освіти в Україні: монографія (До 30-річчя незалежності України)

The publication provides a comprehensive analysis of the state and development of national education over the 30 years of Ukraine’s independence, identifies current problems in education, ascertains the causes of their emergence, offers scientifically reasoned ways to modernise domestic education in the context of globalisation, European integration, innovative development, and national self-identification. Designed for legislators, state officials, education institutions leaders, teaching and academic staff, the general public, all those who seek to increase the competitiveness of Ukrainian education in the context of civilisation changes.У виданні здійснено всебічний аналіз стану і розвитку національної освіти за 30-річний період незалежності України, визначено актуальні проблеми освітньої сфери, виявлено причини їх виникнення, запропоновано науково обґрунтовані шляхи модернізації вітчизняної освіти в умовах глобалізації, європейської інтеграції, інноваційного розвитку та національної самоідентифікації. Розраховано на законодавців, державних управлінців, керівників закладів освіти, педагогічних і науково-педагогічних працівників, широку громадськість, усіх, хто прагне підвищення конкурентоспроможності української освіти в контексті цивілізаційних змін

Non-isothermal physical and chemical processes in superfluid helium

Metal atoms and small clusters introduced into superfluid helium (He II) concentrate there in quantized vortices to form (by further coagulation) the thin nanowires. The nanowires’ thickness and structure are well predicted by a double-staged mechanism. On the first stage the coagulation of cold particles in the vortex cores leads to melting of their fusion product, which acquires a spherical shape due to surface tension. Then (second stage) provided these particles reach a certain size they do not possess sufficient energy to melt and eventually coalesce into the nano-wires. Nevertheless the assumption of melting for such refractory metal as tungsten, especially in He II, which possesses an extremely high thermal conductivity, induces natural skepticism. That is why we decided to register directly the visible thermal emission accompanying metals coagulation in He II. The brightness temperatures of this radiation for the tungsten, molybdenum, and platinum coagulation were found to be noticeably higher than even the metals’ melting temperatures. The region of He II that contained suspended metal particles expanded with the velocity of 50 m/s, being close to the Landau velocity, but coagulation took place even more quickly, so that the whole process of nanowire growth is completed at distances about 1.5 mm from the place of metal injection into He II. High rate of coagulation of guest metal particles as well as huge local overheating are associated with them concentrating in quantized vortex cores. The same process should take place not only for metals but for any atoms, molecules and small clusters embedded into He II

Non-isothermal physical and chemical processes in superfluid helium

Metal atoms and small clusters introduced into superfluid helium (He II) concentrate there in quantized vortices to form (by further coagulation) the thin nanowires. The nanowires’ thickness and structure are well predicted by a double-staged mechanism. On the first stage the coagulation of cold particles in the vortex cores leads to melting of their fusion product, which acquires a spherical shape due to surface tension. Then (second stage) provided these particles reach a certain size they do not possess sufficient energy to melt and eventually coalesce into the nano-wires. Nevertheless the assumption of melting for such refractory metal as tungsten, especially in He II, which possesses an extremely high thermal conductivity, induces natural skepticism. That is why we decided to register directly the visible thermal emission accompanying metals coagulation in He II. The brightness temperatures of this radiation for the tungsten, molybdenum, and platinum coagulation were found to be noticeably higher than even the metals’ melting temperatures. The region of He II that contained suspended metal particles expanded with the velocity of 50 m/s, being close to the Landau velocity, but coagulation took place even more quickly, so that the whole process of nanowire growth is completed at distances about 1.5 mm from the place of metal injection into He II. High rate of coagulation of guest metal particles as well as huge local overheating are associated with them concentrating in quantized vortex cores. The same process should take place not only for metals but for any atoms, molecules and small clusters embedded into He II