52 research outputs found
Energy gap tuning in graphene on hexagonal boron nitride bilayer system
We use a tight binding approach and density functional theory calculations to
study the band structure of graphene/hexagonal boron nitride bilayer system in
the most stable configuration. We show that an electric field applied in the
direction perpendicular to the layers significantly modifies the electronic
structure of the whole system, including shifts, anticrossing and other
deformations of bands, which can allow to control the value of the energy gap.
It is shown that band structure of biased system may be tailored for specific
requirements of nanoelectronics applications. The carriers' mobilities are
expected to be higher than in the bilayer graphene devices.Comment: 10 pages, 7 figures, submitted to Physical Review
Low-temperature phosphorescence of dicyanoacetylene in rare gas solids
A strong visible ã³Σu⁺ – X̃¹Σg⁺
luminescence was observed upon the UV excitation of cryogenic rare gas (argon,
krypton, and xenon) matrices doped with dicyanoacetylene (NC₄N). Spectra and lifetimes of this phosphorescence
have been measured. A detailed analysis of resolved vibronic bands is presented
Formation of atomic tritium clusters and condensates
We present an extensive study of the static and dynamic properties of systems
of spin-polarized tritium atoms. In particular, we calculate the two-body
|F,m_F>=|0,0> s-wave scattering length and show that it can be manipulated via
a Feshbach resonance at a field strength of about 870G. Such a resonance might
be exploited to make and control a Bose-Einstein condensate of tritium in the
|0,0> state. It is further shown that the quartet tritium trimer is the only
bound hydrogen isotope and that its single vibrational bound state is a
Borromean state. The ground state properties of larger spin-polarized tritium
clusters are also presented and compared with those of helium clusters.Comment: 5 pages, 3 figure
Centre-of-mass separation in quantum mechanics: Implications for the many-body treatment in quantum chemistry and solid state physics
We address the question to what extent the centre-of-mass (COM) separation
can change our view of the many-body problem in quantum chemistry and solid
state physics. It was shown that the many-body treatment based on the
electron-vibrational Hamiltonian is fundamentally inconsistent with the
Born-Handy ansatz so that such a treatment can never respect the COM problem.
Born-Oppenheimer (B-O) approximation reveals some secret: it is a limit case
where the degrees of freedom can be treated in a classical way. Beyond the B-O
approximation they are inseparable in principle. The unique covariant
description of all equations with respect to individual degrees of freedom
leads to new types of interaction: besides the known vibronic (electron-phonon)
one the rotonic (electron-roton) and translonic (electron-translon)
interactions arise. We have proved that due to the COM problem only the
hypervibrations (hyperphonons, i.e. phonons + rotons + translons) have true
physical meaning in molecules and crystals; nevertheless, the use of pure
vibrations (phonons) is justified only in the adiabatic systems. This fact
calls for the total revision of our contemporary knowledge of all non-adiabatic
effects, especially the Jahn-Teller effect and superconductivity. The vibronic
coupling is responsible only for removing of electron (quasi)degeneracies but
for the explanation of symmetry breaking and forming of structure the rotonic
and translonic coupling is necessary.Comment: 39 pages, 11 sections, 3 appendice
Strong absorption by interstellar hydrogen fluoride: Herschel/HIFI observations of the sight-line to G10.6-0.4 (W31C)
We report the detection of strong absorption by interstellar hydrogen
fluoride along the sight-line to the submillimeter continuum source G10.6-0.4
(W31C). We have used Herschel's HIFI instrument, in dual beam switch mode, to
observe the 1232.4763 GHz J=1-0 HF transition in the upper sideband of the Band
5a receiver. The resultant spectrum shows weak HF emission from G10.6-0.4 at
LSR velocities in the range -10 to -3 km/s, accompanied by strong absorption by
foreground material at LSR velocities in the range 15 to 50 km/s. The spectrum
is similar to that of the 1113.3430 GHz 1(11)-0(00) transition of para-water,
although at some frequencies the HF (hydrogen fluoride) optical depth clearly
exceeds that of para-H2O. The optically-thick HF absorption that we have
observed places a conservative lower limit of 1.6E+14 cm-2 on the HF column
density along the sight-line to G10.6-0.4. Our lower limit on the HF abundance,
6E-9 relative to hydrogen nuclei, implies that hydrogen fluoride accounts for
between ~ 30 and 100% of the fluorine nuclei in the gas phase along this
sight-line. This observation corroborates theoretical predictions that -
because the unique thermochemistry of fluorine permits the exothermic reaction
of F atoms with molecular hydrogen - HF will be the dominant reservoir of
interstellar fluorine under a wide range of conditions.Comment: Accepted for publication in Astronomy and Astrophysics (Herschel
special issue). This revised version corrects a typographic error in the HTML
abstract, in which the lower limit on the HF abundance (should be 6E-9) was
previously misstated. The abstract in the PDF version is correct and the
latter has not been modifie
Detection of hydrogen fluoride absorption in diffuse molecular clouds with Herschel/HIFI: a ubiquitous tracer of molecular gas
We discuss the detection of absorption by interstellar hydrogen fluoride (HF)
along the sight line to the submillimeter continuum sources W49N and W51. We
have used Herschel's HIFI instrument in dual beam switch mode to observe the
1232.4762 GHz J = 1 - 0 HF transition in the upper sideband of the band 5a
receiver. We detected foreground absorption by HF toward both sources over a
wide range of velocities. Optically thin absorption components were detected on
both sight lines, allowing us to measure - as opposed to obtain a lower limit
on - the column density of HF for the first time. As in previous observations
of HF toward the source G10.6-0.4, the derived HF column density is typically
comparable to that of water vapor, even though the elemental abundance of
oxygen is greater than that of fluorine by four orders of magnitude. We used
the rather uncertain N(CH)-N(H2) relationship derived previously toward diffuse
molecular clouds to infer the molecular hydrogen column density in the clouds
exhibiting HF absorption. Within the uncertainties, we find that the abundance
of HF with respect to H2 is consistent with the theoretical prediction that HF
is the main reservoir of gas-phase fluorine for these clouds. Thus, hydrogen
fluoride has the potential to become an excellent tracer of molecular hydrogen,
and provides a sensitive probe of clouds of small H2 column density. Indeed,
the observations of hydrogen fluoride reported here reveal the presence of a
low column density diffuse molecular cloud along the W51 sight line, at an LSR
velocity of ~ 24kms-1, that had not been identified in molecular absorption
line studies prior to the launch of Herschel.Comment: 4 pages, 3 figures, A&A Letter special issue, accepted on 07/13/201
Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction
We report the detection of absorption by interstellar hydroxyl cations and
water cations, along the sight-line to the bright continuum source W49N. We
have used Herschel's HIFI instrument, in dual beam switch mode, to observe the
972 GHz N = 1 - 0 transition of OH+ and the 1115 GHz 1(11) - 0(00) transition
of ortho-H2O+. The resultant spectra show absorption by ortho-H2O+, and strong
absorption by OH+, in foreground material at velocities in the range 0 to 70
km/s with respect to the local standard of rest. The inferred OH+/H2O+
abundance ratio ranges from ~ 3 to ~ 15, implying that the observed OH+ arises
in clouds of small molecular fraction, in the 2 - 8% range. This conclusion is
confirmed by the distribution of OH+ and H2O+ in Doppler velocity space, which
is similar to that of atomic hydrogen, as observed by means of 21 cm absorption
measurements, and dissimilar from that typical of other molecular tracers. The
observed OH+/H abundance ratio of a few E-8 suggests a cosmic ray ionization
rate for atomic hydrogen of (0.6 - 2.4) E-16 s-1, in good agreement with
estimates inferred previously for diffuse clouds in the Galactic disk from
observations of interstellar H3+ and other species.Comment: Accepted for publication in A&A Letter
Excitation and Abundance of C3 in star forming cores:Herschel/HIFI observations of the sight-lines to W31C and W49N
We present spectrally resolved observations of triatomic carbon (C3) in
several ro-vibrational transitions between the vibrational ground state and the
low-energy nu2 bending mode at frequencies between 1654-1897 GHz along the
sight-lines to the submillimeter continuum sources W31C and W49N, using
Herschel's HIFI instrument. We detect C3 in absorption arising from the warm
envelope surrounding the hot core, as indicated by the velocity peak position
and shape of the line profile. The sensitivity does not allow to detect C3
absorption due to diffuse foreground clouds. From the column densities of the
rotational levels in the vibrational ground state probed by the absorption we
derive a rotation temperature (T_rot) of ~50--70 K, which is a good measure of
the kinetic temperature of the absorbing gas, as radiative transitions within
the vibrational ground state are forbidden. It is also in good agreement with
the dust temperatures for W31C and W49N. Applying the partition function
correction based on the derived T_rot, we get column densities N(C3)
~7-9x10^{14} cm^{-2} and abundance x(C3)~10^{-8} with respect to H2. For W31C,
using a radiative transfer model including far-infrared pumping by the dust
continuum and a temperature gradient within the source along the line of sight
we find that a model with x(C3)=10^{-8}, T_kin=30-50 K, N(C3)=1.5 10^{15}
cm^{-2} fits the observations reasonably well and provides parameters in very
good agreement with the simple excitation analysis.Comment: Accepted for publication in Astronomy and Astrophysics (HIFI first
results issue
Nitrogen hydrides in interstellar gas: Herschel/HIFI observations towards G10.6-0.4 (W31C)
The HIFI instrument on board the Herschel Space Observatory has been used to
observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4
in order to improve our understanding of the interstellar chemistry of
nitrogen. We report observations of absorption in NH N=1-0, J=2-1 and ortho-NH2
1_1,1-0_0,0. We also observed ortho-NH3 1_0-0_0, and 2_0-1_0, para-NH3 2_1-1_1,
and searched unsuccessfully for NH+. All detections show emission and
absorption associated directly with the hot-core source itself as well as
absorption by foreground material over a wide range of velocities. All spectra
show similar, non-saturated, absorption features, which we attribute to diffuse
molecular gas. Total column densities over the velocity range 11-54 km/s are
estimated. The similar profiles suggest fairly uniform abundances relative to
hydrogen, approximately 6*10^-9, 3*10^-9, and 3*10^-9 for NH, NH2, and NH3,
respectively. These abundances are discussed with reference to models of
gas-phase and surface chemistry.Comment: 5 pages, 3 figures, 2 online pages with 2 figures. Accepted for
publication in A&A July 6 (Herschel/HIFI special issue
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