Carbon and hydrogen isotopic characterization of methane from wetlands and lakes of the Yukon-Kuskokwim Delta, western Alaska

The total methane flux to the troposphere from tundra environments of the Yukon-Kuskokwim Delta is dominated by emissions from wet meadow tundra (~75%) and small, organic-rich lakes (~20%). The mean δ13C value of methane diffusing into collar-mounted flux chambers from wet meadow environments near Bethel, Alaska, was -65.82±2.21‰ (±1 sigma, n=18) for the period July 10 to August 10, 1988. A minimum ebullition estimated for the 5% of total Delta area comprised of small lakes ranges from 0.34 to 9.7 × 1010g Ch4yr-1, which represents 0.6% to 17% of the total Delta methane emission. The δ13C and δD values of this ebullitive flux are -61.41±2.46‰ (n=38) and -341.8±18.2‰ (n=21), respectively. The methane in gas bubbles from two lakes is of modern, bomb carbon enriched, radiocarbon age. Gas bubble δ13C values varied from 2 to 5‰ seasonally, reaching heaviest values in midsummer; no such variations in δD values were observed

Radon 222 tracing of soil and forest canopy trace gas exchange in an open canopy boreal forest

A set of continuous, high-resolution atmospheric radon (222Rn) concentration time series and radon soil flux measurements were acquired during the summer of 1990 at a micrometeorological tower site 13 km northwest of Schefferville, Quebec, Canada. The tower was located in a dry upland, open-canopy lichen-spruce woodland. For the period July 23 to August 1, 1990, the mean radon soil flux was 41.1 ± 4.8 Bq m-2 h-1. Radon surface flux from the two end-member forest floor cover types (lichen mat and bare soil) were 38.8 ± 5.1 and 61.8 ± 15.6 Bq m-2 h-1, respectively. Average total forest canopy resistances computed using a simple "flux box" model for radon exchange between the forest canopy and the overlying atmosphere range from 0.47 ± 0.24 s cm-1 to 2.65 ± 1.61 s cm-1 for daytime hours (0900-1700 LT) and from 3.44 ± 0.91 s cm-1 to 10.55 ± 7.16 s cm-1 for nighttime hours (2000-0600) for the period July 23 to August 6, 1990. Continuous radon profiling of canopy atmospheres is a suitable approach for determining rates of biosphere/atmosphere trace gas exchange for remote field sites where daily equipment maintenance is not possible

INFLUENCE OF STEEL ALLOY COMPOSITION ON THE PROCESS ROBUSTNESS OF AS-BUILT HARDNESS IN LASER-DIRECTED ENERGY DEPOSITION

To ensure consistent quality of additively manufactured parts, it is advantageous to identify alloys which can meet performance criteria while being robust to process variations. Toward such an end, this work studied the effect of steel alloy composition on the process robustness of as-built hardness in laser-directed energy deposition (L-DED). In-situ blending of ultra-high-strength lowalloy steel (UHSLA) and pure iron powders produced 10 alloys containing 10-100% UHSLA by mass. Thin-wall samples were deposited, and the hardness sensitivity of each alloy was evaluated with respect to laser power and interlayer delay time. The sensitivity peaked at 40-50% UHSLA, corresponding to phase fluctuations between lath martensite and upper bainite depending on the cooling rate. Lower (10-20%) or higher (70-100%) alloy contents transformed primarily to ferrite or martensite, respectively, with auto-tempering of martensite at lower cooling rates. By avoiding martensite/bainite fluctuations, the robustness was improved.Mechanical Engineerin

Polarons with a twist

We consider a polaron model where molecular \emph{rotations} are important. Here, the usual hopping between neighboring sites is affected directly by the electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This model may be of relevance for electronic transport in complex molecules and polymers with torsional degrees of freedom, such as DNA, as well as in molecular electronics experiments where molecular twist motion is significant. We use a tight-binding representation and find that very different polaronic properties are already exhibited by a two-site model -- these are due to the nonlinearity of the restoring force of the twist excitations, and of the electron-phonon interaction in the model. In the adiabatic regime, where electrons move in a {\em low}-frequency field of twisting-phonons, the effective splitting of the energy levels increases with coupling strength. The bandwidth in a long chain shows a power-law suppression with coupling, unlike the typical exponential dependence due to linear phonons.Comment: revtex4 source and one eps figur

Rochechouart 2017-Drilling Campaign: First Results

No abstract available

Ultrasound attenuation in gap-anisotropic systems

Transverse ultrasound attenuation provides a weakly-coupled probe of momentum current correlations in electronic systems. We develop a simple theory for the interpretation of transverse ultrasound attenuation coefficients in systems with nodal gap anisotropy. Applying this theory we show how ultrasound can delineate between extended-s and d-wave scenarios for the cuprate superconductors.Comment: Uuencode file: 4 pages (Revtex), 3 figures. Some references adde

The Intentional Use of Service Recovery Strategies to Influence Consumer Emotion, Cognition and Behaviour

Service recovery strategies have been identified as a critical factor in the success of. service organizations. This study develops a conceptual frame work to investigate how specific service recovery strategies influence the emotional, cognitive and negative behavioural responses of . consumers., as well as how emotion and cognition influence negative behavior. Understanding the impact of specific service recovery strategies will allow service providers' to more deliberately and intentionally engage in strategies that result in positive organizational outcomes. This study was conducted using a 2 x 2 between-subjects quasi-experimental design. The results suggest that service recovery has a significant impact on emotion, cognition and negative behavior. Similarly, satisfaction, negative emotion and positive emotion all influence negative behavior but distributive justice has no effect

Nonlinear Integer Programming

Research efforts of the past fifty years have led to a development of linear integer programming as a mature discipline of mathematical optimization. Such a level of maturity has not been reached when one considers nonlinear systems subject to integrality requirements for the variables. This chapter is dedicated to this topic. The primary goal is a study of a simple version of general nonlinear integer problems, where all constraints are still linear. Our focus is on the computational complexity of the problem, which varies significantly with the type of nonlinear objective function in combination with the underlying combinatorial structure. Numerous boundary cases of complexity emerge, which sometimes surprisingly lead even to polynomial time algorithms. We also cover recent successful approaches for more general classes of problems. Though no positive theoretical efficiency results are available, nor are they likely to ever be available, these seem to be the currently most successful and interesting approaches for solving practical problems. It is our belief that the study of algorithms motivated by theoretical considerations and those motivated by our desire to solve practical instances should and do inform one another. So it is with this viewpoint that we present the subject, and it is in this direction that we hope to spark further research.Comment: 57 pages. To appear in: M. J\"unger, T. Liebling, D. Naddef, G. Nemhauser, W. Pulleyblank, G. Reinelt, G. Rinaldi, and L. Wolsey (eds.), 50 Years of Integer Programming 1958--2008: The Early Years and State-of-the-Art Surveys, Springer-Verlag, 2009, ISBN 354068274

The <i>Castalia</i> mission to Main Belt Comet 133P/Elst-Pizarro

We describe Castalia, a proposed mission to rendezvous with a Main Belt Comet (MBC), 133P/Elst-Pizarro. MBCs are a recently discovered population of apparently icy bodies within the main asteroid belt between Mars and Jupiter, which may represent the remnants of the population which supplied the early Earth with water. Castalia will perform the first exploration of this population by characterising 133P in detail, solving the puzzle of the MBC’s activity, and making the first in situ measurements of water in the asteroid belt. In many ways a successor to ESA’s highly successful Rosetta mission, Castalia will allow direct comparison between very different classes of comet, including measuring critical isotope ratios, plasma and dust properties. It will also feature the first radar system to visit a minor body, mapping the ice in the interior. Castalia was proposed, in slightly different versions, to the ESA M4 and M5 calls within the Cosmic Vision programme. We describe the science motivation for the mission, the measurements required to achieve the scientific goals, and the proposed instrument payload and spacecraft to achieve these

A Kinematically Complete Measurement of the Proton Structure Function F2 in the Resonance Region and Evaluation of Its Moments

We measured the inclusive electron-proton cross section in the nucleon resonance region (W < 2.5 GeV) at momentum transfers Q**2 below 4.5 (GeV/c)**2 with the CLAS detector. The large acceptance of CLAS allowed for the first time the measurement of the cross section in a large, contiguous two-dimensional range of Q**2 and x, making it possible to perform an integration of the data at fixed Q**2 over the whole significant x-interval. From these data we extracted the structure function F2 and, by including other world data, we studied the Q**2 evolution of its moments, Mn(Q**2), in order to estimate higher twist contributions. The small statistical and systematic uncertainties of the CLAS data allow a precise extraction of the higher twists and demand significant improvements in theoretical predictions for a meaningful comparison with new experimental results.Comment: revtex4 18 pp., 12 figure