1,359 research outputs found
Use of prismatic films to control light distribution
Piping light for illumination purposes is a concept which has been around for a long time. In fact, it was the subject of an 1881 United States patent which proposed the use of mirrors inside a tube to reflect light from wall to wall down the tube. The use of conventional mirrors for this purpose, however, has not worked because mirrors do not reflect well enough. On the other hand, optical fibers composed of certain glasses or plastics are known to transport light much more efficiently. The light that enters is reflected back and forth within the walls of the fiber until it reaches the other end. This is possible by means of a principle known as 'total internal reflection'. No light escapes through the walls and very little is absorbed in the bulk of the fiber. However, while optical fibers are very efficient in transporting light, they are impractical for transporting large quantities of light. Lorne Whitehead, as a student at the University of British Columbia, recognized that prismatic materials could be used to create a 'prism light guide', a hollow structure that can efficiently transport large quantities of light. This invention is a pipe whose transparent walls are formed on the outside into precise prismatic facets. The facets are efficient total internal reflection mirrors which prevent light travelling down the guide from escaping. Very little light is absorbed by the pipe because light travels primarily in the air space within the hollow guide. And, because the guide is hollow, weight and cost factors are much more favorable than would be the case with very large solid fibers. Recent advances in precision micromachining, polymer processing, and certain other manufacturing technologies have made the development of OLF (Optical Lighting Film) possible. The process is referred to as 'microreplication' and has been found to have broad applicability in a number of diverse product areas
Microscopic theory of surface-enhanced Raman scattering in noble-metal nanoparticles
We present a microscopic model for surface-enhanced Raman scattering (SERS)
from molecules adsorbed on small noble-metal nanoparticles. In the absence of
direct overlap of molecular orbitals and electronic states in the metal, the
main enhancement source is the strong electric field of the surface plasmon
resonance in a nanoparticle acting on a molecule near the surface. In small
particles, the electromagnetic enhancement is strongly modified by quantum-size
effects. We show that, in nanometer-sized particles, SERS magnitude is
determined by a competition between several quantum-size effects such as the
Landau damping of surface plasmon resonance and reduced screening near the
nanoparticle surface. Using time-dependent local density approximation, we
calculate spatial distribution of local fields near the surface and enhancement
factor for different nanoparticles sizes.Comment: 8 pages, 6 figures. Considerably extended final versio
pH Dependent surface enhanced Raman study of Phe + Ag Complex and DFT calculations for spectral analysis
Surface enhanced Raman spectra of Phenylalanine (Phe) in Ag colloidal
solution have been recorded for Phe solutions of different pH. Spectral
line-shape analyses of the enhanced modes, at 1005, 1380 and 1582 cm-1, between
pH 4.5 and 10.5, have been carried out. The variation of spectral line-width
with pH reveals two possible mechanisms in solution: (i) the fluctuation of pH
in microscopic volume in an overall uniform pH solution and/or (ii) the
motional narrowing caused by the intermolecular ionic interaction. We suggest
that different charge states of the reference molecule are responsible for the
observed bond softening with decrease in pH. The observed Raman shift and the
Raman activity of the vibrational modes with maximum enhancement have been
explained by carrying out DFT calculations.Comment: 17 pages, 5 figure
Vortex Strings and Four-Dimensional Gauge Dynamics
We study the low-energy quantum dynamics of vortex strings in the Higgs phase
of N=2 supersymmetric QCD. The exact BPS spectrum of the stretched string is
shown to coincide with the BPS spectrum of the four-dimensional parent gauge
theory. Perturbative string excitations correspond to bound W-bosons and quarks
while the monopoles appear as kinks on the vortex string. This provides a
physical explanation for an observation by N. Dorey relating the quantum
spectra of theories in two and four dimensions.Comment: 23 pages, 1 figure. v2: Two extra appendices included: one on the
brane construction, the other describing the potential on the vortex moduli
space. Two figures added. Typos corrected and references added. v3: BPS
nature of quarks correcte
Size Dependence of Electrical Conductivity and Thermoelectric Enhancements in Spin-Coated PEDOT:PSS Single and Multiple Layers
This work reveals that the electrical conductivity σ of a poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) film can be significantly increased by spin-coating multiple thin layers onto a substrate. Generally, σ can be improved by more than fourfold for multiple layers, as compared to a single thicker one. A gradual enhancement is observed for pristine PEDOT:PSS films (up to 2.10 ± 0.26 S cm–1 for five-layered films), while a plateau in σ at around 200 S cm–1 is reached after only three layers, when using a PEDOT:PSS solution with 5 vol% dimethyl sulfoxide. By contrast, only a small change in σ is observed for single layers of varying thickness. Accordingly, the thermoelectric power factor is also increased by up to 3.4 times for the multiple layers. Based on atomic force microscopy, X-ray photoelectron spectroscopy, UV–vis, and Raman spectroscopy measurements, two mechanisms are also proposed, involving an increase in percolation by inclusion of smaller grains within the existing ones, respectively, a reorganization of the PEDOT:PSS chains. These findings represent a direct strategy for enhancing the thermoelectric performance of conductive polymer films without additional reagents, while the mechanistic insights explain existing literature results
Graphene plasmonics: A platform for strong light-matter interaction
Graphene plasmons provide a suitable alternative to noble-metal plasmons
because they exhibit much larger confinement and relatively long propagation
distances, with the advantage of being highly tunable via electrostatic gating.
We report strong light- matter interaction assisted by graphene plasmons, and
in particular, we predict unprecedented high decay rates of quantum emitters in
the proximity of a carbon sheet, large vacuum Rabi splitting and Purcell
factors, and extinction cross sections exceeding the geometrical area in
graphene ribbons and nanometer-sized disks. Our results provide the basis for
the emerging and potentially far-reaching field of graphene plasmonics,
offering an ideal platform for cavity quantum electrodynamics and supporting
the possibility of single-molecule, single-plasmon devices.Comment: 39 pages, 15 figure
Light scattering from disordered overlayers of metallic nanoparticles
We develop a theory for light scattering from a disordered layer of metal
nanoparticles resting on a sample. Averaging over different disorder
realizations is done by a coherent potential approximation. The calculational
scheme takes into account effects of retardation, multipole excitations, and
interactions with the sample. We apply the theory to a system similar to the
one studied experimentally by Stuart and Hall [Phys. Rev. Lett. {\bf 80}, 5663
(1998)] who used a layered Si/SiO/Si sample. The calculated results agree
rather well with the experimental ones. In particular we find conspicuous
maxima in the scattering intensity at long wavelengths (much longer than those
corresponding to plasmon resonances in the particles). We show that these
maxima have their origin in interference phenomena in the layered sample.Comment: 19 pages, 12 figure
Optical detection of single non-absorbing molecules using the surface plasmon of a gold nanorod
Current optical detection schemes for single molecules require light
absorption, either to produce fluorescence or direct absorption signals. This
severely limits the range of molecules that can be detected, because most
molecules are purely refractive. Metal nanoparticles or dielectric resonators
detect non-absorbing molecules by a resonance shift in response to a local
perturbation of the refractive index, but neither has reached single-protein
sensitivity. The most sensitive plasmon sensors to date detect single molecules
only when the plasmon shift is amplified by a highly polarizable label or by a
localized precipitation reaction on the particle's surface. Without
amplification, the sensitivity only allows for the statistical detection of
single molecules. Here we demonstrate plasmonic detection of single molecules
in realtime, without the need for labeling or amplification. We monitor the
plasmon resonance of a single gold nanorod with a sensitive photothermal assay
and achieve a ~ 700-fold increase in sensitivity compared to state-of-the-art
plasmon sensors. We find that the sensitivity of the sensor is intrinsically
limited due to spectral diffusion of the SPR. We believe this is the first
optical technique that detects single molecules purely by their refractive
index, without any need for photon absorption by the molecule. The small size,
bio-compatibility and straightforward surface chemistry of gold nanorods may
open the way to the selective and local detection of purely refractive proteins
in live cells
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