Wetting of Nematic Liquid Crystals on Crenellated Substrates: A Frank–Oseen Approach

We revisit the wetting of nematic liquid crystals in contact with crenellated substrates, studied previously using the Landau–de Gennes formalism. However, due to computational limitations, the characteristic length scales of the substrate relief considered in that study limited to less than 100 nematic correlation lengths. The current work uses an extended Frank–Oseen formalism, which includes not only the free-energy contribution due to the elastic deformations but also the surface tension contributions and, if disclinations or other orientational field singularities are present, their core contributions. Within this framework, which was successfully applied to the anchoring transitions of a nematic liquid crystal in contact with structured substrates, we extended the study to much larger length scales including the macroscopic scale. In particular, we analyzed the interfacial states and the transitions between them at the nematic–isotropic coexistence

Distributed multivariate regression with unknown noise covariance in the presence of outliers: an MDL approach

We consider the problem of estimating the coefficients in a multivariable linear model by means of a wireless sensor network which may be affected by anomalous measurements. The noise covariance matrices at the different sensors are assumed unknown. Treating outlying samples, and their support, as additional nuisance parameters, the Maximum Likelihood estimate is investigated, with the number of outliers being estimated according to the Minimum Description Length principle. A distributed implementation based on iterative consensus techniques is then proposed, and it is shown effective for managing outliers in the data.Peer ReviewedPostprint (author's final draft

Time Series Heterogeneous Co-execution on CPU+GPU

Time series motif (similarities) and discords discovery is one of the most important and challenging problems nowadays for time series analytics. We use an algorithm called “scrimp” that excels in collecting the relevant information of time series by reducing the computational complexity of the searching. Starting from the sequential algorithm we develop parallel alternatives based on a variety of scheduling policies that target different computing devices in a system that integrates a CPU multicore and an embedded GPU. These policies are named Dynamic -using Intel TBB- and Static -using C++11 threads- when targeting the CPU, and they are compared to a heterogeneous adaptive approach named LogFit -using Intel TBB and OpenCL- when targeting the co-execution on the CPU and GPU.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Preparation of Decoherence Free Cluster States with Optical Superlattices

We present a protocol to prepare decoherence free cluster states using ultracold atoms loaded in a two dimensional superlattice. The superlattice geometry leads to an array of 2*2 plaquettes, each of them holding four spin-1/2 particles that can be used for encoding a single logical qubit in the two-fold singlet subspace, insensitive to uniform magnetic field fluctuations in any direction. Dynamical manipulation of the supperlattice yields distinct inter and intra plaquette interactions and permits to realize one qubit and two qubit gates with high fidelity, leading to the generation of universal cluster states for measurement based quantum computation. Our proposal based on inter and intra plaquette interactions also opens the path to study polymerized Hamiltonians which support ground states describing arbitrary quantum circuits.Comment: 17 pages, 12 figure

Fuzzy logic in the design of public policies: application of law

This paper presents a methodological proposal in the field of uncertainty management, FuzzyLogic, to support efficient and effective decision-making in the field of Legal Sciences. We aim to contribute to provide more elements to a better guidance in law application. We apply the methodology to assign a sanction in years of imprisonment to a given felony; in this case to parricide. This work aims to foster the design of new public policies to qualify the sentences of felonies in all areas of justice in order to establish databases of felonies characterizations to provide the judge a greater number of elements to make more deficient and effective decisions

Modified electrodes prepared with polyphenolic film containing ruthenium complex and metal ligand anchored by azo covalent bond

This work presents two new modified carbon electrodes which were prepared via the polymerization of a phenolic moiety previously functionalized with azo groups (bipyridine and 2-methoxypyridine) as key structures to anchor the desired ligands. The syntheses of BAP (4-([2,2’]-bipyridinyl-4-ylazo)-phenol) and PAPmethoxy (5-(4-hidroxyphenylazo) pyridin-2-methoxy) were simple to perform, gave good yields and the monomers were easily electropolymerized resulting in chemically and mechanically stable modified electrodes. The PAP-methoxy ME formed stable complexes with Cd, Cu and Pb in aqueous media at open circuit and produced well defined redox peaks, showing good potential for future analytical applications. The BAP monomer was used to produce a ruthenium complex (BAP-Ru) which was electropolymerized from +0.50 to +0.75V (vs. Ag/AgCl) to leave the ruthenium available to act as a catalyst. The BAP-Ru ME was able to oxidize a variety of organic substrates with good selectivity. The yields obtained were either similar to, or better than, those obtained by homogeneous catalysis using a similar ruthenium catalyst or when this type of catalyst is supported in a carbon paste electrode.Este trabalho apresenta dois novos eletrodos de grafite modificados que foram preparados via polimerização da função fenólica, previamente funcionalizada por grupos azo (bipiridina e 2-metoxipiridina), que atuam como estruturas chaves para a ancoragem de ligantes de interesse. As sínteses dos monômeros BAP (4-([2,2’]bipiridinil-4-ilazo)-fenol) e PAPmetóxi (5-(4-hidroxifenilazo)piridin-2-metóxi) foram simples, deram bons rendimentos e os monômeros foram facilmente eletropolimerizados, levando à formação de eletrodos modificados (EM) química e mecanicamente estáveis. Em solução aquosa e em circuito aberto, o EM PAP-metóxi formou complexos estáveis com Cd, Cu e Pb, produzindo picos redox bem definidos, demonstrando o grande potencial deste eletrodo para futuras aplicações analíticas. O monômero BAP foi utilizado para produzir um complexo de rutênio (BAP-Ru) que foi eletropolimerizado entre +0.50 e +0.75V (vs. Ag/AgCl), permitindo que o rutênio permanecesse disponível para atuar como catalisador. O EM BAP-Ru oxidou seletivamente uma variedade de substratos orgânicos dando produtos com rendimentos próximos ou melhores que aqueles obtidos por catálise homogênea com complexos de rutênio similares, ou quando este tipo de catalisador é impregnado em pasta de carbono.CNPqCoordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES

CONSOLE Project - Deliverable 6.1 - "Project website"

This document consists of Task 6.2 (Website, Hub and communication materials) in the framework of WP6 (Dissemination and outreach) and Deliverable 6.1 Project Website. The main aim will be to boost the impact of the project, through communicating the knowledge and results of the project. The project will target a wide range of audiences in order to link research, evidence-based policy and public awareness. Communication activities, such as workshops, social media accounts and websites have been discussed in this plan as well as identified actors and stakeholders in order to effectively promote innovation in delivery of agri-environmental climate public goods (AECPG) by EU agriculture and forestry. This is a living document and will be continuously updated according to CONSOLE’s progress

Internal preference mapping of milk–fruit beverages: Influence of color and appearance on its acceptability

The individual preferences of 100 consumers between 20 and 30 years old for the color of 16 milk–fruit juice beverages (MFJB) were investigated by preference mapping technique. Consumers were asked to evaluate, just by looking at the samples, how much they liked them (from “Extremely dislike” to “Extremely like”). The color of the samples was analyzed by two different instrumental techniques. Results obtained from the instrumental color measurement showed the wide diversity in hues of the beverages available in the market, and correlations between techniques proved that both of them were appropriate to analyze color. Results showed that participants preferred samples with orangish appearance instead of those with a whiter look. Anyway, punctuations given by the consumers suggest that generally, color of these products is not highly evaluated by consumers, as the best mean punctuation was 6.6.Consejería de Innovación Ciencia y Empresa, Junta de Andalucía P11-AGR-778

Activation of a spherical carbon for toluene adsorption at low concentration

This paper complements a previous one [1] about toluene adsorption on a commercial spherical activated carbon and on samples obtained from it by CO2 or steam activation. The present paper deals with the activation of a commercial spherical carbon (SC) having low porosity and high bed density (0.85 g/cm3) using the same procedure. Our results show that SC can be well activated with CO2 or steam. The increase in the burn-off percentage leads to an increase in the gravimetric adsorption capacity (more intensively for CO2) and a decrease in bed density (more intensively for CO2). However, for similar porosity developments similar bed densities are achieved for CO2 and steam. Especial attention is paid to differences between both activating agents, comparing samples having similar or different activation rates, showing that CO2 generates more narrow porosity and penetrates more inside the spherical particles than steam. Steam activates more from the outside to the interior of the spheres and hence produces larger spheres size reductions. With both activation agents and with a suitable combination of porosity development and bed density, quite high volumetric adsorption values of toluene (up to 236 g toluene/L) can be obtained even using a low toluene concentration (200 ppmv).Generalitat Valenciana (Prometeo/2009/047 and FEDER), MICINN and plan E (CTQ2012-3176) and MINECO (MAT-2012-32832)