Low temperature dielectric relaxation in ordinary perovskite ferroelectrics: enlightenment from high-energy x-ray diffraction

Ordinary ferroelectrics exhibit a second order phase transition that is characterized by a sharp peak in the dielectric permittivity at a frequency-independent temperature. Furthermore, these materials show a low temperature dielectric relaxation that appears to be a common behavior of perovskite systems. Tetragonal lead zirconate titanate is used here as a model system in order to explore the origin of such an anomaly, since there is no consensus about the physical phenomenon involved in it. Crystallographic and domain structure studies are performed from temperature dependent synchrotron x-ray diffraction measurement. Results indicate that the dielectric relaxation cannot be associated with crystallographic or domain configuration changes. The relaxation process is then parameterized by using the Vogel–Fulcher–Tammann phenomenological equation. Results allow us to hypothesize that the observed phenomenon is due to changes in the dynamic behavior of the ferroelectric domains related to the fluctuation of the local polarization.Postprint (author's final draft

Estrategias metodológicas para la enseñanza-aprendizaje de los estudiantes de Ingeniería durante la COVID-19

In this paper, an analysis is made of the teaching strategies and methodologies used by some higher education institutions in Colombia in order to continue with some engineering programs during lockdown, as a result of the COVID-19 pandemic. To carry out the study, a mixed methodological approach was adopted in two phases, in which the instrument used to collect the information was designed, implemented and analyzed. The results show that teachers and students have common views on various aspects including: the duration of synchronous sessions, the preferred use of digital whiteboards, the need for both specialized software and ongoing training, the importance of a careful development of didactic sequences as well as the optimization of work times. Based on the results obtained, engineering teachers could redirect the strategies used in developing their courses in order to continue holding them in times of emergency, according to their own context.En el presente artículo se realiza un análisis de las estrategias y metodologías de enseñanza utilizadas por algunas Instituciones de Educación Superior en Colombia, para continuar con el desarrollo de algunos programas de Ingeniería durante el aislamiento social, producto de la COVID-19. Para realizar el estudio se propone un diseño metodológico con enfoque mixto, estructurado en dos fases, donde se diseña, implementa y analiza el instrumento utilizado para la recolección de la información. Los resultados demuestran que hay correspondencia entre docentes y estudiantes, respecto a la duración de los encuentros síncronos, el uso de la pizarra digital, el manejo de software especializado, la capacitación continua, el desarrollo cuidadoso de secuencia didáctica y optimización de tiempos de trabajo. Con base en los resultados obtenidos, los docentes de Ingeniería podrían redireccionar las estrategias utilizadas en el desarrollo de sus cursos para continuar con ellos en tiempos de emergencia según su propio contexto

Fast jitter tolerance testing for high-speed serial links in post-silicon validation

Post-silicon electrical validation of high-speed input/output (HSIO) links is a critical process for product qualification schedules of high-performance computer platforms under current aggressive time-to-market (TTM) commitments. Improvements in signaling methods, circuits, and process technologies have allowed HSIO data rates to scale well beyond 10 Gb/s. Noise and EM effects can create multiple signal integrity problems, which are aggravated by continuously faster bus technologies. The goal of post-silicon validation for HSIO links is to ensure design robustness of both receiver (Rx) and transmitter (Tx) circuitry in real system environments. One of the most common ways to evaluate the performance of a HSIO link is to characterize the Rx jitter tolerance (JTOL) performance by measuring the bit error rate (BER) of the link under worst stressing conditions. However, JTOL testing is extremely time-consuming when executed at specification BER considering manufacturing process, voltage, and temperature (PVT) test coverage. In order to significantly accelerate this process, we propose a novel approach for JTOL testing based on an efficient direct search optimization methodology. Our approach exploits the fast execution of a modified golden section search with a high BER, while overcoming the lack of correlation between different BERs by performing a downward linear search at the actual target BER until no errors are found. Our proposed methodology is validated in a realistic industrial server post-silicon validation platform for three different computer HSIO links: SATA, USB3, and PCIe3.ITESO, A.C

Loss of Bone Mineral Density Associated with Age in Male Rats Fed on Sunflower Oil Is Avoided by Virgin Olive Oil Intake or Coenzyme Q Supplementation

The role of dietary fat unsaturation and the supplementation of coenzyme Q have been evaluated in relation to bone health. Male Wistar rats were maintained for 6 or 24 months on two diets varying in the fat source, namely virgin olive oil, rich in monounsaturated fatty acids, or sunflower oil, rich in n-6 polyunsaturated fatty acids. Both dietary fats were supplemented or not with coenzyme Q10 (CoQ10). Bone mineral density (BMD) was evaluated in the femur. Serum levels of osteocalcin, osteopontin, receptor activator of nuclear factor κB ligand (RANKL), osteoprotegerin (OPG), adrenocorticotropin (ACTH) and parathyroid hormone (PTH), as well as urinary F2-isoprostanes were measured. Aged animals fed on virgin olive oil showed higher BMD than those fed on sunflower oil. In addition, CoQ10 prevented the age-related decline in BMD in animals fed on sunflower oil. Urinary F2-isoprostanes analysis showed that sunflower oil led to the highest oxidative status in old animals, which was avoided by supplementation with CoQ10. In conclusion, lifelong feeding on virgin olive oil or the supplementation of sunflower oil on CoQ10 prevented, at least in part mediated by a low oxidative stress status, the age-related decrease in BMD found in sunflower oil fed animals.This work was supported by the Spanish Ministry of Education and Science (AGL2008-01057) and the Autonomous Government of Andalusia (AGR832)

PCIe Gen5 Physical Layer Equalization Tuning by Using K-means Clustering and Gaussian Process Regression Modeling in Industrial Post-silicon Validation

Peripheral component interconnect express (PCIe) is a high-performance interconnect architecture widely adopted in the computer industry. The continuously increasing bandwidth demand from new applications has led to the development of the PCIe Gen5, reaching data rates of 32 GT/s. To mitigate undesired channel effects due to such high-speed, the PCIe specification defines an equalization process at the transmitter (Tx) and the receiver (Rx). Current post-silicon validation practices consist of finding an optimal subset of Tx and Rx coefficients by measuring the eye diagrams across different channels. However, these experiments are very time consuming since they require massive lab measurements. In this paper, we use a K-means approach to cluster all available post-silicon data from different channels and feed those clusters to a Gaussian process regression (GPR)-based metamodel for each channel. We then perform a surrogate-based optimization to obtain the optimal tuning settings for the specific channels. Our methodology is validated by measurements of the functional eye diagram of an industrial computer platform.ITESO, A.C

In Search of Critically Endangered Species: The Current Situation of Two Tiny Salamander Species in the Neotropical Mountains of Mexico

Worldwide, one in every three species of amphibian is endangered, 39 species have gone extinct in the last 500 years and another 130 species are suspected to have gone extinct in recent decades. Of the amphibians, salamanders have the highest portion of their species in one of the risk categories, even higher than the frogs. To date there have been few studies that have used recent field data to examine the status of populations of endangered salamanders. In this study we evaluate the current situation of two tiny salamanders, Parvimolge townsendi and Thorius pennatulus, both of which are distributed at intermediate elevations in the mountains of the northern Neotropics and are considered to be critically endangered; the first has been proposed as possibly extinct. By carrying out exhaustive surveys in both historical and potentially suitable sites for these two species, we evaluated their abundance and the characteristics of their habitats, and we estimated their potential geographic distribution. We visited 22 sites, investing 672 person-hours of sampling effort in the surveys, and found 201 P. townsendi salamanders in 11 sites and only 13 T. pennatulus salamanders in 5 sites. Both species were preferentially found in cloud forest fragments that were well conserved or only moderately transformed, and some of the salamanders were found in shade coffee plantations. The potential distribution area of both species is markedly fragmented and we estimate that it has decreased by more than 48%. The results of this study highlight the importance of carrying out exhaustive, systematic field surveys to obtain accurate information about the current situation of critically endangered species, and help us better understand the crisis that amphibians are facing worldwide

Extrinsic response enhancement at the polymorphic phase boundary in piezoelectric materials

Polymorphic phase boundaries (PPBs) in piezoelectric materials have attracted significant interest in recent years, in particular because of the unique properties that can be found in their vicinity. However, to fully harness their potential as micro-nanoscale functional entities, it is essential to achieve reliable and precise control of their piezoelectric response, which is due to two contributions known as intrinsic and extrinsic. In this work we have used a (K,Na)NbO3-based lead-free piezoceramic as a model system to investigate the evolution of the extrinsic contribution around a PPB. X-ray diffraction measurements are performed over a wide range of temperatures in order to determine the structures and transitions. The relevance of the extrinsic contribution at the PPB region is evaluated by means of nonlinear dielectric response measurements. Though it is widely appreciated that certain intrinsic properties of ferroelectric materials increase as PPBs are approached, our results demonstrate that the extrinsic contribution also maximizes. An enhancement of the extrinsic contribution is therefore also responsible for improving the functional properties at the PPB region. Rayleigh’s law is used to quantitatively analyze the nonlinear response. As a result, an evolution of the domain wall motion dynamics through the PPB region is detected. This work demonstrates that the extrinsic contribution at a PPB may have a dynamic role in lead-free piezoelectric materials, thereby exerting a far greater influence on their functional properties than that considered to date.Postprint (author's final draft

Post-silicon Receiver Equalization Metamodeling by Artificial Neural Networks

As microprocessor design scales to the 10 nm technology and beyond, traditional pre- and post-silicon validation techniques are unsuitable to get a full system functional coverage. Physical complexity and extreme technology process variations severely limits the effectiveness and reliability of pre-silicon validation techniques. This scenario imposes the need of sophisticated post-silicon validation approaches to consider complex electromagnetic phenomena and large manufacturing fluctuations observed in actual physical platforms. One of the major challenges in electrical validation of high-speed input/output (HSIO) links in modern computer platforms lies in the physical layer (PHY) tuning process, where equalization techniques are used to cancel undesired effects induced by the channels. Current industrial practices for PHY tuning in HSIO links are very time consuming since they require massive lab measurements. An alternative is to use machine learning techniques to model the PHY, and then perform equalization using the resultant surrogate model. In this paper, a metamodeling approach based on neural networks is proposed to efficiently simulate the effects of a receiver equalizer PHY tuning settings. We use several design of experiments techniques to find a neural model capable of approximating the real system behavior without requiring a large amount of actual measurements. We evaluate the models performance by comparing with measured responses on a real server HSIO link