23 research outputs found

    Elemental chalcogens as a minimal model for chiral charge and orbital order

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    Helices of increased electron density can spontaneously form in materials containing multiple, interacting density waves. Although a macroscopic order parameter theory describing this behaviour has been proposed and experimentally tested, a detailed microscopic understanding of spiral electronic order in any particular material is still lacking. Here, we present the elemental chalcogens Selenium and Tellurium as model materials for the development of chiral charge and orbital order. We formulate minimal models capturing the formation of spiral structures both in terms of a macroscopic Landau theory and a microscopic Hamiltonian. Both reproduce the known chiral crystal structure and are consistent with its observed thermal evolution and behaviour under applied pressure. The combination of microscopic and macroscopic frameworks allows us to distil the essential ingredients in the emergence of helical charge order, and may serve as a guide to understanding spontaneous chirality both in other specific materials and throughout materials classes

    Charge order from structured coupling in VSe2_2

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    Charge order--ubiquitous among correlated materials--is customarily described purely as an instability of the electronic structure. However, the resulting theoretical predictions often do not match high-resolution experimental data. A pertinent case is 1T1T-VSe2_2, whose single-band Fermi surface and weak-coupling nature make it qualitatively similar to the Peierls model underlying the traditional approach. Despite this, its Fermi surface is poorly nested, the thermal evolution of its charge density wave (CDW) ordering vectors displays an unexpected jump, and the CDW gap itself evades detection in direct probes of the electronic structure. We demonstrate that the thermal variation of the CDW vectors is naturally reproduced by the electronic susceptibility when incorporating a structured, momentum-dependent electron-phonon coupling, while the evasive CDW gap presents itself as a localized suppression of spectral weight centered above the Fermi level. Our results showcase the general utility of incorporating a structured coupling in the description of charge ordered materials, including those that appear unconventional

    Charge order from structured coupling in VSe2

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    Charge order -- ubiquitous among correlated materials -- is customarily described purely as an instability of the electronic structure. However, the resulting theoretical predictions often do not match high-resolution experimental data. A pertinent case is 1T-VSe2, whose single-band Fermi surface and weak-coupling nature make it qualitatively similar to the Peierls model underlying the traditional approach. Despite this, its Fermi surface is poorly nested, the thermal evolution of its charge density wave (CDW) ordering vectors displays an unexpected jump, and the CDW gap itself evades detection in direct probes of the electronic structure. We demonstrate that the thermal variation of the CDW vectors is naturally reproduced by the electronic susceptibility when incorporating a structured, momentum-dependent electron-phonon coupling, while the evasive CDW gap presents itself as a localized suppression of spectral weight centered above the Fermi level. Our results showcase the general utility of incorporating a structured coupling in the description of charge ordered materials, including those that appear unconventional

    Prevalence, associated factors and outcomes of pressure injuries in adult intensive care unit patients: the DecubICUs study

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    Funder: European Society of Intensive Care Medicine; doi: http://dx.doi.org/10.13039/501100013347Funder: Flemish Society for Critical Care NursesAbstract: Purpose: Intensive care unit (ICU) patients are particularly susceptible to developing pressure injuries. Epidemiologic data is however unavailable. We aimed to provide an international picture of the extent of pressure injuries and factors associated with ICU-acquired pressure injuries in adult ICU patients. Methods: International 1-day point-prevalence study; follow-up for outcome assessment until hospital discharge (maximum 12 weeks). Factors associated with ICU-acquired pressure injury and hospital mortality were assessed by generalised linear mixed-effects regression analysis. Results: Data from 13,254 patients in 1117 ICUs (90 countries) revealed 6747 pressure injuries; 3997 (59.2%) were ICU-acquired. Overall prevalence was 26.6% (95% confidence interval [CI] 25.9–27.3). ICU-acquired prevalence was 16.2% (95% CI 15.6–16.8). Sacrum (37%) and heels (19.5%) were most affected. Factors independently associated with ICU-acquired pressure injuries were older age, male sex, being underweight, emergency surgery, higher Simplified Acute Physiology Score II, Braden score 3 days, comorbidities (chronic obstructive pulmonary disease, immunodeficiency), organ support (renal replacement, mechanical ventilation on ICU admission), and being in a low or lower-middle income-economy. Gradually increasing associations with mortality were identified for increasing severity of pressure injury: stage I (odds ratio [OR] 1.5; 95% CI 1.2–1.8), stage II (OR 1.6; 95% CI 1.4–1.9), and stage III or worse (OR 2.8; 95% CI 2.3–3.3). Conclusion: Pressure injuries are common in adult ICU patients. ICU-acquired pressure injuries are associated with mainly intrinsic factors and mortality. Optimal care standards, increased awareness, appropriate resource allocation, and further research into optimal prevention are pivotal to tackle this important patient safety threat

    The politics of history education : teaching national history, identity and citizenship in Belgium and the Netherlands, 1830-1880

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    Defence date: 28 March 2014Examining Board: Professor dr. Pavel Kolář, (European University Institute); Professor dr. Heinz-Gerhard Haupt, (European University Institute); Professor dr. Joep Leerssen, (University of Amsterdam); Professor dr. Tom Verschaffel, (KU Leuven)This dissertation has studied the discourses around national history education in Belgium and the Netherlands in the middle of the nineteenth century. The literature on nation building and cultural nationalism often observes the importance of education as an instrument of nation building. Expanding school networks were one of the important conduits through which national awareness was spread among the populace. They helped to disseminate knowledge of the national language, culture and history, thus teaching the future generations about their 'home' and 'nation'. At the same time, historians often note the significance of narratives, often historical narratives, in fostering a sense of pride and attachment to the fatherland. Nevertheless, studies of the contents of and controversies surrounding history education are sparse. In this study, I hope to show that the field of (history) education is an important locus of nation building and therefore worthy of scholarly attention. Following Jörn Rüsen, I argue that history education knows a specific configuration of epistemological, aesthetic and political dimensions that makes it unique. It prioritises the political dimension over the two other dimensions, thus setting it apart from scholarly or literary and artistic forms of history-writing. Due to its pedagogical objective, furthermore, it is also different from other political forms of history-writing. History education addresses the future citizen directly and presents them visions of the good citizen. I argue that the civic virtues are an indispensable part of national identity. The education thereof should consequently be studied more in-depth. This dissertation therefore analyses notions of good citizenship present in the debates and contents of history education. Furthermore, it dissects ideas of national identity along the lines of nation and religion, nation and language, the national territory, nation and dynasty and the nation in the world
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