Adaptive chaotic particle swarm algorithm for isogeometric multi-objective size optimization of FG plates

An effective multi-objective optimization methodology that combines the isogeometric analysis (IGA) and adaptive chaotic particle swarm algorithm is presented for optimizing ceramic volume fraction (CVF) distribution of functionally graded plates (FGPs) under eigenfrequencies. The CVF distribution is represented by the B-spline basis function. Mechanical behaviors of FGPs are obtained with NURBS-based IGA and the recently developed simple first-order shear theory. The design variables are the CVFs at control points in the thickness direction, and the optimization objective is to minimize the mass of structure and maximize the first natural frequency. A recently developed multi-objective adaptive chaotic particle swarm algorithm with high efficiency is employed as an optimizer. All desirable features of the developed approach will be illustrated through four numerical examples, confirming its effectiveness and reliability

Fast determination of thiacloprid by photoinduced chemiluminescence

This paper was published in Applied Spectroscopy and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: http://www.opticsinfobase.org/as/abstract.cfm?URI=as-68-6-642. Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under law.A new and sensitive application of the chemiluminescence detection has been developed for the determination of the pesticide thiacloprid in water. It was based on the on-line photoreaction of thiacloprid in basic medium, with quinine acting as sensitizer of the chemiluminescent response; Cerium (IV) in sulfuric acid medium was used as oxidant. A high automation and reproducibility was provided by a flow injection analysis (FIA) manifold. The validation of the method was performed in terms of selectivity, linearity, LOD, precision and accuracy. Liquid chromatography with UV detection was used as reference for mineral, tap, ground and spring water samples. The proposed method is fast (throughput of 130 h-1), sensitive (LOD of 0.8 ng mL-1 without preconcentration steps and 0.08 ng mL-1 with solid phase extraction (SPE)), low-cost and possible to couple with separative methods for the simultaneous determination of other pesticides. The enhanced chemiluminescence intensity was linear with thiacloprid concentration over the (2-80) and (80-800) ng mL-1 ranges. A possible reaction mechanism is also discussed.The authors thank the Ministerio de Educacion y Ciencia of Spain and the Fondo Europeo de Desarrollo Regional for financial support, Project CTM2006-11991.Catalá Icardo, M.; López Paz, JL.; Pérez Plancha, LM. (2014). Fast determination of thiacloprid by photoinduced chemiluminescence. Applied Spectroscopy. 68(6):642-648. https://doi.org/10.1366/13-07330S642648686Tomizawa, M., & Casida, J. E. (2005). NEONICOTINOID INSECTICIDE TOXICOLOGY: Mechanisms of Selective Action. Annual Review of Pharmacology and Toxicology, 45(1), 247-268. doi:10.1146/annurev.pharmtox.45.120403.095930Tapparo, A., Giorio, C., Soldà, L., Bogialli, S., Marton, D., Marzaro, M., & Girolami, V. (2012). UHPLC-DAD method for the determination of neonicotinoid insecticides in single bees and its relevance in honeybee colony loss investigations. Analytical and Bioanalytical Chemistry, 405(2-3), 1007-1014. doi:10.1007/s00216-012-6338-3Tennekes, H. A., & Sánchez-Bayo, F. (2013). The molecular basis of simple relationships between exposure concentration and toxic effects with time. Toxicology, 309, 39-51. doi:10.1016/j.tox.2013.04.007Peña, A., Rodríguez-Liébana, J. A., & Mingorance, M. D. (2011). Persistence of two neonicotinoid insecticides in wastewater, and in aqueous solutions of surfactants and dissolved organic matter. Chemosphere, 84(4), 464-470. doi:10.1016/j.chemosphere.2011.03.039Di Muccio, A., Fidente, P., Barbini, D. A., Dommarco, R., Seccia, S., & Morrica, P. (2006). Application of solid-phase extraction and liquid chromatography–mass spectrometry to the determination of neonicotinoid pesticide residues in fruit and vegetables. Journal of Chromatography A, 1108(1), 1-6. doi:10.1016/j.chroma.2005.12.111Fidente, P., Seccia, S., Vanni, F., & Morrica, P. (2005). Analysis of nicotinoid insecticides residues in honey by solid matrix partition clean-up and liquid chromatography–electrospray mass spectrometry. Journal of Chromatography A, 1094(1-2), 175-178. doi:10.1016/j.chroma.2005.09.012Seccia, S., Fidente, P., Barbini, D. A., & Morrica, P. (2005). Multiresidue determination of nicotinoid insecticide residues in drinking water by liquid chromatography with electrospray ionization mass spectrometry. Analytica Chimica Acta, 553(1-2), 21-26. doi:10.1016/j.aca.2005.08.006Pareja, L., Martínez-Bueno, M. J., Cesio, V., Heinzen, H., & Fernández-Alba, A. R. (2011). Trace analysis of pesticides in paddy field water by direct injection using liquid chromatography–quadrupole-linear ion trap-mass spectrometry. Journal of Chromatography A, 1218(30), 4790-4798. doi:10.1016/j.chroma.2011.02.044Seccia, S., Fidente, P., Montesano, D., & Morrica, P. (2008). Determination of neonicotinoid insecticides residues in bovine milk samples by solid-phase extraction clean-up and liquid chromatography with diode-array detection. Journal of Chromatography A, 1214(1-2), 115-120. doi:10.1016/j.chroma.2008.10.088Wang, W., Li, Y., Wu, Q., Wang, C., Zang, X., & Wang, Z. (2012). Extraction of neonicotinoid insecticides from environmental water samples with magnetic graphene nanoparticles as adsorbent followed by determination with HPLC. Analytical Methods, 4(3), 766. doi:10.1039/c2ay05734dBi, X., & Yang, K.-L. (2009). On-Line Monitoring Imidacloprid and Thiacloprid in Celery Juice Using Quartz Crystal Microbalance. Analytical Chemistry, 81(2), 527-532. doi:10.1021/ac801786aGámiz-Gracia, L., Garcı́a-Campaña, A. M., Soto-Chinchilla, J. J., Huertas-Pérez, J. F., & González-Casado, A. (2005). Analysis of pesticides by chemiluminescence detection in the liquid phase. TrAC Trends in Analytical Chemistry, 24(11), 927-942. doi:10.1016/j.trac.2005.05.009Roda, A., & Guardigli, M. (2011). Analytical chemiluminescence and bioluminescence: latest achievements and new horizons. Analytical and Bioanalytical Chemistry, 402(1), 69-76. doi:10.1007/s00216-011-5455-8Du, J., & Li, H. (2010). Sensitive Chemiluminescence Determination of Thirteen Cephalosporin Antibiotics with Luminol—Copper(II) Reaction. Applied Spectroscopy, 64(10), 1154-1159. doi:10.1366/000370210792973613Li, Y., Li, Y., & Yang, Y. (2011). Flow-Injection Chemiluminescence Determination of Lisinopril Using Luminol–KMnO4 Reaction Catalyzed by Silver Nanoparticles. Applied Spectroscopy, 65(4), 376-381. doi:10.1366/10-06115Catalá-Icardo, M., López-Paz, J. L., Choves-Barón, C., & Peña-Bádena, A. (2012). Native vs photoinduced chemiluminescence in dimethoate determination. Analytica Chimica Acta, 710, 81-87. doi:10.1016/j.aca.2011.10.043Mestre, Y. F., Zamora, L. L., & Calatayud, J. M. (2001). Flow-chemiluminescence: a growing modality of pharmaceutical analysis. Luminescence, 16(3), 213-235. doi:10.1002/bio.608Lara, F. J., García-Campaña, A. M., & Aaron, J.-J. (2010). Analytical applications of photoinduced chemiluminescence in flow systems—A review. Analytica Chimica Acta, 679(1-2), 17-30. doi:10.1016/j.aca.2010.09.001Icardo, M. C., & Calatayud, J. M. (2008). Photo-Induced Luminescence. Critical Reviews in Analytical Chemistry, 38(2), 118-130. doi:10.1080/10408340802039609RICART, I., ANTONFOS, G., DUART, M., MATEO, J., ZAMORA, L., & CALATAYUD, J. (2007). Theoretical prediction of the photoinduced chemiluminescence of pesticides. Talanta, 72(2), 378-386. doi:10.1016/j.talanta.2006.10.048Abramović, B. F., Banić, N. D., & Šojić, D. V. (2010). Degradation of thiacloprid in aqueous solution by UV and UV/H2O2 treatments. Chemosphere, 81(1), 114-119. doi:10.1016/j.chemosphere.2010.07.016Icardo, M. (2003). FI-on line photochemical reaction for direct chemiluminescence determination of photodegradated chloramphenicol. Talanta, 60(2-3), 405-414. doi:10.1016/s0039-9140(03)00074-2Zhao, Y., Baeyens, W. R. G., Zhang, X., Calokerinos, A. C., Nakashima, K., & Der Weken, G. V. (1997). Chemiluminescence Determination of Tiopronin by Flow Injection Analysis Based on Cerium(IV) Oxidation Sensitized by Quinine. The Analyst, 122(2), 103-106. doi:10.1039/a605703iZhang, Z., Baeyens, W. R. G., Zhang, X., Zhao, Y., & Van Der Weken, G. (1997). Chemiluminescence detection coupled to liquid chromatography for the determination of penicillamine in human urine. Analytica Chimica Acta, 347(3), 325-332. doi:10.1016/s0003-2670(97)00171-2Capitán-Vallvey, L. (2000). Chemiluminescence determination of sodium 2-mercaptoethane sulfonate by flow injection analysis using cerium(IV) sensitized by quinine. Talanta, 51(6), 1155-1161. doi:10.1016/s0039-9140(00)00291-5NIE, L., MA, H., SUN, M., LI, X., SU, M., & LIANG, S. (2003). Direct chemiluminescence determination of cysteine in human serum using quinine–Ce(IV) system. Talanta, 59(5), 959-964. doi:10.1016/s0039-9140(02)00649-5Lakowicz, J. R. (Ed.). (2006). Principles of Fluorescence Spectroscopy. doi:10.1007/978-0-387-46312-4Lookabaugh, M., & Krull, I. S. (1988). Determination of nitrite and nitrate by reversed-phase high-performance liquid chromatography using on-line post-column photolysis with ultraviolet absorbance and electrochemical detection. Journal of Chromatography A, 452, 295-308. doi:10.1016/s0021-9673(01)81454-0Gómez-Benito, C., Meseguer-Lloret, S., & Torres-Cartas, S. (2013). Sensitive determination of Fenamiphos in water samples by flow injection photoinduced chemiluminescence. International Journal of Environmental Analytical Chemistry, 93(2), 152-165. doi:10.1080/03067319.2012.663755CATALÁ-ICARDO, M., LÓPEZ-PAZ, J. L., & PEÑA-BÁDENA, A. (2011). FI-photoinduced Chemiluminescence Method for Diuron Determination in Water Samples. Analytical Sciences, 27(3), 291. doi:10.2116/analsci.27.291Hamilton, D. J., Ambrus, Á., Dieterle, R. M., Felsot, A. S., Harris, C. A., Holland, P. T., … Wong, S.-S. (2003). Regulatory limits for pesticide residues in water (IUPAC Technical Report). Pure and Applied Chemistry, 75(8), 1123-1155. doi:10.1351/pac20037508112

Energy Relaxation in Nonlinear One-Dimensional Lattices

We study energy relaxation in thermalized one-dimensional nonlinear arrays of the Fermi-Pasta-Ulam type. The ends of the thermalized systems are placed in contact with a zero-temperature reservoir via damping forces. Harmonic arrays relax by sequential phonon decay into the cold reservoir, the lower frequency modes relaxing first. The relaxation pathway for purely anharmonic arrays involves the degradation of higher-energy nonlinear modes into lower energy ones. The lowest energy modes are absorbed by the cold reservoir, but a small amount of energy is persistently left behind in the array in the form of almost stationary low-frequency localized modes. Arrays with interactions that contain both a harmonic and an anharmonic contribution exhibit behavior that involves the interplay of phonon modes and breather modes. At long times relaxation is extremely slow due to the spontaneous appearance and persistence of energetic high-frequency stationary breathers. Breather behavior is further ascertained by explicitly injecting a localized excitation into the thermalized array and observing the relaxation behavior

Multi-scale Designed CoxMn3–xO4 Spinels : Smart Pre-Catalysts towards High-Efficiency Pyrolysis-Catalysis Recycling of Waste Plastics

Acknowledgements M. W. and A. W. highly acknowledge the funding by the German Federal Ministry of Education and Research (BMBF) within the NexPlas project (project number: 03SF0618B). Y. S. Z is grateful for financial supports provided by the Royal Society of Chemistry Enablement Grant (E21-5819318767) and Royal Society of Chemistry Mobility Grant (M19-2899).Peer reviewedPostprin

Tunneling of quantum rotobreathers

We analyze the quantum properties of a system consisting of two nonlinearly coupled pendula. This non-integrable system exhibits two different symmetries: a permutational symmetry (permutation of the pendula) and another one related to the reversal of the total momentum of the system. Each of these symmetries is responsible for the existence of two kinds of quasi-degenerated states. At sufficiently high energy, pairs of symmetry-related states glue together to form quadruplets. We show that, starting from the anti-continuous limit, particular quadruplets allow us to construct quantum states whose properties are very similar to those of classical rotobreathers. By diagonalizing numerically the quantum Hamiltonian, we investigate their properties and show that such states are able to store the main part of the total energy on one of the pendula. Contrary to the classical situation, the coupling between pendula necessarily introduces a periodic exchange of energy between them with a frequency which is proportional to the energy splitting between quasi-degenerated states related to the permutation symmetry. This splitting may remain very small as the coupling strength increases and is a decreasing function of the pair energy. The energy may be therefore stored in one pendulum during a time period very long as compared to the inverse of the internal rotobreather frequency.Comment: 20 pages, 11 figures, REVTeX4 styl

Formation of Subtropical Mode Water in a high-resolution ocean simulation of the Kuroshio Extension region

Author Posting. © Elsevier B.V., 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Ocean Modelling 17 (2007): 338-356, doi:10.1016/j.ocemod.2007.03.002.A high-resolution numerical model is used to examine the formation and variability of the North Pacific Subtropical ModeWater (STMW) over a 3-year period. The STMW distribution is found to be highly variable in both space and time, a characteristic often unexplored because of sparse observations or the use of coarse resolution simulations. Its distribution is highly dependent on eddies, and where it was renewed during the previous winter. Although the potential vorticity fluxes associated with down-front winds can be of the same order of magnitude or even greater than the diabatic ones due to air-sea temperature differences, the latter dominate the potential vorticity budget on regional and larger scales. Air-sea fluxes, however, are dominated by a few strong wind events, emphasizing the importance of short time scales in the formation of mode waters. In the Kuroshio Extension region, both advection and mixing play important roles to remove the STMW from the formation region.This work was sponsored by the National Science Foundation OCE-0220161 (S.J.) and OCE-0221781/0549225 (J.M.), the Office of Naval Research (J.M., M.M.), Department of Energy/CCPP (M.M.), and the Office of Science (BER), US Department of Energy, Grant No. DE-FG02-05ER64119 (J.M.)

Coherent electron-phonon coupling and polaron-like transport in molecular wires

We present a technique to calculate the transport properties through one-dimensional models of molecular wires. The calculations include inelastic electron scattering due to electron-lattice interaction. The coupling between the electron and the lattice is crucial to determine the transport properties in one-dimensional systems subject to Peierls transition since it drives the transition itself. The electron-phonon coupling is treated as a quantum coherent process, in the sense that no random dephasing due to electron-phonon interactions is introduced in the scattering wave functions. We show that charge carrier injection, even in the tunneling regime, induces lattice distortions localized around the tunneling electron. The transport in the molecular wire is due to polaron-like propagation. We show typical examples of the lattice distortions induced by charge injection into the wire. In the tunneling regime, the electron transmission is strongly enhanced in comparison with the case of elastic scattering through the undistorted molecular wire. We also show that although lattice fluctuations modify the electron transmission through the wire, the modifications are qualitatively different from those obtained by the quantum electron-phonon inelastic scattering technique. Our results should hold in principle for other one-dimensional atomic-scale wires subject to Peierls transitions.Comment: 21 pages, 8 figures, accepted for publication in Phys. Rev. B (to appear march 2001

Application of phage display to high throughput antibody generation and characterization.

We have created a high quality phage display library containing over 1010 human antibodies and describe its use in the generation of antibodies on an unprecedented scale. We have selected, screened and sequenced over 38,000 recombinant antibodies to 292 antigens, yielding over 7,200 unique clones. 4,400 antibodies were characterized by specificity testing and detailed sequence analysis and the data/clones are available online. Sensitive detection was demonstrated in a bead based flow cytometry assay. Furthermore, positive staining by immunohistochemistry on tissue microarrays was found for 37% (143/381) of antibodies. Thus, we have demonstrated the potential of and illuminated the issues associated with genome-wide monoclonal antibody generation.RIGHTS : This article is licensed under the BioMed Central licence at http://www.biomedcentral.com/about/license which is similar to the 'Creative Commons Attribution Licence'. In brief you may : copy, distribute, and display the work; make derivative works; or make commercial use of the work - under the following conditions: the original author must be given credit; for any reuse or distribution, it must be made clear to others what the license terms of this work are

Partial Wave Analysis of J/ψ→γ(K+K−π+π−)J/\psi \to \gamma (K^+K^-\pi^+\pi^-)

BES data on $J/\psi \to \gamma (K^+K^-\pi^+\pi^-)$ are presented. The $K^*\bar K^*$ contribution peaks strongly near threshold. It is fitted with a broad $0^{-+}$ resonance with mass $M = 1800 \pm 100$ MeV, width $\Gamma = 500 \pm 200$ MeV. A broad $2^{++}$ resonance peaking at 2020 MeV is also required with width $\sim 500$ MeV. There is further evidence for a $2^{-+}$ component peaking at 2.55 GeV. The non-$K^*\bar K^*$ contribution is close to phase space; it peaks at 2.6 GeV and is very different from $K^{*}\bar{K^{*}}$.Comment: 15 pages, 6 figures, 1 table, Submitted to PL