3,309 research outputs found
Thulium and ytterbium-doped titanium oxide thin films deposited by ultrasonic spray pyrolysis
Thin films of thulium and ytterbium-doped titanium oxide were grown by
metal-organic spray pyrolysis deposition from titanium(IV)oxide
bis(acetylacetonate), thulium(III) tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
and ytterbium(III) tris(acetylacetonate). Deposition temperatures have been
investigated from 300{\deg}C to 600{\deg}C. Films have been studied regarding
their crystallity and doping quality. Structural and composition
characterisations of TiO2:Tm,Yb were performed by electron microprobe, X-ray
diffraction and Fourier transform infrared spectroscopy. The deposition rate
can reach 0.8 \mum/h. The anatase phase of TiO2 was obtained after synthesis at
400{\deg}C or higher. Organic contamination at low deposition temperature is
eliminated by annealing treatments.Comment: 6 pages, 6 figure
Fresh concrete pumping arrest investigation for thixotropy by a CFD modelling apporach
Concrete pumping operations determine construction speed, finishing
quality, durability and even structural integrity. When pumping operations
cannot be continued, most problems occur due to complex time-dependent
transformations. This causes significant industrial costs (e.g. material and delay).
Since time-dependent aspects are currently not fully understood and cannot be
predicted, a way to quantify time-dependent aspects is needed. Therefore, we
make an attempt by numerical simulation by comparing thixotropic cases with
different pumping arresting times. After an introduction to fresh concrete rheology
and numerical modelling, ten representative thixotropy cases are analysed.
Despite some unresolved numerical instabilities, the numerical framework
allows to estimate pumping pressure peaks after resting time. The results
evaluate a thixotropy model, which is generally applicable for less thixotropic
SCC’s. It is clear that flow re-initiation after rest in concrete pumping is poorly
understood. Numerical simulation could be one approach for further analysis
and is potentially important for practice. Future work such as simulation of
concrete mixers, pressure increase after pumping arrest, formwork pressure
decay and leakage are therefore recommended
Development of molecular tests for the detection of ILAR and latent viruses in fruit trees.
peer reviewe
Acid/base-triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenes.
Electronic circular dichroism and circularly polarized luminescence acid/base switching activity has been demonstrated in helicene-bipyridine proligand 1 a and in its “rollover” cycloplatinated derivative 2 a. Whereas proligand 1 a displays a strong bathochromic shift (>160 nm) of the nonpolarized and circularly polarized luminescence upon protonation, complex 2 a displays slightly stronger emission. This strikingly different behavior between singlet emission in the organic helicene and triplet emission in the organometallic derivative has been rationalized by using quantum-chemical calculations. The very large bathochromic shift of the emission observed upon protonation of azahelicene-bipyridine 1 a has been attributed to the decrease in aromaticity (promoting a charge-transfer-type transition rather than a π–π* transition) as well as an increase in the HOMO–LUMO character of the transition and stabilization of the LUMO level upon protonation
Frequency and Diversity of Nitrate Reductase Genes among Nitrate-Dissimilating Pseudomonas in the Rhizosphere of Perennial Grasses Grown in Field Conditions
A total of 1246 Pseudomonas strains were isolated from the rhizosphere of two perennial grasses (Lolium perenne and Molinia coerulea) with different nitrogen requirements. The plants were grown in their native soil under ambient and elevated atmospheric CO2 content (pCO2) at the Swiss FACE (Free Air CO2 Enrichment) facility. Root-, rhizosphere-, and non-rhizospheric soil-associated strains were characterized in terms of their ability to reduce nitrate during an in vitro assay and with respect to the genes encoding the membrane-bound (named NAR) and periplasmic (NAP) nitrate reductases so far described in the genus Pseudomonas. The diversity of corresponding genes was assessed by PCR-RFLP on narG and napA genes, which encode the catalytic subunit of nitrate reductases. The frequency of nitrate-dissimilating strains decreased with root proximity for both plants and was enhanced under elevated pCO2 in the rhizosphere of L. perenne. NAR (54% of strains) as well as NAP (49%) forms were present in nitrate-reducing strains, 15.5% of the 439 strains tested harbouring both genes. The relative proportions of narG and napA detected in Pseudomonas strains were different according to root proximity and for both pCO2 treatments: the NAR form was more abundant close to the root surface and for plants grown under elevated pCO2. Putative denitrifiers harbored mainly the membrane-bound (NAR) form of nitrate reductase. Finally, both narG and napA sequences displayed a high level of diversity. Anyway, this diversity was correlated neither with the root proximity nor with the pCO2 treatmen
Radio continuum and far-infrared emission from the galaxies in the Eridanus group
The Eridanus galaxies follow the well-known radio-FIR correlation. Majority
(70%) of these galaxies have their star formation rates below that of the Milky
Way. The galaxies having a significant excess of radio emission are identified
as low luminosity AGNs based on their radio morphologies obtained from the GMRT
observations. There are no powerful AGNs (L{20cm} > 10^{23} W Hz^{-1}) in the
group. The two most far-infrared and radio luminous galaxies in the group have
optical and HI morphologies suggestive of recent tidal interactions. The
Eridanus group also has two far-infrared luminous but radio-deficient galaxies.
It is believed that these galaxies are observed within a few Myr of the onset
of an intense star formation episode after being quiescent for at least a 100
Myr. The upper end of the radio luminosity distribution of the Eridanus
galaxies (L_{20cm} ~ 10^{22} W Hz^{-1}) is consistent with that of the field
galaxies, other groups, and late-type galaxies in nearby clusters.Comment: 16 pages; Accepted for publication in Journal of Astroph. & Astron.
March, 200
Direct mass measurements of 19B, 22C, 29F, 31Ne, 34Na and other light exotic nuclei
We report on direct time-of-flight based mass measurements of 16 light
neutron-rich nuclei. These include the first determination of the masses of the
Borromean drip-line nuclei B, C and F as well as that of
Na. In addition, the most precise determinations to date for N
and Ne are reported. Coupled with recent interaction cross-section
measurements, the present results support the occurrence of a two-neutron halo
in C, with a dominant configuration, and a
single-neutron halo in Ne with the valence neutron occupying
predominantly the 2 orbital. Despite a very low two-neutron separation
energy the development of a halo in B is hindered by the 1
character of the valence neutrons.Comment: 5 page
Application of the Frobenius method to the Schrodinger equation for a spherically symmetric potential: anharmonic oscillator
The power series method has been adapted to compute the spectrum of the
Schrodinger equation for central potential of the form . The bound-state energies
are given as zeros of a calculable function, if the potential is confined in a
spherical box. For an unconfined potential the interval bounding the energy
eigenvalues can be determined in a similar way with an arbitrarily chosen
precision. The very accurate results for various spherically symmetric
anharmonic potentials are presented.Comment: 16 pages, 5 figures, published in J. Phys
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