Chiral QCD, General QCD Parameterization and Constituent Quark Models

Several recent papers -using effective QCD chiral Lagrangians- reproduced results obtained with the general QCD parameterization (GP). These include the baryon 8+10 mass formula, the octet magnetic moments and the coincidental nature of the "perfect" -3/2 ratio between the magnetic moments of p and n. Although we anticipated that the GP covers the case of chiral treatments, the above results explicitly exemplify this fact. Also we show by the GP that -in any model or theory (chiral or non chiral) reproducing the results of exact QCD- the Franklin (Coleman Glashow) sum rule for the octet magnetic moments must be violated.Comment: 10 pages, Latex; abridged version (same results), removed some reference

Temperature-dependent rate coefficients for the reactions of the hydroxyl radical with the atmospheric biogenics isoprene, alpha-pinene and delta-3-carene

Pulsed laser methods for OH generation and detection were used to study atmospheric degradation reactions for three important biogenic gases: OHCisoprene (Reaction R1), OH+α-pinene (Reaction R2) and OH+Δ- 3-carene (Reaction R3). Gas-phase rate coefficients were characterized by non-Arrhenius kinetics for all three reactions. For (R1), k1 (241-356 K)= (1:93±0:08)× 10-11 exp{(466±12)/T} cm3 molecule-1 s-1 was determined, with a room temperature value of k1 (297 K)= (9:3± 0:4)×10-11 cm3 molecule-1 s-1, independent of bath-gas pressure (5-200 Torr) and composition (MDN2 or air). Accuracy and precision were enhanced by online optical monitoring of isoprene, with absolute concentrations obtained via an absorption cross section, αisoprene = (1:28±0:06)× 10-17 cm2 molecule-1 at λ = 184:95 nm, determined in this work. These results indicate that significant discrepancies between previous absolute and relative-rate determinations of k1 result in part from σ values used to derive the isoprene concentration in high-precision absolute determinations. Similar methods were used to determine rate coefficients (in 10-11 cm3 molecule-1 s-1/ for (R2)-(R3): k2 (238-357 K)= (1:83±0:04) ×exp{(330±6)/T } and k3 (235-357 K)= (2:48±0:14) ×exp{(357±17)/T }. This is the first temperature-dependent dataset for (R3) and enables the calculation of reliable atmospheric lifetimes with respect to OH removal for e.g. boreal forest springtime conditions. Room temperature values of k2 (296 K)= (5:4±0:2) ×10-11 cm3 molecule-1 s-1 and k3 (297 K)= (8:1±0:3)×10-11 cm3 molecule-1 s-1 were independent of bathgas pressure (7-200 Torr, N2 or air) and in good agreement with previously reported values. In the course of this work, 184.95 nm absorption cross sections were determined: σ = (1:54±0:08) ×10-17 cm2 molecule-1 for α-pinene and (2:40±0:12)×10-17 cm2 molecule-1 for 1-3-carene

Coherent response of lakes in Ontario, Canada to reductions in sulphur deposition: the effects of climate on sulphate concentrations

International audienceSulphate deposition in south-central Ontario declined between 1976 and 2000 by more than 50%, whereas lake sulphate (SO42?) concentrations decreased by, on average, only half as much. To investigate the factors that controlled this slower than expected response, the temporal patterns in lake SO42? concentrations were compared with patterns in both deposition and climate, since climate has a major influence on the hydrological cycle in this part of the continent. To do this, the temporal coherence in SO42? concentrations between 9 lake basins was estimated using the intraclass correlation from a repeated-measures analysis of variance and two subsets of lakes were found (six in one group, four in the other), each with lakes having synchronous patterns. One subset (4 lakes) included the 3 with the longest water replenishment times (>3.4 yr) which are expected to respond to decreases in SO42? deposition more slowly. However, the average pattern reflecting the temporal changes of each of the two subsets was very similar. The response of both subsets of lakes to the decreasing SO42? deposition over two decades was independent of the degree of acidification or sensitivity to acidification of the lakes. In a determination of which factors best predicted each of those two subsets' SO42? time series, good predictive models were produced by regional/global-scale climate indices, specifically the Southern Oscillation Index (SOI) describing the El Niño Southern Oscillation (ENSO) and the North Atlantic Oscillation Index (NAOI), as well as by SO42? deposition indices. When the predictor variables were combined, models which described the long-term changes in lake SO42? concentration best included the SOI, the NAOI and SO42? deposition. Thus, large-scale climate factors play a major role in determining the response of aquatic systems to changes in SO42? deposition, perhaps through their influence on lake and/or catchment processes that effectively delay recovery. Keywords: Atmospheric deposition, lake recovery, temporal trends, climate, temporal coherenc

Temperature-(208-318 K) and pressure-(18-696Torr) dependent rate coefficients for the reaction between OH and HNO3

Abstract. Rate coefficients (k5) for the title reaction were ob- tained using pulsed laser photolytic generation of OH cou- pled to its detection by laser-induced fluorescence (PLP– LIF). More than 80 determinations of k5 were carried out in nitrogen or air bath gas at various temperatures and pres- sures. The accuracy of the rate coefficients obtained was en- hanced by in situ measurement of the concentrations of both HNO3 reactant and NO2 impurity. The rate coefficients show both temperature and pressure dependence with a rapid in- crease in k5 at low temperatures. The pressure dependence was weak at room temperature but increased significantly at low temperatures. The entire data set was combined with se- lected literature values of k5 and parameterised using a com- bination of pressure-dependent and -independent terms to give an expression that covers the relevant pressure and tem- perature range for the atmosphere. A global model, using the new parameterisation for k 5 rather than those presently ac- cepted, indicated small but significant latitude- and altitude- dependent changes in the HNO 3 / NO x ratio of between − 6 and + 6 %. Effective HNO 3 absorption cross sections (184.95 and 213.86 nm, units of cm 2 molecule − 1 ) were ob- tained as part of this work: σ 213 . 86 = 4.52 + 0 . 23 − 0 . 12 × 10 − 19 and σ 184 . 95 = 1.61 + 0 . 08 − 0 . 04 × 10 − 17

The impact of broadband in schools

The report reviews evidence for the impact of broadband in English schools, exploring; Variations in provision in level of broadband connectivity; Links between the level of broadband activity and nationally accessible performance data; Aspects of broadband connectivity and the school environment that contribute to better outcomes for pupils and teachers; Academic and motivational benefits associated with educational uses of this technology

High-severity wildfire leads to multi-decadal impacts on soil biogeochemistry in mixed-conifer forests.

During the past century, systematic wildfire suppression has decreased fire frequency and increased fire severity in the western United States of America. While this has resulted in large ecological changes aboveground such as altered tree species composition and increased forest density, little is known about the long-term, belowground implications of altered, ecologically novel, fire regimes, especially on soil biological processes. To better understand the long-term implications of ecologically novel, high-severity fire, we used a 44-yr high-severity fire chronosequence in the Sierra Nevada where forests were historically adapted to frequent, low-severity fire, but were fire suppressed for at least 70 yr. High-severity fire in the Sierra Nevada resulted in a long-term (44 +yr) decrease (>50%, P < 0.05) in soil extracellular enzyme activities, basal microbial respiration (56-72%, P < 0.05), and organic carbon (>50%, P < 0.05) in the upper 5 cm compared to sites that had not been burned for at least 115 yr. However, nitrogen (N) processes were only affected in the most recent fire site (4 yr post-fire). Net nitrification increased by over 600% in the most recent fire site (P < 0.001), but returned to similar levels as the unburned control in the 13-yr site. Contrary to previous studies, we did not find a consistent effect of plant cover type on soil biogeochemical processes in mid-successional (10-50 yr) forest soils. Rather, the 44-yr reduction in soil organic carbon (C) quantity correlated positively with dampened C cycling processes. Our results show the drastic and long-term implication of ecologically novel, high-severity fire on soil biogeochemistry and underscore the need for long-term fire ecological experiments

Microwave Continuum Emission and Dense Gas Tracers in NGC 3627: Combining Jansky VLA and ALMA Observations

We present Karl G. Jansky Very Large Array (VLA) Ka band (33 GHz) and Atacama Large Millimeter Array (ALMA) Band 3 (94.5 GHz) continuum images covering the nucleus and two extranuclear star-forming regions within the nearby galaxy NGC 3627 (M 66), observed as part of the Star Formation in Radio Survey (SFRS). Both images achieve an angular resolution of $\lesssim$2\arcsec, allowing us to map the radio spectral indices and estimate thermal radio fractions at a linear resolution of $\lesssim$90 pc at the distance of NGC 3627. The thermal fraction at 33 GHz reaches unity at and around the peaks of each HII region; we additionally observed the spectral index between 33 and 94.5 GHz to become both increasingly negative and positive away from the peaks of the HII regions, indicating an increase of non-thermal extended emission from diffusing cosmic-ray electrons and the possible presence of cold dust, respectively. While the ALMA observations were optimized for collecting continuum data, they also detected line emission from the $J=1\rightarrow0$ transitions of HCN and HCO$^{+}$. The peaks of dense molecular gas traced by these two spectral lines are spatially offset from the peaks of the 33 and 94.5 GHz continuum emission for the case of the extranuclear star-forming regions, indicating that our data reach an angular resolution at which one can spatially distinguish sites of recent star formation from the sites of future star formation. Finally, we find trends of decreasing dense gas fraction and velocity dispersion with increasing star formation efficiency among the three regions observed, indicating that the dynamical state of the dense gas, rather than its abundance, plays a more significant role in the star formation process.Comment: 9 pages, 5 figures, accepted for publication in Ap

Tablet PCs in schools: Case study report: A report for Becta by the Open University

The publication provides an analysis of twelve case studies involving schools in England that were using Tablet PCs. The analysis is complemented by brief individual reports describing aspects of how each of these schools was using Tablet PCs

Review of methods applicable to the assessment of mold exposure to children.

This article presents discussion of the assessment of the exposure of children to fungi, substances derived from fungi, and the environmental conditions that may lead to exposure. The principles driving investigations of fungal contamination and subsequent exposure are presented as well as guidelines for conducting these investigations. A comprehensive description of available research sampling and analysis techniques is also presented