3,117 research outputs found
Remarks on preparation of indandione detection reagents
A modified Claisen condensation with sliced sodium at a higher temperature was recommended for the production of ungranulated charcoal. A new ninhydrin production method by oxidation of benzaldiketohydrinden using available reagents was tried and was unsuccessful. Triketohydrinden was obtained by boiling ninhydrin in acetic acid anhydrides
Electronic properties of very thin native SiO2/a-Si:H interfaces and their comparison with those prepared by both dielectric barrier discharge oxidation at atmospheric pressure and by chemical oxidation
The contribution deals with electronic properties of thin oxide/amorphous hydrogenated silicon (a-Si:H) measured by capacitance-voltage (C-V) and charge version of deep level transient spectroscopy (Q-DLTS). The interest was focused on the studies of the interface properties of very thin dielectrics formed by dielectric barrier discharge (DBD) or natively on the a-Si:H layer. These properties were compared with those of oxide layers prepared by chemical oxidation in HNO3. The DBD was used for the preparation of a very thin SiO2 layer on a-Si:H for the first time to our knowledge. Preliminary electrical measurements confirmed that a very low interface states density was detected in the case of the native oxide/a-Si:H and DBD oxide/a-Si:H
Steady state evaluation of distributed secondary frequency control strategies for microgrids in the presence of clock drifts
Secondary frequency control, i.e., the task of restoring the network frequency to its nominal value following a disturbance, is an important control objective in microgrids. In the present paper, we compare distributed secondary control strategies with regard to their behaviour under the explicit consideration of clock drifts. In particular we show that, if not considered in the tuning procedure, the presence of clock drifts may impair an accurate frequency restoration and power sharing. As a consequence, we derive tuning criteria such that zero steady state frequency deviation and power sharing is achieved even in the presence of clock drifts. Furthermore, the effects of clock drifts of the individual inverters on the different control strategies are discussed analytically and in a numerical case study
Modelling, Analysis and Experimental Validation of Clock Drift Effects in Low-Inertia Power Systems
Clock drift in digital controllers is of great relevance in many applications. Since almost all real clocks exhibit drifts, this applies in particular to networks composed of several individual units, each of which being operated with its individual clock. In the present paper, we demonstrate via extensive experiments on a microgrid in the megawatt range that clock drifts may impair frequency synchronization in low-inertia power systems. The experiments also show that-in the absence of a common clock-the standard model of an inverter as an ideal voltage source does not capture this phenomenon. As a consequence, we derive a suitably modified model of an inverter-interfaced unit that incorporates the phenomenon of clock drifts. By using the derived model, we investigate the effects of clock drifts on the performance of droop-controlled grid-forming inverters with regard to frequency synchronization and active power sharing. The modeling and analysis is validated via extensive experiments on a microgrid in the megawatt range
The Increase of Epidermal Imidazoleacrylic Acid Following Insolation
It has been confirmed, by electron microscopy, that suction blisters detach the epidermis at the dermo-epidermal junction. Inter- and intracellular vacuolization was observed in some of the specimens. On the basis of a study comprising 15 subjects (12 males and 3 females), it was concluded that urocanic acid in the epidermis (suction blister skin) of the upper arm increased 9–11 days following insolation in comparison with specimens situated at an exactly symmetrical site of the control (non-irradiated) arm. This difference was significant in terms of μg urocanic acid per mg dry weight at a 95% level of probability and in terms of μg per cm2 of blister base at a 99% level (t-test for paired values). In two of the subjects other time intervals after insolation were also studied and an increase of epidermal urocanic acid level was noted. Dry weights of epidermis (mg per cm2) on the irradiated and control side (9–11 days following insolation) did not differ significantly in the group of 15 subjects. Significant increase due to insolation was only demonstrated when the values were divided by control values obtained for the respective arms 2 months before the experiment. Histidine ammonia-lyase activity was estimated in 8 subjects. The increase on the irradiated side on the 9–11th day after unilateral insolation was not significant
ForestGEO Dead Wood Census Protocol
After stems die, the wood persists in the ecosystem, either as standing deadwood or woody debris on the ground. Deadwood plays an important role in forest ecosystems, providing significantly different substrate, nutrient source, and microclimate to seedlings as well as habitat to vertebrates and invertebrates. Measurements of dead material on the forest floor can be used to more completely estimate biomass, carbon pools, and carbon fluxes. These methods continue the philosophy of the ForestGEO demography data by tracking the status of individual woody stems after mortality and thereby extending observations to the entire period each woody stem exists in the forest
Tunneling broadening of vibrational sidebands in molecular transistors
Transport through molecular quantum dots coupled to a single vibration mode
is studied in the case with strong coupling to the leads. We use an expansion
in the correlation between electrons on the molecule and electrons in the leads
and show that the tunneling broadening is strongly suppressed by the
combination of the Pauli principle and the quantization of the oscillator. As a
consequence the first Frank-Condon step is sharper than the higher order ones,
and its width, when compared to the bare tunneling strength, is reduced by the
overlap between the groundstates of the displaced and the non-displaced
oscillator.Comment: 8 pages, 3 figures. PRB, in pres
Secondary gas in debris discs released following the decay of long-lived radioactive nuclides, catastrophic or resurfacing collisions
Kuiper-like belts of planetesimals orbiting stars other than the Sun are most
commonly detected from the thermal emission of small dust produced in
collisions. Emission from gas, most notably CO, highlights the cometary nature
of these planetesimals. Here we present models for the release of gas from
comet-like bodies in these belts, both due to their thermophysical evolution,
most notably the decay of long-lived radioactive nuclides and collisional
evolution, including catastrophic and gentler resurfacing collisions. We show
that the rate of gas release is not proportional to the rate of dust release,
if non-catastrophic collisions or thermal evolution dominate the release of CO
gas. In this case, care must be taken when inferring the composition of comets.
Non-catastrophic collisions dominate the gas production at earlier times than
catastrophic collisions, depending on the properties of the planetesimal belt.
We highlight the importance of the thermal evolution of comets, including
crucially the decay of long-lived radioactive nuclides, as a source of CO gas
around young (<50Myr) planetary systems, if large (10-100s kms) planetesimals
are present.Comment: Submitted to MNRAS, 16 page
Study of the microstructure resulting from brazed aluminium materials used in heat exchangers
Re-solidification of AA4343 cladding after brazing as well as the related precipitation in the modified AA3003 core material have been investigated. Analysis of the re-solidified material showed that partial dissolution of the core alloy occurs in both the brazing joints and away of them. Far from the brazing joints, the dissolution is, however, limited and diffusion of silicon from the liquid into the core material leads to solid-state precipitation in the so-called “band of dense precipitates” (BDP). On the contrary, the dissolution is enhanced in the brazing joint to such an extent that no BDP could be observed. The intermetallic phases present in the resolidified areas as well as in the core material have been analyzed and found to be mainly cubic alpha-Al(Mn,Fe)Si. These results were then compared to predictions made with available phase diagram information
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