870 research outputs found

    Programa de crecimiento personal y de formación académica a estudiantes de psicología.

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    Identificar las áreas prioritarias para potenciar el crecimiento; medir la efectividad a través de la evaluación por parte de los participantes. Basando este programa en la Psicología Humanista, concretamente en la teoría de Carl Rogers, quien nos presenta una concepción positiva y optimista de la persona y en su capacidad para auto realizarse. La revisión de la historia de vida propone examinar la historia personal con un objetivo determinado para que de esta manera se convierta en una herramienta terapéutica a nivel individual y grupal; para esto se utilizan matrices de trabajo elaboradas en base la organización “Personalidad y Relaciones Humanas” (PRH). Este estudio plantea las siguientes interrogantes: ¿Qué elementos incluye un programa de crecimiento personal dirigido a estudiantes de psicología y cuáles son las áreas a trabajar en este programa de crecimiento?, y ¿qué resultados se obtienen de la evaluación del programa de crecimiento? Se utilizó la técnica de muestreo aleatorio trabajando con un grupo de estudiantes de cuarto y quinto año de la Licenciatura de Psicología que realizaron su práctica en el Centro de Desarrollo Psicológico Comunitario “Depsic”, ubicado en la colonia Jocotales del municipio de Chinautla, departamento de Guatemala, con sede en la Escuela Nacional “Marta Bolaños de Prado”. Se presentó a los estudiantes la propuesta de trabajar los talleres de crecimiento como una invitación a crecer personalmente y conocer una alternativa de herramienta terapéutica tomando en cuenta que los psicólogos como promotores de la salud mental necesitan estar en un constante proceso de crecimiento personal integral. Para recabar la información se utilizó la observación y el registro de lo que ocurrió en cada taller. Al final se evaluaron los talleres en relación al beneficio obtenido de los mismos. Al terminar los talleres se evidenció la utilidad de implementar un programa de desarrollo humano basado en la revisión de la historia de vida para beneficio personal y como parte de la formación profesional. Todos los participantes manifestaron sentirse invitados a continuar un proceso de crecimiento personal. Recomienda a la Escuela de Psicología realizar actividades de este tipo en forma sistemática y continua

    Ultrasonographic Estimation of Ventricular Volume in Infants Born Preterm with Posthemorrhagic Ventricular Dilatation: A Nested Substudy of the Randomized Controlled Early Versus Late Ventricular Intervention Study (ELVIS) Trial

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    Objective: To study the potential role of ventricular volume (VV) estimation in the management of posthemorrhagic ventricular dilatation related to the need for ventriculoperitoneal (VP)-shunt insertion and 2-year neurodevelopmental outcome in infants born preterm. Study design: We included 59 patients from the Early vs Late Ventricular Intervention Study from 4 participating centers. VV was manually segmented in 209 3-dimensional ultrasound scans and estimated from 2-dimensional ultrasound linear measurements in a total of 1226 ultrasounds. We studied the association of both linear measurements and VV to the need for VP shunt and 2-year neurodevelopmental outcome in the overall cohort and in the 29 infants who needed insertion of a reservoir. We used general estimating equations to account for repeated measures per individual. Results: Maximum pre-reservoir VV (β coefficient = 0.185, P = .0001) and gestational age at birth (β = −0.338; P = .0001) were related to the need for VP shunt. The estimated optimal single VV measurement cut point of 17 cm3 correctly classified 79.31% with an area under the curve of 0.76 (CI 95% 0.74-0.79). Maximum VV (β = 0.027; P = .012) together with VP shunt insertion (β = 3.773; P = .007) and gestational age (β = −0.273; P = .0001) were related to cognitive outcome at 2 years. Maximum ventricular index and anterior horn width before reservoir insertion were independently associated with the need of VP shunt and the proposed threshold groups in the Early vs Late Ventricular Intervention Study trial were associated with long-term outcome. Conclusions: Pre-reservoir VV measurements were associated with the need for VP-shunt insertion and 2-year cognitive outcome among infants born preterm with posthemorrhagic ventricular dilatation. Trial registration: ISRCTN43171322

    Synergetic improvement of stability and conductivity of hybrid composites formed by PEDOT:PSS and SnO nanoparticles

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    In this work, layered hybrid composites formed by tin oxide (SnO) nanoparticles synthesized by hydrolysis and poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) have been analyzed. Prior to the composite study, both SnO and PEDOT:PSS counterparts were characterized by diverse techniques, such as X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), photoluminescence (PL), atomic force microscopy (AFM), optical absorption and Hall effect measurements. Special attention was given to the study of the stability of the polymer under laser illumination, as well as the analysis of the SnO to SnO_2 oxidation assisted by laser irradiation, for which different laser sources and neutral filters were employed. Synergetic effects were observed in the hybrid composite, as the addition of SnO nanoparticles improves the stability and electrical conductivity of the polymer, while the polymeric matrix in which the nanoparticles are embedded hinders formation of SnO_2. Finally, the Si passivation behavior of the hybrid composites was studied

    Evaluation of the silver species nature in Ag-ITQ2 zeolites by the CO oxidation reaction

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    The authors thank the Spanish Ministry of Economy and Competitiveness through RTI2018-101784-B-I00 (MINECO/FEDER) and SEV-2016-0683 projects for the financial support. We gratefully acknowledge ALBA synchrotron for allocating beamtime (proposal 2015091414) and the CLAESS beamline staff for their help and technical support during our experiment. CG and NB thank the TUW Innovative Project GIP165CDGC. CG, SP, VT, NB and GR are thankful for financial support from the Austrian Science Fund (FWF) through projects DK+ Solids4Fun (W1243) and ComCat (I 1041-N28). I. Lopez Hernandez is grateful to Generalitat Valenciana and European Social Fund for the pre doctoral grant ACIF2017.López-Hernández, I.; García Yago, CI.; Truttmann, V.; Pollit, S.; Barrabés, N.; Rupprechter, G.; Rey Garcia, F.... (2020). Evaluation of the silver species nature in Ag-ITQ2 zeolites by the CO oxidation reaction. 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Chemical Reviews, 118(10), 4981-5079. doi:10.1021/acs.chemrev.7b00776Zhao, J., & Jin, R. (2018). Heterogeneous catalysis by gold and gold-based bimetal nanoclusters. Nano Today, 18, 86-102. doi:10.1016/j.nantod.2017.12.009Zhang, B., Kaziz, S., Li, H., Hevia, M. G., Wodka, D., Mazet, C., … Barrabés, N. (2015). Modulation of Active Sites in Supported Au38(SC2H4Ph)24 Cluster Catalysts: Effect of Atmosphere and Support Material. The Journal of Physical Chemistry C, 119(20), 11193-11199. doi:10.1021/jp512022vZhang, B., Sels, A., Salassa, G., Pollitt, S., Truttmann, V., Rameshan, C., … Barrabés, N. (2018). Ligand Migration from Cluster to Support: A Crucial Factor for Catalysis by Thiolate‐protected Gold Clusters. ChemCatChem, 10(23), 5372-5376. doi:10.1002/cctc.201801474Natarajan, G., Mathew, A., Negishi, Y., Whetten, R. L., & Pradeep, T. (2015). A Unified Framework for Understanding the Structure and Modifications of Atomically Precise Monolayer Protected Gold Clusters. The Journal of Physical Chemistry C, 119(49), 27768-27785. doi:10.1021/acs.jpcc.5b08193Tsukuda, T., & Häkkinen, H. (2015). Introduction. Protected Metal Clusters - From Fundamentals to Applications, 1-7. doi:10.1016/b978-0-08-100086-1.00001-4Zhang, X., Qu, Z., Li, X., Wen, M., Quan, X., Ma, D., & Wu, J. (2010). Studies of silver species for low-temperature CO oxidation on Ag/SiO2 catalysts. Separation and Purification Technology, 72(3), 395-400. doi:10.1016/j.seppur.2010.03.012Kolobova, E., Pestryakov, A., Mamontov, G., Kotolevich, Y., Bogdanchikova, N., Farias, M., … Cortes Corberan, V. (2017). Low-temperature CO oxidation on Ag/ZSM-5 catalysts: Influence of Si/Al ratio and redox pretreatments on formation of silver active sites. Fuel, 188, 121-131. doi:10.1016/j.fuel.2016.10.037Ausavasukhi, A., Suwannaran, S., Limtrakul, J., & Sooknoi, T. (2008). Reversible interconversion behavior of Ag species in AgHZSM-5: XRD, 1H MAS NMR, TPR, TPHE, and catalytic studies. Applied Catalysis A: General, 345(1), 89-96. doi:10.1016/j.apcata.2008.04.026Shi, C., Cheng, M., Qu, Z., & Bao, X. (2005). On the correlation between microstructural changes of Ag-H-ZSM-5 catalysts and their catalytic performances in the selective catalytic reduction of NOx by methane. Journal of Molecular Catalysis A: Chemical, 235(1-2), 35-43. doi:10.1016/j.molcata.2004.10.045Afanasev, D. S., Yakovina, O. A., Kuznetsova, N. I., & Lisitsyn, A. S. (2012). High activity in CO oxidation of Ag nanoparticles supported on fumed silica. Catalysis Communications, 22, 43-47. doi:10.1016/j.catcom.2012.02.014Kolobova, E., Pestryakov, A., Shemeryankina, A., Kotolevich, Y., Martynyuk, O., Tiznado Vazquez, H. J., & Bogdanchikova, N. (2014). Formation of silver active states in Ag/ZSM-5 catalysts for CO oxidation. Fuel, 138, 65-71. doi:10.1016/j.fuel.2014.07.011Royer, S., & Duprez, D. (2010). Catalytic Oxidation of Carbon Monoxide over Transition Metal Oxides. 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A., López, J. M. R., & Boix, A. V. (2013). Study of the Nature and Location of Silver in Ag-Exchanged Mordenite Catalysts. Characterization by Spectroscopic Techniques. The Journal of Physical Chemistry C, 117(48), 25433-25442. doi:10.1021/jp4046269Veronesi, G., Deniaud, A., Gallon, T., Jouneau, P.-H., Villanova, J., Delangle, P., … Michaud-Soret, I. (2016). Visualization, quantification and coordination of Ag+ions released from silver nanoparticles in hepatocytes. Nanoscale, 8(38), 17012-17021. doi:10.1039/c6nr04381jVeronesi, G., Aude-Garcia, C., Kieffer, I., Gallon, T., Delangle, P., Herlin-Boime, N., … Carrière, M. (2015). Exposure-dependent Ag+release from silver nanoparticles and its complexation in AgS2sites in primary murine macrophages. Nanoscale, 7(16), 7323-7330. doi:10.1039/c5nr00353aHudson-Smith, N. V., Clement, P. L., Brown, R. P., Krause, M. O. P., Pedersen, J. A., & Haynes, C. L. (2016). Research highlights: speciation and transformations of silver released from Ag NPs in three species. Environmental Science: Nano, 3(6), 1236-1240. doi:10.1039/c6en90025aShimizu, K., Sugino, K., Kato, K., Yokota, S., Okumura, K., & Satsuma, A. (2007). Formation and Redispersion of Silver Clusters in Ag-MFI Zeolite as Investigated by Time-Resolved QXAFS and UV−Vis. The Journal of Physical Chemistry C, 111(4), 1683-1688. doi:10.1021/jp066995aChen, D., Qu, Z., Shen, S., Li, X., Shi, Y., Wang, Y., … Wu, J. (2011). Comparative studies of silver based catalysts supported on different supports for the oxidation of formaldehyde. Catalysis Today, 175(1), 338-345. doi:10.1016/j.cattod.2011.03.059Schuricht, F., & Reschetilowski, W. (2012). Simultaneous selective catalytic reduction (SCR) of NOx and N2O over Ag/ZSM-5 – Catalytic studies and mechanistic implications. Microporous and Mesoporous Materials, 164, 135-144. doi:10.1016/j.micromeso.2012.07.018Akolekar, D. B., & Bhargava, S. K. (2000). 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    The role of snow in scavenging aerosol particles: A physical-chemical characterization

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    [EN] The below cloud scavenging of aerosols by snow has been analysed in León (NW Spain). Six snow events were registered over the course of one year of study. Ultrafine and accumulation aerosol particles were measured using a scanning mobility particle sizer spectrometer, while hydrometeors were characterized using a disdrometer. Furthermore, the chemical composition of the melted snow-water samples (soluble and insoluble fractions) was analysed. The scavenging coefficient (λ) showed a great variability among events. An effective washing of particles was observed during the first 30 min of snowfall. The mean change in the scavenging efficiency (%ΔC) of particle number concentration (PNC) and λ coefficient during this time interval were: i) nucleation mode: 36.3 % and 3.02 · 10−4 s−1; ii) Aitken mode: 30.4 % and 2.37 · 10−4 s−1 and iii) accumulation mode: 22.4 % and 1.77 · 10−4 s−1. The range of particle sizes that is less efficiently scavenged by snowfall was observed between 400 and 600 nm. When analyzing the whole snow event, an increase of PNC was observed. Two possible explanations underlie this behaviour: it could be caused by changes in air masses or by the resuspension of aerosol particles scavenged by snowflakes upon reaching the ground. A clear relationship was observed between Ca2+, SO42− and NO3− concentrations of aerosol particles before the snow event and the concentrations registered in the melted snow-water. The largest and smallest changes in aerosol number concentrations were caused by snowflakes of 3 and 6 mm in diameter, respectively. The particle size distributions (PSD) were fitted to log-normal distributions and the parameters were compared before and after snowfall.S

    New strategies in laser processing of TCOs for light management improvement in thin-film silicon solar cells

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    Light confinement strategies play a crucial role in the performance of thin-film (TF) silicon solar cells. One way to reduce the optical losses is the texturing of the transparent conductive oxide (TCO) that acts as the front contact. Other losses arise from the mismatch between the incident light spectrum and the spectral properties of the absorbent material that imply that low energy photons (below the bandgap value) are not absorbed, and therefore can not generate photocurrent. Up-conversion techniques, in which two sub-bandgap photons are combined to give one photon with a better matching with the bandgap, were proposed to overcome this problem. In particular, this work studies two strategies to improve light management in thin film silicon solar cells using laser technology. The first one addresses the problem of TCO surface texturing using fully commercial fast and ultrafast solid state laser sources. Aluminum doped Zinc Oxide (AZO) samples were laser processed and the results were optically evaluated by measuring the haze factor of the treated samples. As a second strategy, laser annealing experiments of TCOs doped with rare earth ions are presented as a potential process to produce layers with up-conversion properties, opening the possibility of its potential use in high efficiency solar cells

    Characterization and immobilization of engineered sialidases from <em>Trypanosoma rangeli</em> for transsialylation

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    A sialidase (EC 3.2.1.18; GH 33) from non-pathogenic Trypanosoma rangeli has been engineered with the aim of improving its transsialylation activity. Recently, two engineered variants containing 15 and 16 amino acid substitutions, respectively, were found to exhibit significantly improved transsialylation activity: both had a 14 times higher ratio between transsialylation and hydrolysis products compared to the first reported mutant TrSA5mut. In the current work, these two variants, Tr15 and Tr16, were characterized in terms of pH optimum, thermal stability, effect of acceptor-to-donor ratio, and acceptor specificity for transsialylation using casein glycomacropeptide (CGMP) as sialyl donor and lactose or other human milk oligosaccharide core structures as acceptors. Both sialidase variants exhibited pH optima around pH 4.8. Thermal stability of each enzyme was comparable to that of previously developed T. rangeli sialidase variants and higher than that of the native transsialidase from T. cruzi (TcTS). As for other engineered T. rangeli sialidase variants and TcTS, the acceptor specificity was broad: lactose, galactooligosaccharides (GOS), xylooligosaccharides (XOS), and human milk oligosaccharide structures lacto-N-tetraose (LNT), lacto-N-fucopentaose (LNFP V), and lacto-N-neofucopentaose V (LNnFP V) were all sialylated by Tr15 and Tr16. An increase in acceptor-to-donor ratio from 2 to 10 had a positive effect on transsialylation. Both enzymes showed high preference for formation α(2,3)-linkages at the non-reducing end of lactose in the transsialylation. Tr15 was the most efficient enzyme in terms of transsialylation reaction rates and yield of 3’-sialyllactose. Finally, Tr15 was immobilized covalently on glyoxyl-functionalized silica, leading to a 1.5-fold increase in biocatalytic productivity (mg 3’-sialyllactose per mg enzyme) compared to free enzyme after 6 cycles of reuse. The use of glyoxyl-functionalized silica proved to be markedly better for immobilization than silica functionalized with (3-aminopropyl)triethoxysilane (APTES) and glutaraldehyde, which resulted in a biocatalytic productivity which was less than half of that obtained with free enzyme
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