Lock-in transition of charge density waves in quasi-one-dimensional conductors: reinterpretation of McMillan's theory

We investigated the lock-in transition of charge density waves (CDWs) in quasi-one-dimensional conductors, based on McMillan's free energy. The higher-order umklapp terms play an essential role in this study. McMillan's theory was extended by Nakanishi and Shiba in order to treat multiple CDW vectors. Although their theories were aimed at understanding CDWs in quasi-two-dimensional conductors, we applied them to the quasi-one-dimensional conductors, including K$_{0.3}$MoO$_3$, NbSe$_3$, and $m$-TaS$_3$, and confirmed its validity for these cases. Then we discussed our previous experimental result of $o$-TaS$_3$, which revealed the coexistence of commensurate and incommensurate states. We found that the coexistence of multiple CDW vectors is essential for the lock-in transition to occur in $o$-TaS$_3$. The even- and odd-order terms in the free energy play roles for amplitude development and phase modulation, respectively. Moreover, consideration of the condition of being commensurate CDWs allowed us to relate it with that of the weak localization in random media.Comment: 12 pages, 3 figure

Nonlocal transport in the charge density waves of oo-TaS3_3

We studied the nonlocal transport of a quasi-one dimensional conductor $o$-TaS$_3$. Electric transport phenomena in charge density waves include the thermally-excited quasiparticles, and collective motion of charge density waves (CDW). In spite of its long-range correlation, the collective motion of a CDW does not extend far beyond the electrodes, where phase slippage breaks the correlation. We found that nonlocal voltages appeared in the CDW of $o$-TaS$_3$, both below and above the threshold field for CDW sliding. The temperature dependence of the nonlocal voltage suggests that the observed nonlocal voltage originates from the CDW even below the threshold field. Moreover, our observation of nonlocal voltages in both the pinned and sliding states reveals the existence of a carrier with long-range correlation, in addition to sliding CDWs and thermally-excited quasiparticles.Comment: 8 pages, 4 figure

Successful treatment of mucosa-associated lymphoid tissue lymphoma in a patient with gastric and rectal lesions with metachronous and ectopic development

A 75-year-old female, who had an abnormal stomach x-ray finding, was admitted to the hospital for further examination and therapy. Upper GI endoscopy showed reddish and swollen folds on the greater curvature of the gastric body and a biopsy was of this lesion revealed malignant lymphoma (small cell type or mucosa-associated lymphoid tissue (MALT) lymphoma suspected). The patient was infected with Helicobacter pylori (H. pylori), however, in response to the patient's wishes, a total gastrectomy, omentectomy and splenectomy were performed and the histological diagnosis was gastric MALT lymphoma. Two courses of CHOP therapy (cyclophosphamide (CPM) 750 mg/m2/day, day 1, adriamycin (ADM) 50 mg/m2/day, day 1, vincristine sulfate (VCR) 1.4 mg/m2/day, day 1, prednisolone 100 mg/body, day 1–5) were administered as adjuvant chemotherapy. A colonoscopic examination performed about 4.5 yr after the operation revealed rectal submucosal tumors and the biopsied specimens were diagnosed as malignant lymphoma. A transanal focal resection was performed and the histological diagnosis was metachronous and ectopic development of MALT lymphoma. The histological finding was similar to the gastric lesion. About 4 and 7 yr after the first development of rectal MALT lymphoma, MALT lymphomas developed repeatedly in the rectal lesion, however, these were resected repeatedly and no developmenthas occurred during the past two years. This report presents a very rare case of metachronous and ectopic MALT lymphoma development in the gastric and rectal lesions

Intelligent Chiral Sensing Based on Supramolecular and Interfacial Concepts

Of the known intelligently-operating systems, the majority can undoubtedly be classed as being of biological origin. One of the notable differences between biological and artificial systems is the important fact that biological materials consist mostly of chiral molecules. While most biochemical processes routinely discriminate chiral molecules, differentiation between chiral molecules in artificial systems is currently one of the challenging subjects in the field of molecular recognition. Therefore, one of the important challenges for intelligent man-made sensors is to prepare a sensing system that can discriminate chiral molecules. Because intermolecular interactions and detection at surfaces are respectively parts of supramolecular chemistry and interfacial science, chiral sensing based on supramolecular and interfacial concepts is a significant topic. In this review, we briefly summarize recent advances in these fields, including supramolecular hosts for color detection on chiral sensing, indicator-displacement assays, kinetic resolution in supramolecular reactions with analyses by mass spectrometry, use of chiral shape-defined polymers, such as dynamic helical polymers, molecular imprinting, thin films on surfaces of devices such as QCM, functional electrodes, FET, and SPR, the combined technique of magnetic resonance imaging and immunoassay, and chiral detection using scanning tunneling microscopy and cantilever technology. In addition, we will discuss novel concepts in recent research including the use of achiral reagents for chiral sensing with NMR, and mechanical control of chiral sensing. The importance of integration of chiral sensing systems with rapidly developing nanotechnology and nanomaterials is also emphasized