A search for interstellar anthracene toward the Perseus anomalous microwave emission region

We report the discovery of a new broad interstellar (or circumstellar) band at 7088.8 +- 2.0 \AA coincident to within the measurement uncertainties with the strongest band of the anthracene cation (C$_{14}$H$_{10}$$^+$) as measured in gas-phase laboratory spectroscopy at low temperatures (Sukhorukov et al.2004). The band is detected in the line of sight of star Cernis 52, a likely member of the very young star cluster IC 348, and is probably associated with cold absorbing material in a intervening molecular cloud of the Perseus star forming region where various experiments have recently detected anomalous microwave emission. From the measured intensity and available oscillator strength we find a column density of N$_{an^+}$= 1.1(+-0.4) x 10$^{13}$ cm$^{-2}$ implying that ~0.008% of the carbon in the cloud could be in the form of C$_{14}$H$_{10}$$^+$. A similar abundance has been recently claimed for the naphthalene cation (Iglesias-Groth et al. 2008) in this cloud. This is the first location outside the Solar System where specific PAHs are identified. We report observations of interstellar lines of CH and CH$^+$ that support a rather high column density for these species and for molecular hydrogen. The strength ratio of the two prominent diffuse interstellar bands at 5780 and 5797 \AA suggests the presence of a ``zeta'' type cloud in the line of sight (consistent with steep far-UV extinction and high molecular content). The presence of PAH cations and other related hydrogenated carbon molecules which are likely to occur in this type of clouds reinforce the suggestion that electric dipole radiation from fast spinning PAHs is responsible of the anomalous microwave emission detected toward Perseus.Comment: Accepted for publication in Monthly Notices of the Royal Astronomical Societ

The Chemical Composition of Cernis 52 (BD+31 640)

We present an abundance analysis of the star Cernis 52 in whose spectrum we recently reported the napthalene cation in absorption at 6707.4 {\AA}. This star is on a line of sight to the Perseus molecular complex. The analysis of high-resolution spectra using a chi^2-minimization procedure and a grid of synthetic spectra provides the stellar parameters and the abundances of O, Mg, Si, S, Ca, and Fe. The stellar parameters of this star are found to be T_{eff} = 8350 +- 200 K, logg= 4.2 +- 0.4 dex. We derived a metallicity of [Fe/H] = -0.01 +- 0.15. These stellar parameters are consistent with a star of $\sim 2$ \Msun in a pre-main-sequence evolutionary stage. The stellar spectrum is significantly veiled in the spectral range 5150-6730 {\AA} up to almost 55 per cent of the total flux at 5150 {\AA} and decreasing towards longer wavelengths. Using Johnson-Cousins and 2MASS photometric data, we determine a distance to Cernis 52 of 231$^{+135}_{-85}$ pc considering the error bars of the stellar parameters. This determination places the star at a similar distance to the young cluster IC 348. This together with its radial velocity, v_r=13.7+-1 km/s, its proper motion and probable young age support Cernis 52 as a likely member of IC 348. We determine a rotational velocity of v\sin i=65 +- 5 km/s for this star. We confirm that the stellar resonance line of \ion{Li}{1} at 6707.8 {\AA} is unable to fit the broad feature at 6707.4 {\AA}. This feature should have a interstellar origin and could possibly form in the dark cloud L1470 surrounding all the cluster IC 348 at about the same distance.Comment: Accepted for publication in The Astrophysical Journa

Evidence for the naphthalene cation in a region of the interstellar medium with anomalous microwave emission

We report high resolution spectroscopy of the moderately reddened (A$_V$=3) early type star Cernis 52 located in a region of the Perseus molecular cloud complex with anomalous microwave emission. In addition to the presence of the most common diffuse interstellar bands (DIBs) we detect two new interstellar or circumstellar bands coincident to within 0.01% in wavelength with the two strongest bands of the naphthalene cation (C$_{10}$H$_{8}^+$) as measured in gas-phase laboratory spectroscopy at low temperatures and find marginal evidence for the third strongest band. Assuming these features are caused by the naphthalene cation, from the measured intensity and available oscillator strengths we find that 0.008 % of the carbon in the cloud could be in the form of this molecule. We expect hydrogen additions to cause hydronaphthalene cations to be abundant in the cloud and to contribute via electric dipole radiation to the anomalous microwave emission. The identification of new interstellar features consistent with transitions of the simplest polycyclic aromatic hydrocarbon adds support to the hypothesis that this type of molecules are the carriers of both diffuse interstellar bands and anomalous microwave emission.Comment: Accepted for publication in The Astrophysical Journa

Chaotic exchange of solid material between planetary systems: implications for lithopanspermia

We examine a low energy mechanism for the transfer of meteoroids between two planetary systems embedded in a star cluster using quasi-parabolic orbits of minimal energy. Using Monte Carlo simulations, we find that the exchange of meteoroids could have been significantly more efficient than previously estimated. Our study is relevant to astrobiology as it addresses whether life on Earth could have been transferred to other planetary systems in the solar system's birth cluster and whether life on Earth could have been transferred here from beyond the solar system. In the solar system, the timescale over which solid material was delivered to the region from where it could be transferred via this mechanism likely extended to several hundred million years (as indicated by the 3.8-4.0 Ga epoch of the Late Heavy Bombardment). This timescale could have overlapped with the lifetime of the Solar birth cluster (~100-500 Myr). Therefore, we conclude that lithopanspermia is an open possibility if life had an early start. Adopting parameters from the minimum mass solar nebula, considering a range of planetesimal size distributions derived from observations of asteroids and Kuiper Belt Objects and theoretical coagulation models, and taking into account Oort Cloud formation models, the expected number of bodies with mass > 10 kg that could have been transferred between the Sun and its nearest cluster neighbor could be of the order of 1E14-3E16, with transfer timescales of 10s Myr. We estimate that of the order of 3E8 x l(km) could potentially be life-bearing, where l(km) is the depth of the Earth crust in km that was ejected as the result of the early bombardment.Comment: Accepted by Astrobiology. Submitted: Sep. 21, 2011. Accepted: May 2, 2012. 39 pages. 21 figures. arXiv admin note: substantial text overlap with arXiv:0808.326

The formation of fullerenes: clues from new C60, C70, and (possible) planar C24 detections in Magellanic Cloud Planetary Nebulae

We present ten new Spitzer detections of fullerenes in Magellanic Cloud Planetary Nebulae, including the first extragalactic detections of the C70 molecule. These new fullerene detections together with the most recent laboratory data permit us to report an accurate determination of the C60 and C70 abundances in space. Also, we report evidence for the possible detection of planar C24 in some of our fullerene sources, as indicated by the detection of very unusual emission features coincident with the strongest transitions of this molecule at ~6.6, 9.8, and 20 um. The infrared spectra display a complex mix of aliphatic and aromatic species such as hydrogenated amorphous carbon grains (HACs), PAH clusters, fullerenes, and small dehydrogenated carbon clusters (possible planar C24). The coexistence of such a variety of molecular species supports the idea that fullerenes are formed from the decomposition of HACs. We propose that fullerenes are formed from the destruction of HACs, possibly as a consequence of shocks driven by the fast stellar winds, which can sometimes be very strong in transition sources and young PNe. This is supported by the fact that many of our fullerene-detected PNe show altered [NeIII]/[NeII] ratios suggestive of shocks as well as P-Cygni profiles in their UV lines indicative of recently enhanced mass loss.Comment: Accepted for publication in The Astrophysical Journal Letters (16 pages, 2 Tables and 3 figures

Formation of unsaturated hydrocarbons in interstellar ice analogs by cosmic rays

The formation of double and triple C-C bonds from the processing of pure c-C6H12 (cyclohexane) and mixed H2O:NH3:c-C6H12 (1:0.3:0.7) ices by highly-charged, and energetic ions (219 MeV O^{7+} and 632 MeV Ni^{24+}) is studied. The experiments simulate the physical chemistry induced by medium-mass and heavy-ion cosmic rays in interstellar ices analogs. The measurements were performed inside a high vacuum chamber at the heavy-ion accelerator GANIL (Grand Accel\'erat\'eur National d'Ions Lourds) in Caen, France. The gas samples were deposited onto a polished CsI substrate previously cooled to 13 K. In-situ analysis was performed by a Fourier transform infrared (FTIR) spectrometry at different ion fluences. Dissociation cross section of cyclohexane and its half-life in astrophysical environments were determined. A comparison between spectra of bombarded ices and young stellar sources indicates that the initial composition of grains in theses environments should contain a mixture of H2O, NH3, CO (or CO2), simple alkanes, and CH3OH. Several species containing double or triple bounds were identified in the radiochemical products, such as hexene, cyclohexene, benzene, OCN-, CO, CO2, as well as several aliphatic and aromatic alkenes and alkynes. The results suggest an alternative scenario for the production of unsaturated hydrocarbons and possibly aromatic rings (via dehydrogenation processes) in interstellar ices induced by cosmic ray bombardment.Comment: 14 pages, 10 figures, 4 tables. Accepted to be published in MNRA