3,477 research outputs found
Source apportionment of carbonaceous chemical species to fossil fuel combustion, biomass burning and biogenic emissions by a coupled radiocarbon-levoglucosan marker method
An intensive aerosol measurement and sample collection campaign was conducted in central Budapest in a mild winter for 2 weeks. The online instruments included an FDMS-TEOM, RT-OC/EC analyser, DMPS, gas pollutant analysers and meteorological sensors. The aerosol samples were collected on quartz fibre filters by a low-volume sampler using the tandem filter method. Elemental carbon (EC), organic carbon (OC), levoglucosan, mannosan, galactosan, arabitol and mannitol were determined, and radiocarbon analysis was performed on the aerosol samples. Median atmospheric concentrations of EC, OC and PM2.5 mass were 0.97, 4.9 and 25 mu g m(-3), respectively. The EC and organic matter (1.6 x OC) accounted for 4.8 and 37 %, respectively, of the PM2.5 mass. Fossil fuel (FF) combustion represented 36% of the total carbon (TC = EC + OC) in the PM2.5 size fraction. Biomass burning (BB) was a major source (40 %) for the OC in the PM2.5 size fraction, and a substantial source (11 %) for the PM10 mass. We propose and apply here a novel, straightforward, coupled radiocarbon-levoglucosan marker method for source apportionment of the major carbonaceous chemical species. The contributions of EC and OC from FF combustion (ECFF and OCFF to the TC were 11.0 and 25 %, respectively, EC and OC from BB (ECBB and OCBB were responsible for 5.8 and 34 %, respectively, of the TC, while the OC from biogenic sources (OCBIO made up 24% of the TC. The overall relative uncertainty of the OCBIO and OCBB contributions was assessed to be up to 30 %, while the relative uncertainty for the other apportioned species is expected to be below 20 %. Evaluation of the apportioned atmospheric concentrations revealed some of their important properties and relationships among them. ECFF and OCFF were associated with different FF combustion sources. Most ECFF was emitted by vehicular road traffic, while the contribution of non-vehicular sources such as domestic and industrial heating or cooking using gas, oil or coal to OCFF was substantial. The mean contribution of BB to EC particles was smaller by a factor of approximately 2 than that of road traffic. The main formation processes of OCFF, OCBB and OCBIO from volatile organic compounds were jointly influenced by a common factor, which is most likely the atmospheric photochemistry, while primary organic emissions can also be important. Technological improvements and control measures for various BB appliances, together with efficient education and training of their users, in particular on the admissible fuel types, offer an important potential for improving the air quality in Budapest, and likely in other cities as well
Native Speaker Perceptions of Accented Speech: The English Pronunciation of Macedonian EFL Learners
The paper reports on the results of a study that aimed to describe the vocalic and consonantal features of the English pronunciation of Macedonian EFL learners as perceived by native speakers of English and to find out whether native speakers who speak different standard variants of English perceive the same segments as non-native. A specially designed computer web application was employed to gather two types of data: a) quantitative (frequency of segment variables and global foreign accent ratings on a 5-point scale), and b) qualitative (open-ended questions). The result analysis points out to three most frequent markers of foreign accent in the English speech of Macedonian EFL learners: final obstruent devoicing, vowel shortening and substitution of English dental fricatives with Macedonian dental plosives. It also reflects additional phonetic aspects poorly explained in the available reference literature such as allophonic distributional differences between the two languages and intonational mismatch
Particle Motion in Rapidly Oscillating Potentials: The Role of the Potential's Initial Phase
Rapidly oscillating potentials with a vanishing time average have been used
for a long time to trap charged particles in source-free regions. It has been
argued that the motion of a particle in such a potential can be approximately
described by a time independent effective potential, which does not depend upon
the initial phase of the oscillating potential. However, here we show that the
motion of a particle and its trapping condition significantly depend upon this
initial phase for arbitrarily high frequencies of the potential's oscillation.
We explain this novel phenomenon by showing that the motion of a particle is
determined by the effective potential stated in the literature only if its
initial conditions are transformed according to a transformation which we show
to significantly depend on the potential's initial phase for arbitrarily high
frequencies. We confirm our theoretical findings by numerical simulations.
Further, we demonstrate that the found phenomenon offers new ways to manipulate
the dynamics of particles which are trapped by rapidly oscillating potentials.
Finally, we propose a simple experiment to verify the theoretical findings of
this work.Comment: 9 pages, 8 figures, published in PR
Attosecond investigation of extreme-ultraviolet multi-photon multi-electron ionization
Multi-electron dynamics in atoms and molecules very often occur on sub- to few-femtosecond time scales. The available intensities of extreme-ultraviolet (XUV) attosecond pulses have previously allowed the time-resolved investigation of two-photon, two-electron interactions. Here we study double and triple ionization of argon atoms involving the absorption of up to five XUV photons using a pair of intense attosecond pulse trains (APTs). By varying the time delay between the two APTs with attosecond precision and the spatial overlap with nanometer precision, we obtain information on complex nonlinear multi-photon ionization pathways. Our experimental and numerical results show that Ar2+ is predominantly formed by a sequential two-photon process, whereas the delay dependence of the Ar3+ ion yield exhibits clear signatures of the involvement of a simultaneous two-photon absorption process. Our experiment suggests that it is possible to investigate multi-electron dynamics using attosecond pulses for both pumping and probing the dynamics
Attosecond investigation of extreme-ultraviolet multi-photon multi-electron ionization
Multi-electron dynamics in atoms and molecules very often occur on sub- to few-femtosecond time scales. The available intensities of extreme-ultraviolet (XUV) attosecond pulses have previously allowed the time-resolved investigation of two-photon, two-electron interactions. Here we study double and triple ionization of argon atoms involving the absorption of up to five XUV photons using a pair of intense attosecond pulse trains (APTs). By varying the time delay between the two APTs with attosecond precision and the spatial overlap with nanometer precision, we obtain information on complex nonlinear multi-photon ionization pathways. Our experimental and numerical results show that Ar2+ is predominantly formed by a sequential two-photon process, whereas the delay dependence of the Ar3+ ion yield exhibits clear signatures of the involvement of a simultaneous two-photon absorption process. Our experiment suggests that it is possible to investigate multi-electron dynamics using attosecond pulses for both pumping and probing the dynamics
A Study of Bus Stop Accessibility: Public Health Students Working in Partnership with the Center for Independent Living
Over 54 million U.S. citizens report living with at least one disability. The Americans with Disabilities Act stipulates legislation that prohibits the discrimination of persons on the basis of disability. Rather than riding the bus in areas that offer a fixed-route bus system, individuals with disabilities often rely on expensive and limited paratransit services, or on family and friends. It has been proposed that with improvements in bus accessibility, riders with disabilities could use the fixed-route system more often and increase their options for independence and community participation. During their 2008 spring semester, participants in the University of Florida College of Public Health and Health Professions’ course, Assessment and Surveillance, partnered with the Center for Independent Living (CIL) of North Central Florida to conduct an accessibility study of the Gainesville, Florida fixed-route bus system. Students focused on factors that make bus stops user-friendly for persons with disabilities. This paper presents the rationale, methods, and findings from this accessibility study and efforts undertaken to forge a mutually beneficial partnership among UF-PHHP students and the CIL
Direct Observation of Propagating Gigahertz Coherent Guided Acoustic Phonons in Free Standing Single Copper Nanowires
We report on gigahertz acoustic phonon waveguiding in free-standing single
copper nanowires studied by femtosecond transient reflectivity measurements.
The results are discussed on the basis of the semianalytical resolution of the
Pochhammer and Chree equation. The spreading of the generated Gaussian wave
packet of two different modes is derived analytically and compared with the
observed oscillations of the sample reflectivity. These experiments provide a
unique way to independently obtain geometrical and material characterization.
This direct observation of coherent guided acoustic phonons in a single
nano-object is also the first step toward nanolateral size acoustic transducer
and comprehensive studies of the thermal properties of nanowires
Linear Paul trap design for an optical clock with Coulomb crystals
We report on the design of a segmented linear Paul trap for optical clock
applications using trapped ion Coulomb crystals. For an optical clock with an
improved short-term stability and a fractional frequency uncertainty of 10^-18,
we propose 115In+ ions sympathetically cooled by 172Yb+. We discuss the
systematic frequency shifts of such a frequency standard. In particular, we
elaborate on high precision calculations of the electric radiofrequency field
of the ion trap using the finite element method. These calculations are used to
find a scalable design with minimized excess micromotion of the ions at a level
at which the corresponding second- order Doppler shift contributes less than
10^-18 to the relative uncertainty of the frequency standard
A comment on black hole entropy or does Nature abhor a logarithm?
There has been substantial interest, as of late, in the quantum-corrected
form of the Bekenstein-Hawking black hole entropy. The consensus viewpoint is
that the leading-order correction should be a logarithm of the horizon area;
however, the value of the logarithmic prefactor remains a point of notable
controversy. Very recently, Hod has employed statistical arguments that
constrain this prefactor to be a non-negative integer. In the current paper, we
invoke some independent considerations to argue that the "best guess" for the
prefactor might simply be zero. Significantly, this value complies with the
prior prediction and, moreover, seems suggestive of some fundamental symmetry.Comment: 10 pages and Revtex; (v2) imperative title change and added one
reference; (v3) minor content and style changes throughout; 7 new citations;
(v4) 8 new citations, an addendum and other minor changes; (v5) yet more
references, some points clarified, and a recent criticism is addressed
(addendum 2
Experimental Determination of the Characteristics of a Positron Source Using Channeling
Numerical simulations and `proof of principle' experiments showed clearly the
interest of using crystals as photon generators dedicated to intense positron
sources for linear colliders. An experimental investigation, using a 10 GeV
secondary electron beam, of the SPS-CERN, impinging on an axially oriented
thick tungsten crystal, has been prepared and operated between May and August
2000. After a short recall on the main features of positron sources using
channeling in oriented crystals, the experimental set-up is described. A
particular emphasis is put on the positron detector made of a drift chamber,
partially immersed in a magnetic field. The enhancement in photon and positron
production in the aligned crystal have been observed in the energy range 5 to
40 GeV, for the incident electrons, in crystals of 4 and 8 mm as in an hybrid
target. The first results concerning this experiment are presented hereafter.Comment: 3 pages, 6 figures, submitted to Linac200
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