SubcriticalWater – a Perspective ReactionMedia for Biomass Processing to Chemicals: Study on Cellulose Conversion as aModel for Biomass

Biomass and water are recognized as a key renewable feedstock in sustainable production of chemicals, fuels and energy. Subcritical water (SubCW), or commonly referred as hot compressed water (HCW), is the water above boiling and below critical point (CP; 374 °C, 22.1 MPa). It has gained great attention in the last few decades as a green, cheap, and nontoxic reagent for conversion of biomass into valuable chemicals. In this paper, hydrothermal reactions of cellulose, as the model biomass substance, with subcritical water at mild temperature and pressure regimes have been studied. The experiments were done in a batch reactor in the temperature range of 220 ° – 300 °C. The main products distributed in liquid, gaseous and solid phase were separated and quantified. The conversions to each group of products were found strongly dependent on the temperature and residence time

Helical edge states in multiple topological mass domains

The two-dimensional topological insulating phase has been experimentally discovered in HgTe quantum wells (QWs). The low-energy physics of two-dimensional topological insulators (TIs) is described by the Bernevig-Hughes-Zhang (BHZ) model, where the realization of a topological or a normal insulating phase depends on the Dirac mass being negative or positive, respectively. We solve the BHZ model for a mass domain configuration, analyzing the effects on the edge modes of a finite Dirac mass in the normal insulating region (soft-wall boundary condition). We show that at a boundary between a TI and a normal insulator (NI), the Dirac point of the edge states appearing at the interface strongly depends on the ratio between the Dirac masses in the two regions. We also consider the case of multiple boundaries such as NI/TI/NI, TI/NI/TI and NI/TI/NI/TI.Comment: 11 pages, 15 figure

Helical edge states in multiple topological mass domains

The two-dimensional topological insulating phase has been experimentally discovered in HgTe quantum wells (QWs). The low-energy physics of two-dimensional topological insulators (TIs) is described by the Bernevig-Hughes-Zhang (BHZ) model, where the realization of a topological or a normal insulating phase depends on the Dirac mass being negative or positive, respectively. We solve the BHZ model for a mass domain configuration, analyzing the effects on the edge modes of a finite Dirac mass in the normal insulating region (soft-wall boundary condition). We show that at a boundary between a TI and a normal insulator (NI), the Dirac point of the edge states appearing at the interface strongly depends on the ratio between the Dirac masses in the two regions. We also consider the case of multiple boundaries such as NI/TI/NI, TI/NI/TI and NI/TI/NI/TI.Comment: 11 pages, 15 figure

Reduction of physiological stress by urban green space in a multisensory virtual experiment

Although stress is an increasing global health problem in cities, urban green spaces can provide health benefits. There is, however, a lack of understanding of the link between physiological mechanisms and qualities of urban green spaces. Here, we compare the effects of visual stimuli (360 degree virtual photos of an urban environment, forest, and park) to the effects of congruent olfactory stimuli (nature and city odours) and auditory stimuli (bird songs and noise) on physiological stress recovery. Participants (N = 154) were pseudo-randomised into participating in one of the three environments and subsequently exposed to stress (operationalised by skin conductance levels). The park and forest, but not the urban area, provided significant stress reduction. High pleasantness ratings of the environment were linked to low physiological stress responses for olfactory and to some extent for auditory, but not for visual stimuli. This result indicates that olfactory stimuli may be better at facilitating stress reduction than visual stimuli. Currently, urban planners prioritise visual stimuli when planning open green spaces, but urban planners should also consider multisensory qualities

C2D Spitzer-IRS spectra of disks around T Tauri stars: IV. Crystalline silicates

Aims. Dust grains in the planet-forming regions around young stars are expected to be heavily processed due to coagulation, fragmentation, and crystallization. This paper focuses on the crystalline silicate dust grains in protoplanetary disks for a statistically significant number of TTauri stars (96). Methods. As part of the cores to disks (c2d) legacy program, we obtained more than a hundred Spitzer/IRS spectra of TTauri stars, over a spectral range of 5-35 μm where many silicate amorphous and crystalline solid-state features are present. At these wavelengths, observations probe the upper layers of accretion disks up to distances of a dozen AU from the central object. Results. More than 3/4 of our objects show at least one crystalline silicate emission feature that can be essentially attributed to Mg-rich silicates. The Fe-rich crystalline silicates are largely absent in the c2d IRS spectra. The strength and detection frequency of the crystalline features seen at λ > 20 μm correlate with each other, while they are largely uncorrelated with the observational properties of the amorphous silicate 10 μm feature. This supports the idea that the IRS spectra essentially probe two independent disk regions: a warm zone (≤1 AU) emitting at ~ 10 μm and a much colder region emitting at λ > 20 μm (≤10 AU). We identify a crystallinity paradox, as the long-wavelength (λ > 20 m) crystalline silicate features are detected 3.5 times more frequently (~55% vs. ~15%) than the crystalline features arising from much warmer disk regions (λ ~ 10 μm). This suggests that the disk has an inhomogeneous dust composition within ~10 AU. The analysis of the shape and strength of both the amorphous 10 μm feature and the crystalline feature around 23 μm provides evidence for the prevalence of μm-sized (amorphous and crystalline) grains in upper layers of disks. Conclusions. The abundant crystalline silicates found far from their presumed formation regions suggest efficient outward radial transport mechanisms in the disks around TTauri stars. The presence of μm-sized grains in disk atmospheres, despite the short timescales for settling to the midplane, suggests efficient (turbulent) vertical diffusion, probably accompanied by grain-grain fragmentation to balance the expected efficient growth. In this scenario, the depletion of submicron-sized grains in the upper layers of the disks points toward removal mechanisms such as stellar winds or radiation pressure

Landscape perception: linking physical monitoring data to perceived landscape properties

Changes in the landscape affect not only people's well-being but also how people perceive and use the landscape. An increasing number of policies have highlighted the importance of conserving a landscape's recreational and aesthetical values. This study develops and evaluates a model that links people's perceptions of a mountain landscape to physical monitoring data. Using a questionnaire, we revealed how respondents working with the Swedish mountains characterise the Magnificent Mountain landscape (as defined by Swedish policy objectives) and translated these characteristics into data from the National Inventory of Landscapes in Sweden (NILS). We found 14 potential indicators that could be derived from the existing NILS physical monitoring data and which could be used to monitor changes in the landscape values as perceived by people. Based on the results, we suggest how to simultaneously utilise field sampling of physical data and field photos to provide temporal information about landscape perception

Effects of CO2 on H2O band profiles and band strengths in mixed H2O:CO2 ices

H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent Spitzer observations have revealed CO2 ice in high abundances and it has been suggested that CO2 mixed into H2O ice can affect relative strengths of the 3 um and 6 um bands. We used laboratory infrared transmission spectroscopy of H2O:CO2 ice mixtures to investigate the effects of CO2 on H2O ice spectral features at 15-135 K. We find that the H2O peak profiles and band strengths are significantly different in H2O:CO2 ice mixtures compared to pure H2O ice. In all H2O:CO2 mixtures, a strong free-OH stretching band appears around 2.73 um, which can be used to put an upper limit on the CO2 concentration in the H2O ice. The H2O bending mode profile also changes drastically with CO2 concentration; the broad pure H2O band gives way to two narrow bands as the CO2 concentration is increased. This makes it crucial to constrain the environment of H2O ice to enable correct assignments of other species contributing to the interstellar 6 um absorption band. The amount of CO2 present in the H2O ice of B5:IRS1 is estimated by simultaneously comparing the H2O stretching and bending regions and the CO2 bending mode to laboratory spectra of H2O, CO2, H2O:CO2 and HCOOH.Comment: 12 pages, 11 figures, accepted by A&