Relation between potential and catalytic activity of rhodium in propylene combustion

The relation between the catalyst potential and the catalytic performance has been investigated in the gas-phase combustion of propylene with oxygen over rhodium catalysts at 375 °C. The rhodium catalyst, deposited on yttria-stabilized zirconia (YSZ) solid electrolyte, also served as working electrode in the electrochemical cell. Under open-circuit conditions, the measured catalyst potential was found to be a sensitive indicator of the oxidation state of the rhodium catalyst, which influences the catalytic reaction rate dramatically and depends strongly both on the method of catalyst film preparation and on the composition of the reacting gas mixture. In turn, under closed-circuit conditions, the applied catalyst potential is a convenient tool to maintain the catalyst in its more active, reduced form and to control its catalytic performance. The activity of atomic oxygen at the three-phase boundary (tpb) during open-circuit catalytic reaction was estimated from solid electrolyte potentiometric (SEP) measurements, in good agreement with the average surface oxidation state obtained from XRD and XPS analyses. O/Rh atomic ratios higher than stoichiometric were found by XPS at the outer surface of the catalysts suggesting a strong open circuit O2− spillover due to strong metal support interactions (SMSI) and a concomitant extension of the electric double layer to the gas-exposed catalyst surface, similarly to emersed electrodes in aqueous electrochemistry. Applying potentials up to several hundreds of mV, highly nonfaradaic promotion of propylene combustion was achieved. Electrochemical promotion of catalysis (EPOC) was most efficient at stoichiometric gas composition, that is, close to the limit of surface reduction, and with the catalyst exhibiting the smallest O2− spillover population at open-circuit condition

Distant red galaxies in the Hubble Ultra Deep Field

We take advantage of the Hubble Ultra Deep Field (UDF) data to study the restframe optical and ultra violet (UV) morphologies of the novel population of Distant Red Galaxies (DRGs). Six galaxies with J-Ks > 2.3 are found to Ks=21.5, five of which have photometric redshifts z_phot > 2, corresponding to a surface density of 0.9/arcmin^2. The surface brightness distributions of the z_phot > 2 galaxies are better represented by exponential disks than R^{1/4}-laws. Two of the z_phot > 2 galaxies are extended, while three have compact morphologies. The restframe optical morphology of the z_phot > 2 galaxies is quite different from the restframe UV morphology: all the galaxies have red central components which dominate in the NICMOS H_{160}-band images, and distinct off-center blue features which show up in (and often dominate) the ACS images. The mean measured effective radius of the z_phot > 2 galaxies is =1.9+/-1.4 kpc, similar (within the errors) to the mean size of LBGs at similar redshifts. All the DRGs are resolved in the ACS images, while four are resolved in the NICMOS images. Two of the z_phot > 2 galaxies are bright X-ray sources and hence host AGN. The diverse restframe optical and UV morphological properties of DRGs derived here suggest that they have complex stellar populations, consisting of both evolved populations that dominate the mass and the restframe optical light, and younger populations, which show up as patches of star formation in the restframe UV light; in many ways resembling the properties of normal local galaxies. This interpretation is supported by fits to the broadband SEDs, which for all five z_phot > 2 are best represented by models with extended star formation histories and substantial amounts of dust.Comment: Accepted for publication in APJ

Discovery of a Galaxy Cluster via Weak Lensing

We report the discovery of a cluster of galaxies via its weak gravitational lensing effect on background galaxies, the first spectroscopically confirmed cluster to be discovered through its gravitational effects rather than by its electromagnetic radiation. This fundamentally different selection mechanism promises to yield mass-selected, rather than baryon or photon-selected, samples of these important cosmological probes. We have confirmed this cluster with spectroscopic redshifts of fifteen members at z=0.276, with a velocity dispersion of 615 km/s. We use the tangential shear as a function of source photometric redshift to estimate the lens redshift independently and find z_l = 0.30 +- 0.08. The good agreement with the spectroscopy indicates that the redshift evolution of the mass function may be measurable from the imaging data alone in shear-selected surveys.Comment: revised version with minor changes, to appear in ApJ

Finding Galaxy Groups In Photometric Redshift Space: the Probability Friends-of-Friends (pFoF) Algorithm

We present a structure finding algorithm designed to identify galaxy groups in photometric redshift data sets: the probability friends-of-friends (pFoF) algorithm. This algorithm is derived by combining the friends-of-friends algorithm in the transverse direction and the photometric redshift probability densities in the radial dimension. The innovative characteristic of our group-finding algorithm is the improvement of redshift estimation via the constraints given by the transversely connected galaxies in a group, based on the assumption that all galaxies in a group have the same redshift. Tests using the Virgo Consortium Millennium Simulation mock catalogs allow us to show that the recovery rate of the pFoF algorithm is larger than 80% for mock groups of at least 2\times10^{13}M_{\sun}, while the false detection rate is about 10% for pFoF groups containing at least $\sim8$ net members. Applying the algorithm to the CNOC2 group catalogs gives results which are consistent with the mock catalog tests. From all these results, we conclude that our group-finding algorithm offers an effective yet simple way to identify galaxy groups in photometric redshift catalogs.Comment: AJ accepte

The infrared luminosity function of galaxies at redshifts z=1 and z~2 in the GOODS fields

We present the rest-frame 8 micron luminosity function (LF) at redshifts z=1 and ~2, computed from Spitzer 24 micron-selected galaxies in the GOODS fields over an area of 291 sq. arcmin. Using classification criteria based on X-ray data and IRAC colours, we identify the AGN in our sample. The rest-frame 8 micron LF for star-forming galaxies at redshifts z=1 and ~2 have the same shape as at z~0, but with a strong positive luminosity evolution. The number density of star-forming galaxies with log_{10}(nu L_nu(8 micron))>11 increases by a factor >250 from redshift z~0 to 1, and is basically the same at z=1 and ~2. The resulting rest-frame 8 micron luminosity densities associated with star formation at z=1 and ~2 are more than four and two times larger than at z~0, respectively. We also compute the total rest-frame 8 micron LF for star-forming galaxies and AGN at z~2 and show that AGN dominate its bright end, which is well-described by a power-law. Using a new calibration based on Spitzer star-forming galaxies at 0<z<0.6 and validated at higher redshifts through stacking analysis, we compute the bolometric infrared (IR) LF for star-forming galaxies at z=1 and ~2. We find that the respective bolometric IR luminosity densities are (1.2+/-0.2) x 10^9 and (6.6^{+1.2}_{-1.0}) x 10^8 L_sun Mpc^{-3}, in agreement with previous studies within the error bars. At z~2, around 90% of the IR luminosity density associated with star formation is produced by luminous and ultraluminous IR galaxies (LIRG and ULIRG), with the two populations contributing in roughly similar amounts. Finally, we discuss the consistency of our findings with other existing observational results on galaxy evolution.Comment: Accepted for publication in the ApJ. 33 pages, 15 figures. Uses emulateap

Properties of high-z galaxies as seen through lensing clusters

We discuss the first results obtained on the study of a sample of high-z galaxies (2 < z < 7), using the gravitational amplification effect in the core of lensing clusters. Sources are located close to the critical lines in clusters with well constrained mass distributions, and selected through photometric redshifts, computed on a large wavelength domain, and lens inversion techniques.Comment: 5 pages, 3 figures, Conference Proceedings of the "Clustering at High Redshift" Conference, June 29 to July 2, 1999, Marseille (France

The VIPERS Multi-Lambda Survey. II. Diving with massive galaxies in 22 square degrees since z = 1.5

We investigate the evolution of the galaxy stellar mass function (SMF) and stellar mass density from redshift z=0.2 to z=1.5 of a $K_{AB}$<22-selected sample with highly reliable photometric redshifts and over an unprecedentedly large area. Our study is based on NIR observations carried out with WIRCam at CFHT over the footprint of the VIPERS spectroscopic survey and benefits from the high quality optical photometry from the CFHTLS and UV observations with the GALEX satellite. The accuracy of our photometric redshifts is $\sigma_z$ < 0.03 and 0.05 for the bright ($i_{AB}$22.5) samples, respectively. The SMF is measured with ~760,000 galaxies down to $K_s$=22 and over an effective area of ~22.4 deg$^2$, the latter of which drastically reduces the statistical uncertainties (i.e. Poissonian error & cosmic variance). We point out the importance of a careful control of the photometric calibration, whose impact becomes quickly dominant when statistical uncertainties are reduced, which will be a major issue for future generation of cosmological surveys with, e.g. EUCLID or LSST. By exploring the rest-frame (NUV-r) vs (r-$K_s$) color-color diagram separating star-forming and quiescent galaxies, (1) we find that the density of very massive log($M_*/ M_{\odot}$) > 11.5 galaxies is largely dominated by quiescent galaxies and increases by a factor 2 from z~1 to z~0.2, which allows for additional mass assembly via dry mergers, (2) we confirm a scenario where star formation activity is impeded above a stellar mass log($M^*_{SF} / M_{\odot}$) = 10.64$\pm$0.01, a value that is found to be very stable at 0.2 < z < 1.5, (3) we discuss the existence of a main quenching channel that is followed by massive star-forming galaxies, and finally (4) we characterise another quenching mechanism required to explain the clear excess of low-mass quiescent galaxies observed at low redshift.Comment: 22 pages, 20 figures. Accepted for publication in A&A. Version to be publishe

The lensing system towards the doubly imaged quasar SBS 1520+530

The gravitational potential responsible for the lensing effect in SBS 1520+530 is studied over length scales from a few arc-seconds to a few arc-minutes. For this purpose, we use sharply deconvolved Hubble Space Telescope images in the optical and near-IR, in combination with ground based optical data obtained over a wider field-of-view. In particular, we have carried out a multi-color analysis in order to identify groups or clusters of galaxies along the line of sight. Photometric redshifts are measured for 139 galaxies unveiling significant excesses of galaxies 1.0 arcmin, NW and 1.7 arcmin, SW of the main lensing galaxy. The photometric redshift inferred both for the main lensing galaxy and for the galaxy concentrations is z=0.9^{+0.10}_{-0.25}. This is in rough agreement with the measured spectroscopic redshift of the main lensing galaxy, z=0.71 (Burud et al. 2002), suggesting that it is part of a larger group or cluster. We investigate the impact of including the galaxy cluster, first on the modelling of the lensing system, and second on the expected time--delay between the two quasar images.Comment: Accepted in A&A. 10 pages. Includes 3 jpg figure

Obscured and unobscured active galactic nuclei in the Spitzer Space Telescope First Look Survey

Selection of active galactic nuclei (AGN) in the infrared allows the discovery of AGN whose optical emission is extinguished by dust. In this paper, we use the Spitzer Space Telescope First Look Survey (FLS) to assess what fraction of AGN with mid-infrared luminosities comparable to quasars are missed in optical quasar surveys due to dust obscuration. We begin by using the Sloan Digital Sky Survey (SDSS) database to identify 54 quasars within the 4 deg^2 extragalactic FLS. These quasars occupy a distinct region in mid-infrared color space by virtue of their strong, red, continua. This has allowed us to define a mid-infrared color criterion for selecting AGN candidates. About 2000 FLS objects have colors consistent with them being AGN, but most are much fainter in the mid-infrared than the SDSS quasars, which typically have 8 micron flux densities, S(8.0), ~1 mJy. We have investigated the properties of the 43 objects with S(8.0) >= 1 mJy satisfying our AGN color selection. This sample should contain both unobscured quasars, and AGN which are absent from the SDSS survey due to extinction in the optical. After removing 16 known quasars, three probable normal quasars, and eight spurious or confused objects from the initial sample of 43, we are left with 16 objects which are likely to be obscured quasars or luminous Seyfert-2 galaxies. This suggests the numbers of obscured and unobscured AGN are similar in samples selected in the mid-infrared at S(8.0)~1 mJy.Comment: To appear in the ApJS Spitzer Special Issu