Nanolithography for metallic quasi crystals for nanobio applications

There is currently an urgent need to develop micro and nanotechnique for the fabrications of quasi periodic crystals in a plane for the study and applications of novel optical properties when light propagating in or through such a photonic structures with fold symmetries (10 fold symmetry in this work). It has been clear that quasi periodical crystals in dielectrics with various fold symmetries also exhibits complete photonic band gap (PBG) property as periodical photonic crystals do. However, the novel physical properties related to the interactions of electromagnetic waves with metallic holes arrays in quasi periodical order (metallic quasi crystals) is being discovered both theoretically and experimentally, which demands technical development for the construction of theoretically designed structures. [1] In this work, we report a nanofabrication technique recently developed for the replication of quasi crystal in 100 nm Al on a slab (quartz wafer in this work) by electron beam lithography using chemically amplified resist, UVN-30. A wealth of novel photonic behaviours of lights vertically incident through the q-crystal were observed

Carrier relaxation in Si/SiO2_2 quantum dots

Carrier relaxation due to both optical and nonradiative intraband transitions in silicon quantum dots in SiO$_2$ has been considered. Interaction of confined holes with optical phonons has been studied. The Huang-Rhys factor is calculated for such transitions. The probability of intraband transition of a confined hole emitting several optical phonons is estimated.Comment: 8 pages, 2 figures, submitted as an extended abstract to the E-MRS Spring Meeting 200

The effective equation method

In this chapter we present a general method of constructing the effective equation which describes the behaviour of small-amplitude solutions for a nonlinear PDE in finite volume, provided that the linear part of the equation is a hamiltonian system with a pure imaginary discrete spectrum. The effective equation is obtained by retaining only the resonant terms of the nonlinearity (which may be hamiltonian, or may be not); the assertion that it describes the limiting behaviour of small-amplitude solutions is a rigorous mathematical theorem. In particular, the method applies to the three-- and four--wave systems. We demonstrate that different possible types of energy transport are covered by this method, depending on whether the set of resonances splits into finite clusters (this happens, e.g. in case of the Charney-Hasegawa-Mima equation), or is connected (this happens, e.g. in the case of the NLS equation if the space-dimension is at least two). For equations of the first type the energy transition to high frequencies does not hold, while for equations of the second type it may take place. In the case of the NLS equation we use next some heuristic approximation from the arsenal of wave turbulence to show that under the iterated limit "the volume goes to infinity", taken after the limit "the amplitude of oscillations goes to zero", the energy spectrum of solutions for the effective equation is described by a Zakharov-type kinetic equation. Evoking the Zakharov ansatz we show that stationary in time and homogeneous in space solutions for the latter equation have a power law form. Our method applies to various weakly nonlinear wave systems, appearing in plasma, meteorology and oceanology

Achieving Conformational Control in RTP and TADF Emitters by Functionalization of the Central Core

Three new symmetrical donor–acceptor–donor (D–A–D)-type molecules were prepared with phenothiazine (PTZ) as electron donors and 9,9-dimethylthioxanthene (TX) as the electron acceptor. The PTZ groups are attached at different positions on the acceptor core – ortho or meta to the sulfur of TX. The molecules have been characterized by X-ray crystallography, in-depth photophysical studies and theoretical calculations. This series provides new insights into how molecular functionalization and intramolecular charge transfer determines the singlet-triplet gap ΔEST. Two of the molecules have weak D/A decoupling and a relatively large ΔEST of 0.52 eV which prohibits the upconversion of triplet excitons to the singlet state, showing strong room temperature phosphorescence (RTP). When the TX acceptor strength is enhanced by the attachment of benzoyl substituents a very small ΔEST of <0.01 eV is observed. In this case excitons in the triplet state can be efficiently upconverted to the singlet state via reverse intersystem crossing (RISC) resulting in thermally activated delayed fluorescence (TADF). TADF and RTP are unambiguously assigned by distinctive photophysical data, notably a comparison of degassed and aerated luminescence spectra, temperature-dependent time-resolved fluorescence decays and power dependence of the intensity of delayed emission (for the TADF emitter)

Quasi-separatrix layers and three-dimensional reconnection diagnostics for line-tied tearing modes

In three-dimensional magnetic configurations for a plasma in which no closed field line or magnetic null exists, no magnetic reconnection can occur, by the strictest definition of reconnection. A finitely long pinch with line-tied boundary conditions, in which all the magnetic field lines start at one end of the system and proceed to the opposite end, is an example of such a system. Nevertheless, for a long system of this type, the physical behavior in resistive magnetohydrodynamics (MHD) essentially involves reconnection. This has been explained in terms comparing the geometric and tearing widths [1, 2]. The concept of a quasi-separatrix layer[3, 4] was developed for such systems. In this paper we study a model for a line-tied system in which the corresponding periodic system has an unstable tearing mode. We analyze this system in terms of two magnetic field line diagnostics, the squashing factor[3-5] and the electrostatic potential difference used in kinematic reconnection studies[6, 7]. We discuss the physical and geometric significance of these two diagnostics and compare them in the context of discerning tearing-like behavior in line-tied modes. [1] G. L. Delzanno and J. M. Finn. Physics of Plasmas, 15(3):032904, 2008. [2] Y.-M. Huang and E. G. Zweibel. Physics of Plasmas, 16(4):042102, 2009. [3] E. R. Priest and P. D\'emoulin. J. Geophys. Res., 100(A12):23443-23463, 1995. [4] P. D\'emoulin, J. C. Henoux, E. R. Priest, and C. H. Mandrini. Astron. Astrophys., 308:643-655, Apr. 1996. [5] V. S. Titov and G. Hornig. Advances in Space Research, 29(7):1087-1092, 2002. [6] Y. Lau and J. M. Finn. The Astrophysical Journal, 350:672-691, Feb. 1990. [7] Y. Lau and J. M. Finn. The Astrophysical Journal, 366:577-591, 1991.Comment: 13 pages, 9 figures, Submitted to Commun Nonlinear Sci Numer Simula

Extensive Renyi Statistics from Non-Extensive Entropy

We show that starting with either the non-extensive Tsallis entropy in Wang's formalism or the extensive Renyi entropy, it is possible to construct the equilibrium statistical mechanics with non-Gibbs canonical distribution functions. The transformation formulas between Tsallis statistics and Renyi statistics are presented. The one-particle distribution function in Renyi statistics with extensive entropy for the classical ideal gas at finite particle number develops a power-law tail for high momenta.Comment: 14 pages, 2 figures, LaTe

Spectroscopy of vibrational modes in metal nanoshells

We study the spectrum of vibrational modes in metal nanoparticles with a dielectric core. Vibrational modes are excited by the rapid heating of the particle lattice that takes place after laser excitation, and can be monitored by means of pump-probe spectroscopy as coherent oscillations of transient optical spectra. In nanoshells, the presence of two metal surfaces results in a substantially different energy spectrum of acoustic vibrations than for solid particles. We calculated the energy spectrum as well as the damping of nanoshell vibrational modes. The oscillator strength of fundamental breathing mode is larger than that in solid nanoparticles. At the same time, in very thin nanoshells, the fundamental mode is overdamped due to instantaneous energy transfer to the surrounding medium

Limits of complete equilibration of fragments produced in central Au on Au collisions at intermediate energies

Experimental data related to fragment production in central Au on Au collisions were analyzed in the framework of a modified statistical model which considers cluster production both prior and at the equilibrated stage. The analysis provides limits to the number of nucleons and to the temperature of the equilibrated source. The rather moderate temperatures obtained from experimental double-yield ratios of d,t,3He and 4He are in agreement with the model calculations. A phenomenological relation was established between the collective flow and the chemical temperature in these reactions. It was shown that dynamical mechanisms of fragment production, e.g. coalescence, dominate at high energies. It is demonstrated that coalescence may be consistent with chemical equilibrium between the produced fragments. The different meaning of chemical and kinetic temperatures is discussed.Comment: 13 pages, 10 figures, accepted at EPJ

Role of Dimerization of the Membrane-associated Growth Factor Kit Ligand in Juxtacrine Signaling: The Sl17H Mutation Affects Dimerization and Stability—Phenotypes in Hematopoiesis

The Kit ligand (KL)/Kit receptor pair functions in hematopoiesis, gametogenesis, and melanogenesis. KL is encoded at the murine steel (Sl) locus and encodes a membrane growth factor which may be proteolytically processed to produce soluble KL. The membrane-associated form of KL is critical in mediating Kit function in vivo. Evidence for a role of cytoplasmic domain sequences of KL comes from the Sl17H mutation, a splice site mutation that replaces the cytoplasmic domain with extraneous amino acids. Using deletion mutants and the Sl17H allele, we have investigated the role of the cytoplasmic domain sequences of KL in biosynthetic processing and cell surface presentation. The normal KL protein products are processed for cell surface expression, where they form dimers. Both Sl17H and the cytoplasmic deletion mutants of KL were processed to the cell surface; however, the rate of transport and protein stability were affected by the mutations. Deletion of cytoplasmic domain sequences of KL did not affect dimerization of KL. In contrast, dimerization of the Sl17H protein was reduced substantially. In addition, we have characterized the hematopoietic cell compartment in Sl17H mutant mice. The Sl17H mutation has only minor effects on hematopoiesis. Tissue and peritoneal mast cell numbers were reduced in mutant mice as well as in myeloid progenitors. Interestingly, long-term bone marrow cultures from Sl17H mice did not sustain the long-term production of hematopoietic cells. In addition, homing of normal hematopoietic progenitors to the spleen of irradiated Sl17H/Sl17H recipient mice was diminished in transplantation experiments, providing evidence for a role of Kit in homing or lodging. These results demonstrate that the membrane forms of KL exist as homodimers on the cell surface and that dimerization may play an important role in KL/Kit-mediated juxtacrine signaling