1,543 research outputs found
Alternating magnetic anisotropy of Li(Li)N with = Mn, Fe, Co, and Ni
Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be
substituted for Li in single crystalline Li(Li)N. Isothermal and
temperature-dependent magnetization measurements reveal local magnetic moments
with magnitudes significantly exceeding the spin-only value. The additional
contributions stem from unquenched orbital moments that lead to rare-earth-like
behavior of the magnetic properties. Accordingly, extremely large magnetic
anisotropies have been found. Most notably, the magnetic anisotropy alternates
as easy-plane easy-axis easy-plane
easy-axis when progressing from = Mn Fe Co
Ni. This behavior can be understood based on a perturbation
approach in an analytical, single-ion model. The calculated magnetic
anisotropies show a surprisingly good agreement with the experiment and capture
the basic features observed for the different transition metals.Comment: 5 pages, 3 figures, published as PRB Rapid Communication, Fig. 3
update
High Resolution Spectroscopy and Spectropolarimetry of some late F-/early G-type sun-like stars as targets for Zeeman Doppler imaging
High resolution spectroscopy and spectropolarimetry have been undertaken at
the Anglo-Australian Telescope in order to identify suitable targets for
magnetic studies of young sun-like stars, for the proxy study of early solar
evolution. This study involved the investigation of some variable late F-/early
G-type sun-like stars originally identified by the Hipparcos mission. Of the 38
stars observed for this study, HIP 31021, HIP 64732, HIP 73780 were found to be
spectroscopic binary stars while HIP 19072, HIP 67651 and HIP 75636 are also
likely to be binaries while HIP 33111 could even be a triple system. Magnetic
fields were detected on a number of the survey stars: HIP 21632, HIP 43720, HIP
48770, HIP 62517, HIP 71933, HIP 77144, HIP 89829, HIP 90899 and HIP 105388,
making these stars good candidates for follow-up Zeeman Doppler imaging
studies.Comment: 16 pages, 16 figures, 4 tables Accepted for publication in PAS
ASAS Light Curves of Intermediate Mass Eclipsing Binaries and the Parameters of HI Mon
We present a catalog of 56 candidate intermediate mass eclipsing binary
systems extracted from the 3rd data release of the All Sky Automated Survey. We
gather pertinent observational data and derive orbital properties, including
ephemerides, for these systems as a prelude to anticipated spectroscopic
observations. We find that 37 of the 56, or ~66% of the systems are not
identified in the Simbad Astronomical Database as known binaries. As a specific
example, we show spectroscopic data obtained for the system HI Mon (B0 V + B0.5
V) observed at key orbital phases based on the computed ephemeris, and we
present a combined spectroscopic and photometric solution for the system and
give stellar parameters for each component.Comment: 83 pages, 63 figure
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Isomeric triazines exhibit unique profiles of bioorthogonal reactivity.
Expanding the scope of bioorthogonal reactivity requires access to new and mutually compatible reagents. We report here that 1,2,4-triazines can be tuned to exhibit unique reaction profiles with biocompatible strained alkenes and alkynes. Computational analyses were used to identify candidate orthogonal reactions, and the predictions were experimentally verified. Notably, 5-substituted triazines, unlike their 6-substituted counterparts, undergo rapid [4 + 2] cycloadditions with a sterically encumbered strained alkyne. This unique, sterically controlled reactivity was exploited for dual bioorthogonal labeling. Mutually orthogonal triazines and cycloaddition chemistries will enable new multi-component imaging applications
Target selection for the SUNS and DEBRIS surveys for debris discs in the solar neighbourhood
Debris discs - analogous to the Asteroid and Kuiper-Edgeworth belts in the
Solar system - have so far mostly been identified and studied in thermal
emission shortward of 100 um. The Herschel space observatory and the SCUBA-2
camera on the James Clerk Maxwell Telescope will allow efficient photometric
surveying at 70 to 850 um, which allow for the detection of cooler discs not
yet discovered, and the measurement of disc masses and temperatures when
combined with shorter wavelength photometry. The SCUBA-2 Unbiased Nearby Stars
(SUNS) survey and the DEBRIS Herschel Open Time Key Project are complimentary
legacy surveys observing samples of ~500 nearby stellar systems. To maximise
the legacy value of these surveys, great care has gone into the target
selection process. This paper describes the target selection process and
presents the target lists of these two surveys.Comment: 67 pages with full tables, 7 figures, accepted to MNRA
The Lick-Carnegie Survey: A New Two-Planet System Around the Star HD 207832
Keck/HIRES precision radial velocities of HD 207832 indicate the presence of
two Jovian-type planetary companions in Keplerian orbits around this G star.
The planets have minimum masses of 0.56 and 0.73 Jupiter-masses with orbital
periods of ~162 and ~1156 days, and eccentricities of 0.13 and 0.27,
respectively. Stromgren b and y photometry reveals a clear stellar rotation
signature of the host star with a period of 17.8 days, well separated from the
period of the radial velocity variations, reinforcing their Keplerian origin.
The values of the semimajor axes of the planets suggest that these objects have
migrated from the region of giant planet formation to closer orbits. In order
to examine the possibility of the existence of additional (small) planets in
the system, we studied the orbital stability of hypothetical terrestrial-sized
objects in the region between the two planets and interior to the orbit of the
inner body. Results indicated that stable orbits exist only in a small region
interior to planet b. However, the current observational data offer no evidence
for the existence of additional objects in this system.Comment: 23 pages, 4 figures, 5 tables, accepted for publication in Ap
High-dispersion absorption-line spectroscopy of AE Aqr
High-dispersion time-resolved spectroscopy of the unique magnetic cataclysmic variable AE Aqr is presented. A radial velocity analysis of the absorption lines yields K2= 168.7 ± 1 km sâ1. Substantial deviations of the radial velocity curve from a sinusoid are interpreted in terms of intensity variations over the secondary star's surface. A complex rotational velocity curve as a function of orbital phase is detected which has a modulation frequency of twice the orbital frequency, leading to an estimate of the binary inclination angle that is close to 70°. The minimum and maximum rotational velocities are used to indirectly derive a mass ratio of q= 0.6 and a radial velocity semi-amplitude of the white dwarf of K1= 101 ± 3 km sâ1. We present an atmospheric temperature indicator, based on the absorption-line ratio of Fe I and Cr I lines, whose variation indicates that the secondary star varies from K0 to K4 as a function of orbital phase. The ephemeris of the system has been revised, using more than 1000 radial velocity measurements, published over nearly five decades. From the derived radial velocity semi-amplitudes and the estimated inclination angle, we calculate that the masses of the stars are M1= 0.63 ± 0.05 Mâ; M2= 0.37 ± 0.04 Mâ, and their separation is a= 2.33 ± 0.02 Râ. Our analysis indicates the presence of a late-type star whose radius is larger, by a factor of nearly 2, than the radius of a normal main-sequence star of the same mass. Finally, we discuss the possibility that the measured variations in the rotational velocity, temperature and spectral type of the secondary star as functions of orbital phase may, like the radial velocity variations, be attributable to regions of enhanced absorption on the star's surface
Correlation Between the Deuteron Characteristics and the Low-energy Triplet np Scattering Parameters
The correlation relationship between the deuteron asymptotic normalization
constant, , and the triplet np scattering length, , is
investigated. It is found that 99.7% of the asymptotic constant is
determined by the scattering length . It is shown that the linear
correlation relationship between the quantities and
provides a good test of correctness of various models of nucleon-nucleon
interaction. It is revealed that, for the normalization constant and
for the root-mean-square deuteron radius , the results obtained with the
experimental value recommended at present for the triplet scattering length
are exaggerated with respect to their experimental counterparts. By
using the latest experimental phase shifts of Arndt et al., we obtain, for the
low-energy scattering parameters (, , ) and for the
deuteron characteristics (, ), results that comply well with
experimental data.Comment: 19 pages, 1 figure, To be published in Physics of Atomic Nucle
Giant magnetic anisotropy and tunnelling of the magnetization in Li2(Li1âxFex)N
Large magnetic anisotropy and coercivity are key properties of functional
magnetic materials and are generally associated with rare earth elements. Here
we show an extreme, uniaxial magnetic anisotropy and the emergence of magnetic
hysteresis in Li2(Li1-xFex)N. An extrapolated, magnetic anisotropy field of 220
Tesla and a coercivity field of over 11 Tesla at 2 Kelvin outperform all known
hard-ferromagnets and single-molecule magnets (SMMs). Steps in the hysteresis
loops and relaxation phenomena in striking similarity to SMMs are particularly
pronounced for x << 1 and indicate the presence of nano-scale magnetic centres.
Quantum tunnelling, in form of temperature-independent relaxation and
coercivity, deviation from Arrhenius behaviour and blocking of the relaxation,
dominates the magnetic properties up to 10 Kelvin. The simple crystal
structure, the availability of large single crystals, and the ability to vary
the Fe concentration make Li2(Li1-xFex)N (i) an ideal model system to study
macroscopic quantum effects at elevated temperatures and (ii) a basis for novel
functional magnetic materials.Comment: 19 pages, 5 figures, Supplementary Information attached, revised
version published in Nature Communication
Probing Stereoselectivity in Ring-Opening Metathesis Polymerization Mediated by Cyclometalated Ruthenium-Based Catalysts: A Combined Experimental and Computational Study
The microstructures of polymers produced by ring-opening metathesis polymerization (ROMP) with cyclometalated Ru-carbene metathesis catalysts were investigated. A strong bias for a cis,syndiotactic microstructure with minimal head-to-tail bias was observed. In instances where trans errors were introduced, it was determined that these regions were also syndiotactic. Furthermore, hypothetical reaction intermediates and transition structures were analyzed computationally. Combined experimental and computational data support a reaction mechanism in which cis,syndio-selectivity is a result of stereogenic metal control, while microstructural errors are predominantly due to alkylidene isomerization via rotation about the RuâC double bond
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