Reversible shift in the superconducting transition for La1.85Sr0.15CuO4 and BaFe1.8Co0.2As2 using piezoelectric substrates

The use of piezoelectric substrates enables a dynamic observation of strain dependent properties of functional materials. Based on studies with La1.85Sr0.15CuO4 we extended this approach to the iron arsenic superconductors represented by BaFe2-xCoxAs2 to investigate strain driven changes in detail. We demonstrate that epitaxial thin films can be prepared on (001)Pb(Mg1/3Nb2/3)0.72Ti0.28O3 substrates using pulsed laser deposition. The structural as well as the electric properties of the grown films were characterized in detail. A reversible shift of the superconducting transition of 0.44 K for La1.85Sr0.15CuO4 and 0.2 K for BaFe1.8Co0.2As2 was observed applying a biaxial strain of 0.022% and 0.017% respectively

In situ measurements of fine sediment infiltration (FSI) in gravel-bed rivers with a hydropeaking flow regime

The overpresence of fine sediment and fine sediment infiltration (FSI) in the aquatic environment of rivers are of increasing importance due to their limiting effects on habitat quality and use. The habitats of both macroinvertebrates and fish, especially spawning sites, can be negatively affected. More recently, hydropeaking has been mentioned as a driving factor in fine sediment dynamics and FSI in gravel-bed rivers. The primary aim of the present study was to quantify FSI in the vertical stratigraphy of alpine rivers with hydropeaking flow regimes in order to identify possible differences in FSI between the permanently wetted area (during base and peak flows) and the so-called dewatering areas, which are only inundated during peak flows. Moreover, we assessed whether the discharge ratio between base and peak flow is able to explain the magnitude of FSI. To address these aims, freeze-core samples were taken in eight different alpine river catchments. The results showed significant differences in the vertical stratification of FSI between the permanently wetted area during base flow and the dewatering sites. Surface clogging occurred only in the dewatering areas, with decreasing percentages of fine sediments associated with increasing core depths. In contrast, permanently wetted areas contained little or no fine sediment concentrations on the surface of the river bed. Furthermore, no statistical relationship was observed between the magnitude of hydropeaking and the sampled FSI rate. A repeated survey of FSI in the gravel matrix revealed the importance of de-clogging caused by flooding and the importance of FSI in the aquatic environment, especially in the initial stages of riparian vegetation establishment

On the correlation between the oxygen in hydrogen content and the catalytic activity of cathode catalysts in PEM water electrolysis

Altogether five platinum group metal (PGM) and PGM-free cathode catalysts were investigated in full PEM water electrolysis cells regarding their polarisation behaviour and their hydrogen and oxygen recombination properties. It was shown that the recombination activity of permeated oxygen and evolved hydrogen within the cathodic catalyst layer correlates with the activity of the oxygen reduction reaction (ORR) which was determined ex situ with linear sweep voltammetry. We found that the investigated PGM-free cathode catalysts had a low activity for the ORR resulting in higher measurable oxygen in hydrogen volume fractions compared to the PGM catalysts, which are more active for the ORR. Out of the three investigated PGM-free catalysts, only one commercially available material based on a Ti suboxide showed a similar good polarisation behaviour as the state of the art cathode catalyst platinum, while its recombination activity was the lowest of all catalysts. In addition to the recombination of hydrogen and oxygen on the electrocatalysts, we found that the prevalent carbon-based cathodic porous transport layers (PTL) also offer catalytically active recombination sites. In comparison to an inactive PTL, the measurable oxygen flux using carbon-based PTLs was lower and the recombination was enhanced by microporous coatings with high surface areas. © 2021 The Author(s)

Large pinning forces and matching effects in YBa2Cu3O7-δ thin films with Ba2Y(Nb/Ta)O6 nano-precipitates

The addition of mixed double perovskite Ba2Y(Nb/Ta)O6 (BYNTO) to YBa2Cu3O7−δ (YBCO) thin films leads to a large improvement of the in-field current carrying capability. For low deposition rates, BYNTO grows as well-oriented, densely distributed nanocolumns. We achieved a pinning force density of 25 GN/m3 at 77 K at a matching field of 2.3 T, which is among the highest values reported for YBCO. The anisotropy of the critical current density shows a complex behavior whereby additional maxima are developed at field dependent angles. This is caused by a matching effect of the magnetic fields c-axis component. The exponent N of the current-voltage characteristics (inversely proportional to the creep rate S) allows the depinning mechanism to be determined. It changes from a double-kink excitation below the matching field to pinning-potential-determined creep above it

A Multi-wavelength Study of the Sunyaev-Zel'dovich Effect in the Triple-Merger Cluster MACS J0717.5+3745 with MUSTANG and Bolocam

We present 90, 140, and 268GHz sub-arcminute resolution imaging of the Sunyaev-Zel'dovich effect (SZE) in MACSJ0717.5+3745. Our 90GHz SZE data result in a sensitive, 34uJy/bm map at 13" resolution using MUSTANG. Our 140 and 268GHz SZE imaging, with resolutions of 58" and 31" and sensitivities of 1.8 and 3.3mJy/beam respectively, was obtained using Bolocam. We compare these maps to a 2-dimensional pressure map derived from Chandra X-ray observations. Our MUSTANG data confirm previous indications from Chandra of a pressure enhancement due to shock-heated, >20keV gas immediately adjacent to extended radio emission seen in low-frequency radio maps. The MUSTANG data also detect pressure substructure that is not well-constrained by the X-ray data in the remnant core of a merging subcluster. We find that the small-scale pressure enhancements in the MUSTANG data amount to ~2% of the total pressure measured in the 140GHz Bolocam observations. The X-ray template also fails on larger scales to accurately describe the Bolocam data, particularly at the location of a subcluster known to have a high line of sight optical velocity (~3200km/s). Our Bolocam data are adequately described when we add an additional component - not described by a thermal SZE spectrum - coincident with this subcluster. Using flux densities extracted from our model fits, and marginalizing over the temperature constraints for the region, we fit a thermal+kinetic SZE spectrum to our data and find the subcluster has a best-fit line of sight proper velocity of 3600+3440/-2160km/s. This agrees with the optical velocity estimates for the subcluster. The probability of velocity<0 given our measurements is 2.1%. Repeating this analysis using flux densities measured non-parametrically results in a 3.4% probability of a velocity<=0. We note that this tantalizing result for the kinetic SZE is on resolved, subcluster scales.Comment: 10 Figures, 18 pages. this version corrects issues with the previous arXiv versio

Macroporous ultramicroelectrodes for improved electroanalytical measurements

Recent work on the preparation of highly organized macroporous electrodes and nanoporous ultramicroelectrodes has been combined and extended to elaborate macroporous ultramicroelectrodes (UMEs) by template synthesis using colloidal crystals and following two different and complementary methods. On the one hand, arched porous UMEs were prepared, and on the other hand, cylindrical porous UMEs were obtained by using cavity UMEs. These macroporous UMEs have an active surface area which is up to 2 orders of magnitude higher compared to that of a classical disk UME as characterized by cyclic voltammetry. To study their analytical performance, the macroporous UMEs have been modified with a redox-active thiol and also a model bioelectrocatalytical system containing a redox mediator, a cofactor, and glucose-dehydrogenase. In both cases the electrochemical signal is amplified by up to 2 orders of magnitude, which increases significantly the analytical performance of such electrodes and therefore opens up new applications for this kind of miniaturized electrochemical system

Fluid-structure interaction simulation of prosthetic aortic valves : comparison between immersed boundary and arbitrary Lagrangian-Eulerian techniques for the mesh representation

In recent years the role of FSI (fluid-structure interaction) simulations in the analysis of the fluid-mechanics of heart valves is becoming more and more important, being able to capture the interaction between the blood and both the surrounding biological tissues and the valve itself. When setting up an FSI simulation, several choices have to be made to select the most suitable approach for the case of interest: in particular, to simulate flexible leaflet cardiac valves, the type of discretization of the fluid domain is crucial, which can be described with an ALE (Arbitrary Lagrangian-Eulerian) or an Eulerian formulation. The majority of the reported 3D heart valve FSI simulations are performed with the Eulerian formulation, allowing for large deformations of the domains without compromising the quality of the fluid grid. Nevertheless, it is known that the ALE-FSI approach guarantees more accurate results at the interface between the solid and the fluid. The goal of this paper is to describe the same aortic valve model in the two cases, comparing the performances of an ALE-based FSI solution and an Eulerian-based FSI approach. After a first simplified 2D case, the aortic geometry was considered in a full 3D set-up. The model was kept as similar as possible in the two settings, to better compare the simulations' outcomes. Although for the 2D case the differences were unsubstantial, in our experience the performance of a full 3D ALE-FSI simulation was significantly limited by the technical problems and requirements inherent to the ALE formulation, mainly related to the mesh motion and deformation of the fluid domain. As a secondary outcome of this work, it is important to point out that the choice of the solver also influenced the reliability of the final results

On the Correlation between the Oxygen in Hydrogen Content and the Catalytic Activity of Cathode Catalysts in PEM Water Electrolysis

Altogether five platinum group metal (PGM) and PGM-free cathode catalysts were investigated in full PEM water electrolysis cells regarding their polarisation behaviour and their hydrogen and oxygen recombination properties. It was shown that the recombination activity of permeated oxygen and evolved hydrogen within the cathodic catalyst layer correlates with the activity of the oxygen reduction reaction (ORR) which was determined ex situ with linear sweep voltammetry. We found that the investigated PGM-free cathode catalysts had a low activity for the ORR resulting in higher measurable oxygen in hydrogen volume fractions compared to the PGM catalysts, which are more active for the ORR. Out of the three investigated PGM-free catalysts, only one commercially available material based on a Ti suboxide showed a similar good polarisation behaviour as the state of the art cathode catalyst platinum, while its recombination activity was the lowest of all catalysts. In addition to the recombination of hydrogen and oxygen on the electrocatalysts, we found that the prevalent carbon-based cathodic porous transport layers (PTL) also offer catalytically active recombination sites. In comparison to an inactive PTL, the measurable oxygen flux using carbon-based PTLs was lower and the recombination was enhanced by microporous coatings with high surface areas.BMBF, 03SF0536F, Verbundvorhaben PowerMEE: Lebensdauer- und Leistungserhöhung (POWER) von Polymerelektrolytmembranelektrolyseuren durch Hochleistungsmembranelektrodeneinheiten (MEE) - Teilprojekt: Herstellung von Membran Elektrodeneinheiten und tomographische Analys

Commonality and variation in mental representations of music revealed by a cross-cultural comparison of rhythm priors in 15 countries

Music is present in every known society but varies from place to place. What, if anything, is universal to music cognition? We measured a signature of mental representations of rhythm in 39 participant groups in 15 countries, spanning urban societies and Indigenous populations. Listeners reproduced random 'seed' rhythms; their reproductions were fed back as the stimulus (as in the game of 'telephone'), such that their biases (the prior) could be estimated from the distribution of reproductions. Every tested group showed a sparse prior with peaks at integer-ratio rhythms. However, the importance of different integer ratios varied across groups, often reflecting local musical practices. Our results suggest a common feature of music cognition: discrete rhythm 'categories' at small-integer ratios. These discrete representations plausibly stabilize musical systems in the face of cultural transmission but interact with culture-specific traditions to yield the diversity that is evident when mental representations are probed across many cultures. [Abstract copyright: © 2024. The Author(s).

An animal-specific FSI model of the abdominal aorta in anesthetized mice

Recent research has revealed that angiotensin II-induced abdominal aortic aneurysm in mice can be related to medial ruptures occurring in the vicinity of abdominal side branches. Nevertheless a thorough understanding of the biomechanics near abdominal side branches in mice is lacking. In the current work we present a mouse-specific fluid-structure interaction (FSI) model of the abdominal aorta in ApoE(-/-) mice that incorporates in vivo stresses. The aortic geometry was based on contrast-enhanced in vivo micro-CT images, while aortic flow boundary conditions and material model parameters were based on in vivo high-frequency ultrasound. Flow waveforms predicted by FSI simulations corresponded better to in vivo measurements than those from CFD simulations. Peak-systolic principal stresses at the inner and outer aortic wall were locally increased caudal to the celiac and left lateral to the celiac and mesenteric arteries. Interestingly, these were also the locations at which a tear in the tunica media had been observed in previous work on angiotensin II-infused mice. Our preliminary results therefore suggest that local biomechanics play an important role in the pathophysiology of branch-related ruptures in angiotensin-II infused mice. More elaborate follow-up research is needed to demonstrate the role of biomechanics and mechanobiology in a longitudinal setting