Atomic structure of surface defects in alumina studied by dynamic force microscopy: strain-relief-, translation- and reflection-related boundaries, including their junctions

We present an extensive atomic resolution frequency modulation dynamic force microscopy study of ultrathin aluminium oxide on a single crystalline NiAl(110) surface. One-dimensional surface defects produced by domain boundaries have been resolved. Images are presented for reflection domain boundaries (RDBs), four different types of antiphase domain boundaries, a nucleation-related translation domain boundary and also domain boundary junctions. New structures and aspects of the boundaries and their network are revealed and merged into a comprehensive picture of the defect arrangements. The alumina film also covers the substrate completely at the boundaries and their junctions and follows the structural building principles found in its unit cell. This encompasses square and rectangular groups of surface oxygen sites. The observed structural elements can be related to the electronic signature of the boundaries and therefore to the electronic defects associated with the boundaries. A coincidence site lattice predicted for the RDBs is in good agreement with experimental data. With Σ = 19 it can be considered to be of low-sigma type, which frequently coincides with special boundary properties. Images of asymmetric RDBs show points of good contact alternating with regions of nearly amorphous disorder in the oxygen sublattice

New Cataclysmic Variables and other Exotic Binaries in the Globular Cluster 47 Tucanae

We present 22 new (+3 confirmed) cataclysmic variables (CVs) in the non core-collapsed globular cluster 47 Tucanae (47 Tuc). The total number of CVs in the cluster is now 43, the largest sample in any globular cluster so far. For the identifications we used near-ultraviolet (NUV) and optical images from the Hubble Space Telescope, in combination with X-ray results from the Chandra X-ray Observatory. This allowed us to build the deepest NUV CV luminosity function of the cluster to date. We found that the CVs in 47 Tuc are more concentrated towards the cluster center than the main sequence turnoff stars. We compared our results to the CV populations of the core-collapsed globular clusters NGC 6397 and NGC 6752. We found that 47 Tuc has fewer bright CVs per unit mass than those two other clusters. That suggests that dynamical interactions in core-collapsed clusters play a major role creating new CVs. In 47 Tuc, the CV population is probably dominated by primordial and old dynamically formed systems. We estimated that the CVs in 47 Tuc have total masses of approx. 1.4 M_sun. We also found that the X-ray luminosity function of the CVs in the three clusters is bimodal. Additionally, we discuss a possible double degenerate system and an intriguing/unclassified object. Finally, we present four systems that could be millisecond pulsar companions given their X-ray and NUV/optical colors. For one of them we present very strong evidence for being an ablated companion. The other three could be CO- or He-WDs.Comment: Published on MNRAS. 31 Pages, 23 Figures, 5 Tables. Minor changes with respect to previous arXiv versio

Discovery of near-ultraviolet counterparts to millisecond pulsars in the globular cluster 47 Tucanae

We report the discovery of the likely white dwarf companions to radio millisecond pulsars 47 Tuc Q and 47 Tuc S in the globular cluster 47 Tucanae. These blue stars were found in near-ultraviolet images from the Hubble Space Telescope for which we derived accurate absolute astrometry, and are located at positions consistent with the radio coordinates to within 0.016 arcsec (0.2sigma). We present near-ultraviolet and optical colours for the previously identified companion to millisecond pulsar 47 Tuc U, and we unambiguously confirm the tentative prior identifications of the optical counterparts to 47 Tuc T and 47 Tuc Y. For the latter, we present its radio-timing solution for the first time. We find that all five near-ultraviolet counterparts have U300-B390 colours that are consistent with He white dwarf cooling models for masses ~0.16-0.3 Msun and cooling ages within ~0.1-6 Gyr. The Ha-R625 colours of 47 Tuc U and 47 Tuc T indicate the presence of a strong Ha absorption line, as expected for white dwarfs with an H envelope.Comment: Accepted for publication on MNRAS. 12 pages, 5 figures, 3 table

Bayesian Estimation of Hardness Ratios: Modeling and Computations

A commonly used measure to summarize the nature of a photon spectrum is the so-called Hardness Ratio, which compares the number of counts observed in different passbands. The hardness ratio is especially useful to distinguish between and categorize weak sources as a proxy for detailed spectral fitting. However, in this regime classical methods of error propagation fail, and the estimates of spectral hardness become unreliable. Here we develop a rigorous statistical treatment of hardness ratios that properly deals with detected photons as independent Poisson random variables and correctly deals with the non-Gaussian nature of the error propagation. The method is Bayesian in nature, and thus can be generalized to carry out a multitude of source-population--based analyses. We verify our method with simulation studies, and compare it with the classical method. We apply this method to real world examples, such as the identification of candidate quiescent Low-mass X-ray binaries in globular clusters, and tracking the time evolution of a flare on a low-mass star.Comment: 43 pages, 10 figures, 3 tables; submitted to Ap

Constraining the nature of the accreting binary in CXOGBS J174623.5-310550

We report optical and infrared observations of the X-ray source CXOGBS J174623.5-310550. This Galactic object was identified as a potential quiescent low-mass X-ray binary accreting from an M-type donor on the basis of optical spectroscopy and the broad Halpha emission line. The analysis of X-shooter spectroscopy covering 3 consecutive nights supports an M2/3-type spectral classification. Neither radial velocity variations nor rotational broadening is detected in the photospheric lines. No periodic variability is found in I- and r'-band light curves. We derive r' = 20.8, I = 19.2 and Ks = 16.6 for the optical and infrared counterparts with the M-type star contributing 90% to the I-band light. We estimate its distance to be 1.3-1.8 kpc. The lack of radial velocity variations implies that the M-type star is not the donor star in the X-ray binary. This could be an interloper or the outer body in a hierarchical triple. We constrain the accreting binary to be a < 2.2 hr orbital period eclipsing cataclysmic variable or a low-mass X-ray binary lying in the foreground of the Galactic Bulge.Comment: (9 pages, 5 figures, accepted for publication in MNRAS

Spectroscopic classification of X-ray sources in the Galactic Bulge Survey

We present the classification of 26 optical counterparts to X-ray sources discovered in the Galactic Bulge Survey. We use (time-resolved) photometric and spectroscopic observations to classify the X-ray sources based on their multi-wavelength properties. We find a variety of source classes, spanning different phases of stellar/binary evolution. We classify CX21 as a quiescent cataclysmic variable (CV) below the period gap, and CX118 as a high accretion rate (nova-like) CV. CXB12 displays excess UV emission, and could contain a compact object with a giant star companion, making it a candidate symbiotic binary or quiescent low mass X-ray binary (although other scenarios cannot be ruled out). CXB34 is a magnetic CV (polar) that shows photometric evidence for a change in accretion state. The magnetic classification is based on the detection of X-ray pulsations with a period of 81 $\pm$ 2 min. CXB42 is identified as a young stellar object, namely a weak-lined T Tauri star exhibiting (to date unexplained) UX Ori-like photometric variability. The optical spectrum of CXB43 contains two (resolved) unidentified double-peaked emission lines. No known scenario, such as an AGN or symbiotic binary, can easily explain its characteristics. We additionally classify 20 objects as likely active stars based on optical spectroscopy, their X-ray to optical flux ratios and photometric variability. In 4 cases we identify the sources as binary stars.Comment: Accepted for publication in MNRA

Photoswitching in nanoporous, crystalline solids: an experimental and theoretical study for azobenzene linkers incorporated in MOFs

In this article, we use the popular photoswitchable molecule, azobenzene, to demonstrate that the embedding in a nanoporous, crystalline solid enables a precise understanding of light-induced, reversible molecular motion. We investigate two similar azobenzene-containing, pillared-layer metal–organic frameworks (MOFs): Cu2(AzoBPDC)2(BiPy) and Cu2(NDC)2(AzoBiPy). Experimental results from UV-vis spectroscopy and molecular uptake experiments as well as theoretical results based on density-functional theory (DFT) show that in the Cu2(AzoBPDC)2(BiPy) MOF structure, the azobenzene side groups undergo photoisomerization when irradiated with UV or visible light. In a very similar MOF structure, Cu2(NDC)2(AzoBiPy), the experimental studies show an unexpected absence of photoisomerization. The DFT calculations reveal that in both MOFs the initial and final states of the photoswitching process (the trans and the cis conformation) have similar energies, which strongly suggests that the reason for the effective blocking of photoswitching in the AzoBiPy-based MOFs must be related to the switching process itself. More detailed calculations show that in Cu2(NDC)2(AzoBiPy) a naphthalene linker from the molecular framework blocks the photoisomerization trajectory which leads from the trans to the cis conformation. For Cu2(AzoBPDC)2(BiPy), as a result of the different geometry, such a steric hindrance is absent

The X-ray source population of the globular cluster M15: Chandra high resolution imaging

The globular cluster M15 was observed on three occasions with the High Resolution Camera on board Chandra in 2001 in order to investigate the X-ray source population in the cluster centre. After subtraction of the two bright central sources, four faint sources were identified within 50 arcsec of the core. One of these sources is probably the planetary nebula, K648, making this the first positive detection of X-rays from a planetary nebula inside a globular cluster. Another two are identified with UV variables (one previously known), which we suggest are cataclysmic variables (CVs). The nature of the fourth source is more difficult to ascertain, and we discuss whether it is possibly a quiescent soft X-ray transient (qSXT) or also a CV.Comment: 9 pages, 6 figures, accepted for publication in MNRAS. Original figures can be obtained from http://www.astro.helsinki.fi/~diana/M15.htm