O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission

Oxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon?photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core?valence double excitations, while shape resonances are suppressed. In contrast, the partial fluorescence yield in the wavelength window 300?650 nm and the excitation functions of selected O+ and C+ emission lines in the wavelength range 400?500 nm display all of the absorption features. The relative intensity of ionic emission in the visible range increases towards higher photon energies, which is attributed to O 1s shake-off photoionization. VUV photon?photoion coincidence spectra reveal major contributions from the C+ and O+ ions and a minor contribution from C2+. No conclusive changes in the intensity ratios among the different ions are observed above the O 1s threshold. The line shape of the VUV?O+ coincidence peak in the mass spectrum carries some information on the initial core excitatio

Effective Rheology of Bubbles Moving in a Capillary Tube

We calculate the average volumetric flux versus pressure drop of bubbles moving in a single capillary tube with varying diameter, finding a square-root relation from mapping the flow equations onto that of a driven overdamped pendulum. The calculation is based on a derivation of the equation of motion of a bubble train from considering the capillary forces and the entropy production associated with the viscous flow. We also calculate the configurational probability of the positions of the bubbles.Comment: 4 pages, 1 figur

Morphology and ecology of Thalassiosira Cleve (Bacillariophyta) species rarely recorded in Brazilian coastal waters

The detailed description of rarely recorded Thalassiosira species in Brazil is presented with light microscope (LM) and scanning electron microscope (SEM) illustrations. A total of 78 phytoplankton net samples (20 µm) collected between the years 2000 and 2006 in coastal waters of southern Brazilian, Cassino Beach and the estuary of Lagoa dos Patos, were studied in cleaned material using the Axiovert Zeiss LM and Jeol 6060 SEM. Water temperature and salinity of samples and six species are presented: Thalassiosira endoseriata, T. hendeyi, T. lundiana, T. minuscula, T. oceanica and T. wongii. Two species, Thalassiosira hendeyi and T. endoseriata were the most common being observed in all seasons at Cassino Beach in a widen temperature range (10-26 ºC), while only sporadically in the estuary of Lagoa dos Patos. Thalassiosira endoseriata, T. lundiana, T. oceanica and T. wongii are for the first time reported in Brazilian coastal waters. The latter two species, rarely recorded in the world, are fully illustrated based on Brazilian material.A descrição detalhada de seis espécies de Thalassiosira raramente registradas no Brasil é apresentada com ilustrações em microscopia óptica (MO) e microscopia eletrônica de varredura (MEV). Foram estudadas 78 amostras de rede (malha de 20 µm) coletadas entre os anos de 2000 e 2006 em águas costeiras do sul do Brasil, na praia do Cassino e no estuário da Lagoa dos Patos. Dados relativos à temperatura da água e salinidade são apresentados. Thalassiosira endoseriata, T. hendeyi, T. lundiana, T. minuscula, T. oceanica e T. wongii foram estudadas em amostras oxidadas ao MO Axiovert Zeiss e MEV Jeol 6060. Thalassiosira hendeyi e T. endoseriata foram as espécies mais comumente observadas in todas as estações do ano na praia do Cassino em uma grande amplitude de temperatura (10-26 ºC), mas foram observadas esporadicamente no estuário da Lagoa dos Patos.Thalassiosira endoseriata, T. lundiana, T. oceanica e T. wongii são, pela primeira vez, registradas em águas costeiras brasileiras. As duas últimas espécies, raramente registradas em águas costeiras em geral, são ilustradas em detalhe com espécimens brasileiros

Changes in phytoplankton composition in response to tides, wind-induced mixing conditions, and freshwater outflows in an urbanised estuarine complex

Recent reports have shown an increase in potentially harmful phytoplankton in Santos bay (Southeastern Brazilian Coast), located in a highly urbanised estuarine complex. Prediction of blooms is, thus, essential but the phytoplankton community structure in very dynamic regions is difficult to determine. In the present work, we discriminate bloom forming microphytoplankton dominance and their relationship to physical and meteorological variables to look for patterns observed in different tides and seasons. Comparing 8 distinct situations, we found five scenarios of dominance that could be related to winds, tides and rainfall: i) Surfers, diatoms occurring during high surf zone energies; ii) Sinkers, represented by larger celled diatoms during spring tide, after periods of high precipitation rates; iii) Opportunistic mixers, composed of chain forming diatoms with small or elongate cells occurring during neap tides; iv) Local mixers, microplanktonic diatoms and dinoflagellates which occurred throughout the 298 sampling stations; and v) Mixotrophic dinoflagellates, after intense estuarine discharges. Results suggest alterations in the temporal patterns for some bloom-forming species, while others appeared in abundances above safe limits for public health. This approach can also illustrate possible impacts of changes in freshwater discharge in highly urbanised estuaries

Reflecting on siliceous rocks in central Australia: using advanced remote sensing to map ancient “tool-stone” resources

HyMap™ airborne hyperspectral imagery was used to discriminate and map hydrated silica mineralization in the Dalhousie Springs area of central Australia. A spectral feature fitting algorithm was used to match laboratory reference spectra with image pixel spectra, producing a scaled goodness-of-fit raster map of silicified “tool-stone” sources in our study area. Subsequent fieldwork indicated that the algorithm mapped silcrete, a rock composed of hydrated silica, and incidentally, the most frequently utilized raw material for stone artifact manufacture in this area of the Australian arid zone. The soundness of our hydrated silica mineralization map is supported with field observations and spectroscopic analysis of collected silcrete samples. Independent siliceous rock mapping produced by the Commonwealth Scientific and Industry Research Organization offers additional corroboration of our results. Based on the success of our approach, we suggest that archaeologists working in Australia and in similar arid environments elsewhere have much to benefit in using advanced remote sensing products to map lithic resources, including time and cost-saving advantages for field logistics, enriched assessments of land suitability for archaeological site types, and an improved understanding of resource distributions