8 research outputs found

    Erratum to: 36th International Symposium on Intensive Care and Emergency Medicine

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    [This corrects the article DOI: 10.1186/s13054-016-1208-6.]

    Peculiar behavior of the ester carbonyl vibrational modes in anisotropic aliphatic and semi-aromatic polyesters

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    The current work reports on a systematic study related to the vibrational modes of the ester carbonyl group in drawn polyesters. We have observed and try to explain how the presence of aromatic units in the molecular structure substantially affects the respective elements of the Raman tensor in contrast to the dipole moment derivative vector which is only marginally influenced. The work is based on the collection of polarized Raman spectra and FTIR dichroism measurements on the one hand and on DFT calculations on the other. The experimental data were obtained from uniaxially stretched aliphatic and semi-aromatic polyesters. The calculations were applied on relevant oriented oligomers and allowed the extraction: (i) of reliable Raman/FTIR vibrational spectra and (ii) the components of the dipole moment derivative and Raman tensor of the vibrational modes and in particular the ones involving the ester carbonyl group. Experimental data indicate that the intensity of the ester carbonyl band is considerably enhanced in the Raman spectra of semi-aromatic polyesters, which results from a considerable enhancement of the related coupling coefficient. Furthermore, the angles of the principle Raman tensor axis are rotated so that the element of the tensor with the greatest value is oriented towards the direction designated by the segment. The latter explains the peculiar experimentally indicated anisotropy, through the ester carbonyl stretching, for the case of semi-aromatic polyesters, which is totally different with that observed in the aliphatic ones. © 2021 Elsevier B.V

    36th International Symposium on Intensive Care and Emergency Medicine : Brussels, Belgium. 15-18 March 2016.

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    Mental Health in Head and Neck Cancer

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    Acknowledging the health behaviors that lead to HNC, as well as the highly impactful location and functional changes from the cancer and treatment, has led to increasing interest in MH in HNC. The distressing aspects of HNC affect patients, their caregivers, and their physicians alike. MH must be a priority from diagnosis through to the end of these patients’ lives. Here we have summarized the known elements of MH in HNC. We have determined that health behaviors, such as tobacco use, alcohol use, and high-risk sexual behaviors that lead to heighten HPV infection risk, play a long-lasting and complex role with distress levels in HNC. Psychiatric illness is one aspect of psychosocial distress that can more easily be studied due to existing clinical frameworks from which to begin investigation, though other elements of distress are more difficult to identify and quantify. We have highlighted advances in stress management for improving MH in these patients, most notably cognitive behavioral therapy-based interventions. This summary has led to the conclusion that the best is yet to come, with the open opportunities to define the mental health challenges in the landscape of HNC, to generate effective and validated treatments, and to pair treatments with patients and their caregivers

    Erratum to: 36th International Symposium on Intensive Care and Emergency Medicine

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