Analytical electrochemiluminescence

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Experimental and Theoretical Advances on Single Atom and Atomic Cluster-Decorated Low-Dimensional Platforms towards Superior Electrocatalysts

The fundamental relationship between structure and properties, which is called “structure-property”, plays a vital role in the rational designing of high-performance catalysts for diverse electrocatalytic applications. Low-dimensional (LD) nanomaterials, including 0D, 1D, 2D materials, combined with low-nuclearity metal atoms, ranging from single atoms to subnanometer clusters, are currently emerging as rising star nanoarchitectures for heterogeneous catalysis due to their well-defined active sites and unbeatable metal utilization efficiencies. In this work, a comprehensive experimental and theoretical review is provided on the recent development of single atom and atomic cluster-decorated LD platforms towards some typical clean energy reactions, such as water-splitting, nitrogen fixation, and carbon dioxide reduction reactions. The upmost attractive structural properties, advanced characterization techniques, and theoretical principles of these low-nuclearity electrocatalysts as well as their applications in key electrochemical energy devices are also elegantly discussed

Tree ring δ18O reveals no long-term change of atmospheric water demand since 1800 in the northern Great Hinggan Mountains, China

Global warming will significantly increase transpirational water demand, which could dramatically affect plant physiology and carbon and water budgets. Tree ring δ18O is a potential index of the leaf-to-air vapor-pressure deficit (VPD) and therefore has great potential for long-term climatic reconstruction. Here we developed δ18O chronologies of two dominant native trees, Dahurian larch (Larix gmelinii Rupr.) and Mongolian pine (Pinus sylvestris var. mongolica), from a permafrost region in the Great Hinggan Mountains of northeastern China. We found that the July–August VPD and relative humidity were the dominant factors that controlled tree ring δ18O in the study region, indicating strong regulation of stomatal conductance. Based on the larch and pine tree ring δ18O chronologies, we developed a reliable summer (July–August) VPD reconstruction since 1800. Warming growing season temperatures increase transpiration and enrich cellulose 18O, but precipitation seemed to be the most important influence on VPD changes in this cold region. Periods with stronger transpirational demand occurred around the 1850s, from 1914 to 1925, and from 2005 to 2010. However, we found no overall long-term increasing or decreasing trends for VPD since 1800, suggesting that despite the increasing temperatures and thawing permafrost throughout the region, forest transpirational demand has not increased significantly during the past two centuries. Under current climatic conditions, VPD did not limit growth of larch and pine, even during extremely drought years. Our findings will support more realistic evaluations and reliable predictions of the potential influences of ongoing climatic change on carbon and water cycles and on forest dynamics in permafrost regions

New anti-corrosion inhibitor (3ar,6ar)-3a,6a-di-p-tolyltetrahydroimidazo[4,5-d]imidazole-2,5(1 h,3h)-dithione for carbon steel in 1 M HCl medium: gravimetric, electrochemical, surface and quantum chemical analyses

The inhibition of (3ar,6ar)-3a,6a-di-p-tolyltetrahydroimidazo[4,5-d]imidazole-2,5(1 h,3h)-dithione (TTHIIDT) for carbon steel was full characterized in a 1 M hydrochloride acid environment at various inhibitor concentrations and temperatures by the gravimetric, electrochemical, surface and quantum chemical analyses. The obtained results confirmed that the inhibition efficiency of TTHIIDT was over 95–97% and nearly stable in the rise of temperature and concentration; TTHIIDT was mixed type inhibitor and effectively influenced both anodic and cathodic corrosion reactions; a protective hydrophobic thin layer of this inhibitor on the carbon steel surface is more stable and non soluble in 1 M HCl medium; this inhibitor adsorbed endothermically on the carbon steel surface by the chemical and physical adsorption processes. The quantum chemical calculations supported the experimental results and showed that the inhibition efficiency is depends on the structure of inhibitor

Jet stream position explains regional anomalies in European beech forest productivity and tree growth

The mechanistic pathways connecting ocean-atmosphere variability and terrestrial productivity are well-established theoretically, but remain challenging to quantify empirically. Such quantification will greatly improve the assessment and prediction of changes in terrestrial carbon sequestration in response to dynamically induced climatic extremes. The jet stream latitude (JSL) over the North Atlantic-European domain provides a synthetic and robust physical framework that integrates climate variability not accounted for by atmospheric circulation patterns alone. Surface climate impacts of north-south summer JSL displacements are not uniform across Europe, but rather create a northwestern-southeastern dipole in forest productivity and radial-growth anomalies. Summer JSL variability over the eastern North Atlantic-European domain (5-40E) exerts the strongest impact on European beech, inducing anomalies of up to 30% in modelled gross primary productivity and 50% in radial tree growth. The net effects of JSL movements on terrestrial carbon fluxes depend on forest density, carbon stocks, and productivity imbalances across biogeographic regions

Rational Design of Electrochemiluminescent Devices

ConspectusElectrochemiluminescence (ECL) is a light-emitting process which combines the intriguing merits of both electrochemical and chemiluminescent methods. It is an extensively used method especially in clinical analysis and biological research due to its high sensitivity, wide dynamic range, and good reliability. ECL devices are critical for the development and applications of ECL. Much effort has been expended to improve the sensitivity, portability, affordability, and throughput of new ECL devices, which allow ECL to adapt broad usage scenarios.In this Account, we summarize our efforts on the recent development of ECL devices including new electrodes, ECL devices based on a wireless power transfer (WPT) technique, and novel bipolar electrochemistry. As the essential components in the ECL devices, electrodes play an important role in ECL detection. We have significantly improved the sensitivity of luminol ECL detection of H2O2 by using a stainless steel electrode. By using semiconductor materials (e.g., silicon and BiVO4), we have exploited photoinduced ECL to generate intense emission at much lower potentials upon illumination. For convenience, portability, and disposability, ECL devices based on cheap WPT devices have been designed. A small diode has been employed to rectify alternating current into direct current to dramatically enhance ECL intensity, enabling sensitive ECL detection using a smart phone as a detector. Finally, we have developed several ECL devices based on bipolar electrochemistry in view of the convenience of multiplex ECL sensing using a bipolar electrode (BPE). On the basis of the wireless feature of BPE, we have employed movable BPEs (e.g., BPE swimmers and magnetic rotating BPE) for deep exploration of the motional and ECL properties of dynamic BPE systems. To make full use of the ECL solution, we have dispersed numerous micro-/nano-BPEs in solution to produce intense 3D ECL in the entire solution, instead of 2D ECL in conventional ECL devices. In addition, the interference of ECL noise from driving electrodes was minimized by introducing the stainless steel with a passivation layer as the driving electrode. To eliminate the need for the fabrication of electrode arrays and the interference from the driving electrode and to decrease the applied voltage, we develop a new-type BPE device consisting of a single-electrode electrochemical system (SEES) based on a resistance-induced potential difference. The SEES is fabricated easily by attaching a multiperforated plate to a single film electrode. It enables the simultaneous detection of many samples and analytes using only a single film electrode (e.g., screen-printed electrode) instead of electrode arrays. It is of great potential in clinical analysis especially for multiple-biomarker detection, drug screening, and biological studies. Looking forward, we believe that more ECL devices and related ECL materials and detection methods will be developed for a wide range of applications, such as in vitro diagnosis, point-of-care testing, high-throughput analysis, drug screening, biological study, and mechanism investigation.Conversion lumineuse par électrochimiluminescence photoinduit

Family-clinician shared decision making in intensive care units : cluster randomized trial in China

We thank the China Medical Board, which financially supported our study.Objective To investigate if a Family-Clinician Shared Decision-Making (FCSDM) intervention benefits patients, families and intensive care units (ICUs) clinicians.  Methods Six ICUs in China were allocated to intervention or usual care. 548 patients with critical illness, 548 family members and 387 ICU clinicians were included into the study. Structured FCSDM family meetings were held in the intervention group. Scales of SSDM, HADS, QoL2 and CSACD were used to assess families’ satisfaction and distress, patients’ quality of life, and clinicians’ collaboration respectively.  Results Comparing the intervention group with the control group at post-intervention, there were significant differences in the families’ satisfaction (P =0.0001), depression level (P =0.005), and patients’ quality of life (P =0.0007). The clinicians’ mean CSCAD score was more positive in the intervention group than controls (P < 0.05). There was no significant between-group differences on ICU daily medical cost, but the intervention group demonstrated shorter number of days’ stay in ICU (P=0.0004).  Conclusion The FCSDM intervention improved families’ satisfaction and depression, shortened patients’ duration of ICU stay, and enhanced ICU clinicians’ collaboration.  Practice implications Further improvement and promotion of the FCSDM model are needed to provide more evidence to this field in China.Publisher PDFPeer reviewe

Nitrogen rather than streamflow regulates the growth of riparian trees

In arid and semiarid regions, riparian forests are crucial for maintaining ecological biodiversity and sustainability, and supporting social and economic development. For the typical arid and semiarid ecosystem, streamflow variability is thought to be the dominant factor influencing the vulnerability and evolution of the riparian forests, which often leads to the neglect of other potentially important factors such as nutrient availability and transport. Here, we measured annual stable nitrogen isotopes (δ15N) and nitrogen concentrations (N%) in the tree rings of Populus euphratica Oliv. (Euphrates poplar) over a 90 year period (1920–2012), collected from the lower researches of the inland Heihe River, northwestern China. Coupling with our previous dual-isotope (δ13C and δ18O) chronologies and estimated intrinsic water-use efficiency (iWUE), we examined the linkages between tree-ring δ15N and δ18O, iWUE, streamflow, and then explored the contributions of each to tree growth during the study period. Our results show that after 1975, a statistically significant correlation between tree-ring δ15N and river streamflow appears, indicating the river as a potential carrier of nitrogen from the upper and middle reaches to the lower research trees. In addition, the linkage between tree-ring δ15N and iWUE suggests substantial influence of carbon and nitrogen together on photosynthesis and transpiration of trees, although this connection become decoupled since AD 1986. The commonality analysis revealed that the nitrogen impacts indicated by tree-ring δ15N on tree growth cannot be ignored when evaluating riparian forest development. The fertilization effects caused by rising CO2 concentration complicate the nitrogen constraints on tree growth during the later part of the past century. Our results have potentially broad implications for identifying the limited factors for dryland forest ecosystems that are susceptible to natural water resource variations and human activities

Dense matter with eXTP

In this White Paper we present the potential of the Enhanced X-ray Timing and Polarimetry (eXTP) mission for determining the nature of dense matter; neutron star cores host an extreme density regime which cannot be replicated in a terrestrial laboratory. The tightest statistical constraints on the dense matter equation of state will come from pulse profile modelling of accretion-powered pulsars, burst oscillation sources, and rotation-powered pulsars. Additional constraints will derive from spin measurements, burst spectra, and properties of the accretion flows in the vicinity of the neutron star. Under development by an international Consortium led by the Institute of High Energy Physics of the Chinese Academy of Science, the eXTP mission is expected to be launched in the mid 2020s.Comment: Accepted for publication on Sci. China Phys. Mech. Astron. (2019