The Origin of Nitrogen on Jupiter and Saturn from the 15^{15}N/14^{14}N Ratio

The Texas Echelon cross Echelle Spectrograph (TEXES), mounted on NASA's Infrared Telescope Facility (IRTF), was used to map mid-infrared ammonia absorption features on both Jupiter and Saturn in February 2013. Ammonia is the principle reservoir of nitrogen on the giant planets, and the ratio of isotopologues ($^{15}$N/$^{14}$N) can reveal insights into the molecular carrier (e.g., as N$_2$ or NH$_3$) of nitrogen to the forming protoplanets, and hence the source reservoirs from which these worlds accreted. We targeted two spectral intervals (900 and 960 cm$^{-1}$) that were relatively clear of terrestrial atmospheric contamination and contained close features of $^{14}$NH$_3$ and $^{15}$NH$_3$, allowing us to derive the ratio from a single spectrum without ambiguity due to radiometric calibration (the primary source of uncertainty in this study). We present the first ground-based determination of Jupiter's $^{15}$N/$^{14}$N ratio (in the range from $1.4\times10^{-3}$ to $2.5\times10^{-3}$), which is consistent with both previous space-based studies and with the primordial value of the protosolar nebula. On Saturn, we present the first upper limit on the $^{15}$N/$^{14}$N ratio of no larger than $2.0\times10^{-3}$ for the 900-cm$^{-1}$ channel and a less stringent requirement that the ratio be no larger than $2.8\times10^{-3}$ for the 960-cm$^{-1}$ channel ($1\sigma$ confidence). Specifically, the data rule out strong $^{15}$N-enrichments such as those observed in Titan's atmosphere and in cometary nitrogen compounds. To the extent possible with ground-based radiometric uncertainties, the saturnian and jovian $^{15}$N/$^{14}$N ratios appear indistinguishable, implying that $^{15}$N-enriched ammonia ices could not have been a substantial contributor to the bulk nitrogen inventory of either planet, favouring the accretion of primordial N$_2$ from the gas phase or as low-temperature ices.Comment: 33 pages, 19 figures, manuscript accepted for publication in Icaru

H2 Mid-IR Pure Rotational Emission from Young Stars: The TEXES/IRTF Survey

We describe the TEXES survey for mid-IR H2 pure rotational emission from young stars and report early successes. H2 emission is a potential tracer of warm gas in circumstellar disks. Three pure rotational lines are available from the ground: the J=3=>1, J=4=>2, and J=6=>4, transitions at 17.035 microns, 12.279 microns, and 8.025 microns, respectively. Using TEXES at the NASA IRTF 3m, we are midway through a survey of roughly 30 pre-main-sequence stars. To date, detected lines are all resolved, generally with FWHM<10 km/s. Preliminary analysis suggests the gas temperatures are between 400 and 800 K. From the work so far, we conclude that high spectral and spatial resolution are critical to the investigation of H2 in disks.Comment: 6 pages, to appear in Proceedings of the ESO Workshop on "High Resolution Infrared Spectroscopy in Astronomy" held in Garching, Germany, 18-21 November 200

Lipid bilayer thickness determines cholesterol's location in model membranes

Cholesterol is an essential biomolecule of animal cell membranes, and an important precursor for the biosynthesis of certain hormones and vitamins. It is also thought to play a key role in cell signaling processes associated with functional plasma membrane microdomains (domains enriched in cholesterol), commonly referred to as rafts. In all of these diverse biological phenomena, the transverse location of cholesterol in the membrane is almost certainly an important structural feature. Using a combination of neutron scattering and solid-state 2H NMR, we have determined the location and orientation of cholesterol in phosphatidylcholine (PC) model membranes having fatty acids of different lengths and degrees of unsaturation. The data establish that cholesterol reorients rapidly about the bilayer normal in all the membranes studied, but is tilted and forced to span the bilayer midplane in the very thin bilayers. The possibility that cholesterol lies flat in the middle of bilayers, including those made from PC lipids containing polyunsaturated fatty acids (PUFAs), is ruled out. These results support the notion that hydrophobic thickness is the primary determinant of cholesterol's location in membranes

W51 IRS 2: A Massive Jet Emerging from a Molecular Cloud into an H II Region

We have mapped [Ne II] (12.8um) and [S IV] (10.5um) emission from W51 IRS 2 with TEXES on Gemini North, and we compare these data to VLA free-free observations and VLT near-infrared images. With 0.5" spatial and 4 km/s spectral resolution we are able to separate the ionized gas into several components: an extended H II region on the front surface of the molecular cloud, several embedded compact H II regions, and a streamer of high velocity gas. We interpret the high velocity streamer as a precessing or fan-like jet, which has emerged from the molecular cloud into an OB star cluster where it is being ionized.Comment: 3 pages, 4 figures, 2 movie

Language support for immigrant children: a study of state schools in the UK and US

In recent decades, immigrants, refugees and asylum seekers have sought a new way of life in large numbers, often leaving their countries of origin behind in search of places that offer a better way of life. The purpose of this study was to investigate how elementary and middle school students in state schools in Reading, England (primarily speakers of Asian languages), and Richmond, Virginia (primarily speakers of Spanish), were supported academically, when most children’s first language was not English. The authors were interested in exploring whether or not there were cultural or structural differences in the way each country helped or hindered these students as they progressed through the school systems. Three UK schools in a district of approximately 100,000 and three US schools in a district of approximately 250,000 were the focus of this exploration from 2000 to 2003. Findings indicated that there were cultural and legislative differences and similarities. Teachers and administrators in both countries attempted to provide services with limited and sometimes diminishing resources. Community support varied based on resources, attitudes toward various ethnic groups, and the coping strategies adopted by these groups in their new environments. Marked differences appeared with regard to the manner in which assessments took place and how the results were made available to the public

Trends in stream nitrogen concentrations for forested reference catchments across the USA

To examine whether stream nitrogen concentrations in forested reference catchments have changed over time and if patterns were consistent across the USA, we synthesized up to 44 yr of data collected from 22 catchments at seven USDA Forest Service Experimental Forests. Trends in stream nitrogen presented high spatial variability both among catchments at a site and among sites across the USA. We found both increasing and decreasing trends in monthly flow-weighted stream nitrate and ammonium concentrations. At a subset of the catchments, we found that the length and period of analysis influenced whether trends were positive, negative or non-significant. Trends also differed among neighboring catchments within several Experimental Forests, suggesting the importance of catchment-specific factors in determining nutrient exports. Over the longest time periods, trends were more consistent among catchments within sites, although there are fewer long-term records for analysis. These findings highlight the critical value of long-term, uninterrupted stream chemistry monitoring at a network of sites across the USA to elucidate patterns of change in nutrient concentrations at minimally disturbed forested sites

Enhanced C2_2H2_2 absorption within Jupiter's southern auroral oval from Juno UVS observations

Reflected sunlight observations from the Ultraviolet Spectrograph (UVS) on the Juno spacecraft were used to study the distribution of acetylene (C$_2$H$_2$) at Jupiter's south pole. We find that the shape of the C$_2$H$_2$ absorption feature varies significantly across the polar region, and this can be used to infer spatial variability in the C$_2$H$_2$ abundance. There is a localized region of enhanced C$_2$H$_2$ absorption which coincides with the location of Jupiter's southern polar aurora; the C$_2$H$_2$ abundance poleward of the auroral oval is a factor of 3 higher than adjacent quiescent, non-auroral longitudes. This builds on previous infrared studies which found enhanced C$_2$H$_2$ abundances within the northern auroral oval. This suggests that Jupiter's upper-atmosphere chemistry is being strongly influenced by the influx of charged auroral particles and demonstrates the necessity of developing ion-neutral photochemical models of Jupiter's polar regions.Comment: Accepted in JGR: Planet