Runoff and erosion at the micro-plot and slope scale in a small burnt catchment, central Portugal

Wildfires can have important impacts on hydrological processes and soil erosion in forest catchments, due to the destruction of vegetation cover and changes to soil properties. However, the processes involved are non-linear and not fully understood. This has severely limited the understanding on the impacts of wildfires, especially in the up-scaling from hillslopes to catchments; in consequence, current models are poorly adapted for burnt forest conditions. The objective of this presentation is to give an overview of the hydrological response and sediment yield from the micro-plot to slope scale, in the first year following a wildfire (2008/2009) that burnt an entire catchment nearby the Colmeal village, central Portugal. The overview will focus on three slopes inside the catchment, with samples including: • Runoff at micro-plot scale (12 bounded plots) and slope scale (12 open plots); • Sediments and Organic Matter loss at micro-plot scale (12 bounded plots) and slope scale (12 open plots plus 3 Sediment fences); • Rainfall and Soil moisture data; • Soil Water Repellency and Ground Cover data. The analysis of the first year following the wildfire clearly shows the complexity of runoff generation and the associated sediment transport in recently burnt areas, with pronounced differences between hillslopes and across spatial scales as well as with marked variations through time. This work was performed in the framework of the EROSFIRE-II project (PTDC/AGR-CFL/70968/2006) which has as overall aim to predict soil erosion risk in recently burnt forest areas, including common post-fire forest management practices; the project focuses on the simultaneous measurement of runoff and soil erosion at multiple spatial scales.The results to be presented in this session are expected to show how sediment is generated, transported and exported in the Colmeal watershed; and contribute to understand and simulate erosion processes in burnt catchments, including for model development and evaluation

Hydrological and erosion response at micro-plot to -catchment scale following forest wildfire, north-central Portugal

Wildfires can have important impacts on hydrological and soil erosion processes, due to the destruction of vegetation cover and changes to soil properties. According to Shakesby and Doerr (2006), these wildfire effects are: i) much better known at small spatial scales (especially erosion plots) than at the scale of catchments; ii) much better studied with respect to overland flow and streamflow (and, then, especially peak discharges) than to soil erosion. Following up on a precursor project studying runoff generation and the associated soil losses from micro-plot to slope-scale in Portuguese eucalypt forests, the EROSFIRE-II project addresses the connectivity of these processes across hillslopes as well as within the channel network. This is done in the Colmeal study area in central Portugal, where the outlet of an entirely burnt catchment of roughly 10 ha was instrumented with a gauging station continuously recording water level and tubidity, and five slopes were each equipped with 4 runoff plots of < 0,5 m2 (“micro-plot”) and 4 slope-scale plots as well as 1 slope-scale sediment fence. Starting one month after the August 2008 wildfire, the plots were monitored at 1- to 2-weekly intervals, depending on the occurrence of rainfall. The gauging station became operational at the end of November 2008, since the in-situ construction of an H-flume required several weeks. A preliminary analysis of the data collected till the end of 2008, focusing on two slopes with contrasting slope lengths as well as the gauging station: revealed clear differences in runoff and erosion between: (i) the micro-plot and slope-scale plots on the same hillslope; (ii) the two slopes; (iii) an initial dry period and a subsequent much wetter period; (iv) the slopes and the catchment-scale, also depending on the sampling period. These results suggest that the different processes govern the hydrological and erosion response at different spatial scales as well as for different periods, with soil water repellency playing a role during the initial post-fire period. The current presentation will review these preliminary results based on the data collected during the first year after the wildfire

Cephalopod identification keys to Histioteuthidae, Cranchiidae and Octopodiformes of the Azores, with an updated check-list

This work is a combination of unpublished cephalopod identification keys compiled by Malcolm R. Clarke for the Azores region (Central North Atlantic) and a review of the Octopoda of the Azores by João Gonçalves (MSc Thesis 1993, originally written in Portuguese), updated with recent literature. A regional list of cephalopod species of the Azores is provided totaling 83 species, with identification keys for: i) Histioteuthidae, including five species; ii) Cranchiidae, including eleven species; and iii) Octopodiformes, including Vampyroteuthis infernalis Chun, 1903 (Order Vampyromorpha), three cirrate and fourteen incirrate octopuses. Separate keys are given for Octopodiformes species. The revisions are discussed and a more detailed description of Octopoda species is included.Oma – Observatório do Mar dos Açores ; MARE – Centro de Ciências do Mar e do Ambiente ; IMAR – Instituto do Mar ; DOP – Departamento de Oceanografia e Pescas ; Universidade dos Açoresinfo:eu-repo/semantics/publishedVersio

Local knowledge management and innovation spillover

Tourism lifestyle entrepreneurs play an essential role in the innovation and competitiveness of tourist destinations. However, existing knowledge about the determinants of the innovation they generate is far from being fully exploited. There is still little knowledge about the innovation spillover effect, which is a determining factor for the destination's competitiveness. One of the key factors for innovation results from local knowledge management and the ability of tourism lifestyle entrepreneurs to turn this knowledge into innovation. To test the role of knowledge management in innovation and spillover, a survey was conducted on a sample of 115 tourism lifestyle entrepreneurs, with the hypotheses tested using structural equations. The results reveal that place attachment and knowledge acquisition have a direct effect on knowledge assimilation and community-centered strategy. Furthermore, it was also found that community-centered strategy and knowledge assimilation play a mediating role between place attachment and innovation capacity.info:eu-repo/semantics/publishedVersio

Molecular properties via a subsystem density functional theory formulation: A common framework for electronic embedding

In this article, we present a consistent derivation of a density functional theory (DFT) based embedding method which encompasses wave-function theory-in-DFT (WFT-in-DFT) and the DFT-based subsystem formulation of response theory (DFT-in-DFT) by Neugebauer [J. Neugebauer, J. Chem. Phys. 131, 084104 (2009)10.1063/1.3212883] as special cases. This formulation, which is based on the time-averaged quasi-energy formalism, makes use of the variation Lagrangian techniques to allow the use of non-variational (in particular: coupled cluster) wave-function-based methods. We show how, in the time-independent limit, we naturally obtain expressions for the ground-state DFT-in-DFT and WFT-in-DFT embedding via a local potential. We furthermore provide working equations for the special case in which coupled cluster theory is used to obtain the density and excitation energies of the active subsystem. A sample application is given to demonstrate the method. © 2012 American Institute of Physics

Characterization of knowledge and consumption of acetylsalicylic acid in users of community pharmacies

Acetylsalicylic acid (ASA) is one of the drugs most used by the Portuguese population for its anti-inflammatory, analgesic, antipyretic and antiplatelet effect. Thus, this study aimed to characterize the knowledge and the consumption pattern of ASA in users of community pharmacies of three locations in the district of Porto. The investigation was achieved by application of a questionnaire to 390 users of community pharmacies of three locations in the district of Porto (Lousada, Paços de Ferreira e Porto). The dosage of ASA most known and consumed was of 500mg (28.2 and 53%, respectively). Individuals considered having a level of knowledge "Reasonable" about this substance (47.8%). As regards the frequency of use, the most reported by respondents was once per year (48.3%), and time-consuming 1 to 3 days (37.8%). A considerable percentage of respondents indicating that ASA was prescribed by the doctor (36.4%) and on his own initiative (36.4%). The main reasons of use of AAS are flu (41.2%), pain head (40%) and fever (10.7%), have been noted adverse effects in 4.1% of consumers. It was found that the level of knowledge is higher in middle age (40-60 years) (p = 0.220) and in individuals with qualifications of 6-9th year. The present study denotes the existence of gaps of consistent, coherent and updated information about ASA drug

Performance of Graphene/Polydimethylsiloxane Surfaces against S. aureus and P. aeruginosa Single- and Dual-Species Biofilms

The increasing incidence of implant-associated infections has prompted the development of effective strategies to prevent biofilm formation on these devices. In this work, pristine graphene nanoplatelet/polydimethylsiloxane (GNP/PDMS) surfaces containing different GNP loadings (1, 2, 3, 4, and 5 wt%) were produced and evaluated on their ability to mitigate biofilm development. After GNP loading optimization, the most promising surface was tested against single- and dual-species biofilms of Staphylococcus aureus and Pseudomonas aeruginosa. The antibiofilm activity of GNP/PDMS surfaces was determined by the quantification of total, viable, culturable, and viable but nonculturable (VBNC) cells, as well as by confocal laser scanning microscopy (CLSM). Results showed that 5 wt% GNP loading reduced the number of total (57%), viable (69%), culturable (55%), and VBNC cells (85%) of S. aureus biofilms compared to PDMS. A decrease of 25% in total cells and about 52% in viable, culturable, and VBNC cells was observed for P. aeruginosa biofilms. Dual-species biofilms demonstrated higher resistance to the antimicrobial activity of GNP surfaces, with lower biofilm cell reductions (of up to 29% when compared to single-species biofilms). Still, the effectiveness of these surfaces in suppressing single- and dual-species biofilm formation was confirmed by CLSM analysis, where a decrease in biofilm biovolume (83% for S. aureus biofilms and 42% for P. aeruginosa and dual-species biofilms) and thickness (on average 72%) was obtained. Overall, these results showed that pristine GNPs dispersed into the PDMS matrix were able to inhibit biofilm growth, being a starting point for the fabrication of novel surface coatings based on functionalized GNP/PDMS composites

Fabrication of AZ4562 refractive microlenses array for light enhancement on optical microsystems

This paper presents the fabrication of an array of high aspect ratio photoresist based refractive microlenses (ML) using photolithography and thermal reflow. First, and in order to evaluate and predict the MLs optical properties and physical dimensions, finite element analysis was done. These simulations helped to design the super high resolution chrome on soda lime glass photomask as well as the parameters for the lithographic processes. Then, an array of high aspect ratio structures (length 4.9 mm, width 30 μm and 5 μm spacing between adjacent structures) with 5 μm thickness were fabricated. The thermal reflow technique (using a hotplate) was applied and an array of MLs measuring 5 and 32 μm at the vertex and radius, respectively, was achieved. When the photoresist (PR) is heated up above its glass transition temperature, it melts and the surface tension effect causes the fabricated microstructure to obtain the spherical lens profile. The hotplate thermal reflow is simple and easy to control, thus permitting the fabrication of smooth and homogeneous surfaces essential for good quality refractive microlenses.This work was supported by the Portuguese Foundation for Science and Technology under the projects FCT/PTDC/EEA-ELC/109936/2009 and FCT/MITPT/ EDAM-SI/0025/2008