Nitrogen and Oxygen Photochemistry following SL9

The collision of Shoemaker Levy 9 (SL9) with Jupiter caused many new molecular species to be deposited in the Jovian stratosphere. We use a photochemical model to follow the evolution of the impact derived species. Our results regarding the nitrogen and oxygen compounds are presented here. NH3 photolysis initiates the nitrogen photochemistry. Much of the nitrogen ends up in N2, nitrogen-sulfur compounds, and HCN, but NH3 and nitriles such as C2H3CN may also exist in observable quantities for a year or so after the impacts. Oxygen species survive for a long time in the Jovian stratosphere. The only major oxygen containing compounds that exhibit dramatic changes in the lower stratosphere in the first year following the impacts are SO, SO2, and OCS - H2O, CO2, and CO are comparatively stable. We discuss the important photochemical processes operating on the nitrogen and oxygen species in the Jovian stratosphere, make prediction concerning the temporal variation of the major species, and identify molecules that might act as good tracers for atmospheric dynamics

Chemical dynamics of triacetylene formation and implications to the synthesis of polyynes in Titan's atmosphere

For the last four decades, the role of polyynes such as diacetylene (HCCCCH) and triacetylene (HCCCCCCH) in the chemical evolution of the atmosphere of Saturn's moon Titan has been a subject of vigorous research. These polyacetylenes are thought to serve as an UV radiation shield in planetary environments; thus, acting as prebiotic ozone, and are considered as important constituents of the visible haze layers on Titan. However, the underlying chemical processes that initiate the formation and control the growth of polyynes have been the least understood to date. Here, we present a combined experimental, theoretical, and modeling study on the synthesis of the polyyne triacetylene (HCCCCCCH) via the bimolecular gas phase reaction of the ethynyl radical (CCH) with diacetylene (HCCCCH). This elementary reaction is rapid, has no entrance barrier, and yields the triacetylene molecule via indirect scattering dynamics through complex formation in a single collision event. Photochemical models of Titan's atmosphere imply that triacetylene may serve as a building block to synthesize even more complex polyynes such as tetraacetylene (HCCCCCCCCH)

Critical temperature and giant isotope effect in presence of paramagnons

We reconsider the long-standing problem of the effect of spin fluctuations on the critical temperature and isotope effect in a phonon-mediated superconductor. Although the general physics of the interplay between phonons and paramagnons had been rather well understood, the existing approximate formulas fail to describe the correct behavior of $$ for general phonon and paramagnon spectra. Using a controllable approximation, we derive an analytical formula for $T_{c}$ which agrees well with exact numerical solutions of the Eliashberg equations for a broad range of parameters. Based on both numerical and analytical results, we predict a strong enhancement of the isotope effect when the frequencies of spin fluctuation and phonons are of the same order. This effect may have important consequences for near-magnetic superconductors such as MgCNi$_{3}$Comment: 5 pages, 2 figure

Relationship between Diffusion, Selfdiffusion and Viscosity

We investigate the experimental limits of validity of the Stokes-Einstein equation. There is an important difference between diffusion and self-diffusion. There are experimental evidences, that in the case of self-diffusion the product D /T is constant and the equation is still valid. However, comparison of existing experimental data on viscosity and diffusion coefficients D of small, fast moving ions unambiguously show that the product D /T depends strongly on temperature T. The temperature dependence of diffusion coefficient declines from that of viscosity. Therefore, the Stokes-Einstein equation is not valid in this case

Time of life as it is in LiFeAs

The time of life of fermionic quasiparticles, the distribution of which in the momentum-energy space can be measured by angle resolved photoemission (ARPES), is the first quantity to look for fingerprints of interaction responsible for the superconducting pairing. Such an approach has been recently used for superconducting cuprates, but its direct application to pnictides was not possible due to essential three-dimensionality of the electronic band structure and magnetic ordering. Here, we report the investigation of the quasiparticle lifetime in LiFeAs, a non-magnetic stoichiometric superconductor with a well separated two-dimensional band. We have found two energy scales: the lower one contains clear fingerprints of optical phonon modes while the higher scale indicates a presence of strong electron-electron interaction. The result suggests that LiFeAs is a phonon mediated superconductor with strongly enhanced electronic density of states at the Fermi level.Comment: reevaluated electron-phonon coupling strength, added reference

E-learning as a tool for knowledge transfer through traditional and independent study at two UK higher educational institutes: a case study

Much has been made of the advances in computer aided learning activities. Websites, virtual campus, the increased use of Web CT and chat rooms and further advances in the use of WebCT are becoming more commonplace in UK universities. This paper looks for ways of changing higher education students’ perception of the usefulness of recommended internet web sites for learning purposes, with the intention of increasing the usage rate of recommended module web-sites. The change could represent an adaptation of the existing, well-known technology to change students’ perception regarding its potentially formative role. Subsequently, the outcomes from this preliminary research could be used in order to enhance the quality of the Internet use for teaching and learning purposes

Characterization of a Non-Contact Imaging Scintillator-Based Dosimetry System for Total Skin Electron Therapy.

Surface dosimetry is required for ensuring effective administration of total skin electron therapy (TSET); however, its use is often reduced due to the time consuming and complex nature of acquisition. A new surface dose imaging technique was characterized in this study and found to provide accurate, rapid and remote measurement of surface doses without the need for post-exposure processing. Disc-shaped plastic scintillators (1 mm thick  ×  15 mm [Formula: see text]) were chosen as optimal-sized samples and designed to attach to a flat-faced phantom for irradiation using electron beams. Scintillator dosimeter response to radiation damage, dose rate, and temperature were studied. The effect of varying scintillator diameter and thickness on light output was evaluated. Furthermore, the scintillator emission spectra and impact of dosimeter thickness on surface dose were also quantified. Since the scintillators were custom-machined, dosimeter-to-dosimeter variation was tested. Scintillator surface dose measurements were compared to those obtained by optically stimulated luminescence dosimeters (OSLD). Light output from scintillator dosimeters evaluated in this study was insensitive to radiation damage, temperature, and dose rate. Maximum wavelength of emission was found to be 422 nm. Dose reported by scintillators was linearly related to that from OSLDs. Build-up from placement of scintillators and OSLDs had a similar effect on surface dose (4.9% increase). Variation among scintillator dosimeters was found to be 0.3  ±  0.2%. Scintillator light output increased linearly with dosimeter thickness (~1.9  ×  /mm). All dosimeter diameters tested were able to accurately measure surface dose. Scintillator dosimeters can potentially improve surface dosimetry-associated workflow for TSET in the radiation oncology clinic. Since scintillator data output can be automatically recorded to a patient medical record, the chances of human error in reading out and recording surface dose are minimized

Enhanced transport in the polar mesosphere of Jupiter: Evidence from Cassini UVIS helium 584 Å airglow

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95607/1/jgre2060.pd