Esterification of Free Fatty Acids with Glycerol within the Biodiesel Production Framework

Companies in the field of the collection and treatment of waste cooking oils (WCO) for subsequent biodiesel production usually have to cope with high acidity oils, which cannot be directly transformed into fatty acid methyl esters due to soap production. Since glycerine is the main byproduct of biodiesel production, these high acidity oils could be esterified with the glycerine surplus to transform the free fatty acids (FFA) into triglycerides before performing the transesterification. In this work, commercial glycerol was esterified with commercial fatty acids and commercial fatty acid/lampante olive oil mixtures over tin (II) chloride. In the first set of experiments, the esterification of linoleic acid with glycerol excess from 20 to 80% molar over the stoichiometric was performed. From 20% glycerol excess, there was no improvement in FFA reduction. Using 20% glycerol excess, the performance of a biochar obtained from heavy metal-contaminated plant roots was compared to that of SnCl2. Then, the effect of the initial FFA content was assessed using different oleic acid/lampante olive oil mixtures. The results illustrated that glycerolysis was impeded at initial FFA contents lower than 10%. Finally, the glycerolysis of a WCO with 9.94% FFA was assayed, without success

Notes on the gypsies and the formation of ghetto schools in Spain

Entendemos por escuelas-gueto aquéllas en las cuales, debido a procesos de marginación social y conflictos entre los distintos grupos de población, se da una presencia excepcionalmente elevada de alumnado de etnias minoritarias, como es el caso de niñas y niños gitanos en cientos de escuelas en España. Hemos podido observar que ciertas irregularidades en el proceso de formación de estas escuelas-gueto, resultan en el abandono masivo de niños no gitanos de estos centros (“éxodo escolar”), para incorporarse a otros. Algunas escuelas se consolidan como guetos, funcionando a pesar de todo. Son símbolos reales y vivos de exclusión social, que pueden ser analizados desde distintos puntos de vista o perspectivas teóricas. Existen alternativas que también pueden ser consideradas.Ghetto schools are those in which, due to processes of social marginalization and conflicts between different population groups, an exceptionally high presence of students from minority ethnic groups is given, as is the case for Gypsies children in hundreds of schools in Spain. We have observed that certain irregularities in the process of formation of these ghetto schools, result in the massive abandonment of non-Gypsies children of these centers ("school exodus"), to join others. Some schools are consolidated as ghettoes, operating despite everything. They are real and vivid symbols of social exclusion, which can be analyzed from diferent points of view or theoretical perspectives. Also, there are alternatives that can also be considered

Influence of V(C,N) precipitates on microstructure and mechanical properties of continuous cooled C-Mn-V

The effect of chemical composition and processing parameters on the formation of acicular ferrite and/or bainite has been investigated. In particular, this paper deals with the influence that N through its combination with V, as V(C,N) precipitates, has on the decomposition of austenite. Likewise, the intragranular nucleation potency of V(C,N) precipitates is analyzed through the continuous cooling transformation diagrams (CCT) of two C-Mn-V steels with different contents of N. Results reported in this work allow us to conclude that acicular ferrite can only be achieved alloying with vanadium and nitrogen, meanwhile bainite is promoted in steels with a low level of nitrogen. It is concluded that higher strength values are obtained in acicular ferrite than in bainitic steel but a similar brittle-ductile transition temperature (BDT), and lower values of impact absorbed energy (KV) has been recorded in nitrogen-rich steel.VANITEC and the Spanish Ministerio de Ciencia e Innovacion for their financial supportPeer reviewe

SIESTA-PEXSI: Massively parallel method for efficient and accurate \textit{ab initio} materials simulation without matrix diagonalization

We describe a scheme for efficient large-scale electronic-structure calculations based on the combination of the pole expansion and selected inversion (PEXSI) technique with the SIESTA method, which uses numerical atomic orbitals within the Kohn-Sham density functional theory (KSDFT) framework. The PEXSI technique can efficiently utilize the sparsity pattern of the Hamiltonian and overlap matrices generated in SIESTA, and for large systems has a much lower computational complexity than that associated with the matrix diagonalization procedure. The PEXSI technique can be used to evaluate the electron density, free energy, atomic forces, density of states and local density of states without computing any eigenvalue or eigenvector of the Kohn-Sham Hamiltonian. It can achieve accuracy fully comparable to that obtained from a matrix diagonalization procedure for general systems, including metallic systems at low temperature. The PEXSI method is also highly scalable. With the recently developed massively parallel PEXSI technique, we can make efficient use of more than $10,000$ processors on high performance machines. We demonstrate the performance and accuracy of the SIESTA-PEXSI method using several examples of large scale electronic structure calculations, including 1D, 2D and bulk problems with insulating, semi-metallic, and metallic character

Hyperspectral Imaging Coupled with Multivariate Analysis and Image Processing for Detection and Visualisation of Colour in Cooked Sausages Stuffed in Different Modified Casings

A hyperspectral imaging system was for the first time exploited to estimate the core colour of sausages stuffed in natural hog casings or in two hog casings treated with solutions containing surfactants and lactic acid in slush salt. Yellowness of sausages stuffed in natural hog casings (control group, 20.26 ± 4.81) was significantly higher than that of sausages stuffed in casings modified by submersion for 90 min in a solution containing 1:30 (w/w) soy lecithin:distilled water, 2.5% wt. soy oil, and 21 mL lactic acid per kg NaCl (17.66 ± 2.89) (p < 0.05). When predicting the lightness and redness of the sausage core, a partial least squares regression model developed from spectra pre-treated with a second derivative showed calibration coefficients of determination (Rc2) of 0.73 and 0.76, respectively. Ten, ten, and seven wavelengths were selected as the important optimal wavelengths for lightness, redness, and yellowness, respectively. Those wavelengths provide meaningful information for developing a simple, cost-effective multispectral system to rapidly differentiate sausages based on their core colour. According to the canonical discriminant analysis, lightness possessed the highest discriminant power with which to differentiate sausages stuffed in different casings.Japan Society for the Promotion of Science P16104, 16F16104, 20K1547

Extension of the analytic nodal diffusion solver ANDES to triangular-Z geometry and coupling with COBRA-IIIc for hexagonal core analysis.

In this paper the extension of the multigroup nodal diffusion code ANDES, based on the Analytic Coarse Mesh Finite Difference (ACMFD) method, from Cartesian to hexagonal geometry is presented, as well as its coupling with the thermal–hydraulic (TH) code COBRA-IIIc for hexagonal core analysis. In extending the ACMFD method to hexagonal assemblies, triangular-Z nodes are used. In the radial plane, a direct transverse integration procedure is applied along the three directions that are orthogonal to the triangle interfaces. The triangular nodalization avoids the singularities, that appear when applying transverse integration to hexagonal nodes, and allows the advantage of the mesh subdivision capabilities implicit within that geometry. As for the thermal–hydraulics, the extension of the coupling scheme to hexagonal geometry has been performed with the capability to model the core using either assembly-wise channels (hexagonal mesh) or a higher refinement with six channels per fuel assembly (triangular mesh). Achieving this level of TH mesh refinement with COBRA-IIIc code provides a better estimation of the in-core 3D flow distribution, improving the TH core modelling. The neutronics and thermal–hydraulics coupled code, ANDES/COBRA-IIIc, previously verified in Cartesian geometry core analysis, can also be applied now to full three-dimensional VVER core problems, as well as to other thermal and fast hexagonal core designs. Verification results are provided, corresponding to the different cases of the OECD/NEA-NSC VVER-1000 Coolant Transient Benchmarks

Steric and mass-induced sea level variations in the Mediterranean Sea revisited

The total sea level variation (SLV) is the combination of steric and mass␣induced SLV, whose exact shares are key to understanding the oceanic response to climate system changes. Total SLV can be observed by radar altimetry satellites such as TOPEX/POSEIDON and Jason 1/2. The steric SLV can be computed through temperature and salinity profiles from in situ measurements or from ocean general circulation models (OGCM), which can assimilate the said observations. The mass-induced SLV can be estimated from its time-variable gravity (TVG) signals. We revisit this problem in the Mediterranean Sea estimating the observed, steric, and mass-induced SLV, for the latter we analyze the latest TVG data set from the GRACE (Gravity Recovery and Climate Experiment) satellite mission launched in 2002, which is 3.5 times longer than in previous studies, with the application of a two-stage anisotropic filter to reduce the noise in high-degree and -order spherical harmonic coefficients. We confirm that the intra-annual total SLV are only produced by water mass changes, a fact explained in the literature as a result of the wind field around the Gibraltar Strait. The steric SLV estimated from the residual of “altimetry minus GRACE” agrees in phase with that estimated from OGCMs and in situ measurements, although showing a higher amplitude. The net water fluxes through both the straits of Gibraltar and Sicily have also been estimated accordingly.This work was elaborated during the stay of the first author at the National Central University of Taiwan, thanks to a grant from the Generalitat Valenciana, Spain. Jean-Paul Boy is currently visiting NASA Goddard Space Flight Center, with a Marie Curie International Outgoing Fellowship (PIOF-GA-2008-221753). This work was partly funded by two Spanish projects from MICIN, ESP2006-11357, and AYA2009-07981 and one from Generalitat Valenciana (ACOMP2009/031)