282 research outputs found

    The Majorization Arrow in Quantum Algorithm Design

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    We apply majorization theory to study the quantum algorithms known so far and find that there is a majorization principle underlying the way they operate. Grover's algorithm is a neat instance of this principle where majorization works step by step until the optimal target state is found. Extensions of this situation are also found in algorithms based in quantum adiabatic evolution and the family of quantum phase-estimation algorithms, including Shor's algorithm. We state that in quantum algorithms the time arrow is a majorization arrow.Comment: REVTEX4.b4 file, 4 color figures (typos corrected.

    Flow of low viscosity Boger fluids through a microfluidic hyperbolic contraction

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    In this work we focus on the development of low viscosity Boger fluids and assess their elasticity analyzing the flow through a microfluidic hyperbolic contraction. Rheological tests in shear and extensional flows were carried out in order to evaluate the effect of the addition of a salt (NaCl) to dilute aqueous solutions of polyacrylamide at 400, 250, 125 and 50 ppm (w/w). The rheological data showed that when 1% (w/w) of NaCl was added, a significant decrease of the shear viscosity curve was observed, and a nearly constant shear viscosity was found for a wide range of shear rates, indicating Boger fluid behavior. The relaxation times, measured using a capillary break-up extensional rheometer (CaBER), decreased for lower polymer concentrations, and with the addition of NaCl. Visualizations of these Boger fluids flowing through a planar microfluidic geometry containing a hyperbolic contraction, which promotes a nearly uniform extension rate at the centerline of the geometry, was important to corroborate their degree of elasticity. Additionally, the quantification of the vortex growth upstream of the hyperbolic contraction was used with good accuracy and reproducibility to assess the relaxation time for the less concentrated Boger fluids, for which CaBER measurements are difficult to perform

    Optimised cross-slot microdevices for homogeneous extension

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    Microfluidic cross-slot devices can generate wide regions of vorticity-free strong extensional flow near the stagnation point, resulting in large extensional deformation and orientation of the microstructure of complex fluids, with possible applications in extensional rheometry and hydrodynamic stretching of single cells or molecules. Standard cross-slot devices, with sharp or rounded corners, generate a flow field with a non-homogeneous extension rate that peaks at the stagnation point, but decays significantly with distance from the stagnation point. To circumvent this limitation, an optimized shape cross-slot extensional rheometer (OSCER) was designed numerically and shown to generate constant extension rate over a wide region of the in- and out-flowing symmetry planes [Haward et al., Phys. Rev. Lett., 2012, 109, 128301]. Since the OSCER device was based on a 2D flow approximation, the practical implementation requires a large aspect ratio, which cannot be reproduced by standard soft-lithography techniques. Here, we propose a set of new designs for optimized cross-slot geometries, considering aspect ratios of order 1 and different lengths of the homogeneous inlet/outlet-flow regions. Micro-particle image velocimetry experiments were carried out in order to validate the flow kinematics, and the velocity profiles were found to be linear along the in- and outflow centrelines in good quantitative agreement with the numerical predictions

    Job satisfaction and commitment in the entrepreneurial SME

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    In the current global corporate climate that surrounds us, firms would do well to encourage the talent and creativity of their employees to achieve success. This is achieved, not by giving priority to individual talent, but by optimizing the collective as a whole and with the firm¿s activities based on teamwork and joint effort. Heads of organizations might benefit from creating a favorable context for the birth and growth of collective internal cooperation, which is understood to be the collective ability to create and innovate on the part of the team, the firm or the organization. Having contrasted our hypotheses through research on Spanish firms, we have concluded that job satisfaction and ommitment to the team are factors that have a direct and positive effect on Internal Entrepreneurship

    Limite de sensibilidad de CLAR de la determinación de resíduos de insecticidas organoclorados en suelos calizos Comparación con CG.

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    The HPLC and GC sensibility bounds are stablished and compared, in the determination, in calcareous soils, of residues of different insecticides organochlorinated. It is deduced the suitability o£ H,PLC in the case of Aldrin, Heptachlor, DDT, Endosul+fan, Endrin and Dieldrin, and too, for the guide detection of the contarnination grade of these soils for the above mentioned insecticides.Se establecen y comparan los limites de sensibilidad de CLAR y CG, en Ia determinacidn, en suelos calizos, de residuos de diversos insecticidas organocIorados. Se deduce que el empleo de CLAR es apropiado en el caso de Aldrin, Heptacloro, DDT, Endosulfan, Endrin y Dieldrin y de gran utilidad para dictaminar ripidamente el grado de contaminación de estos suelos por los citados insecticidas

    Molecular architecture of redox-active half-sandwich Ru(ii) cyclic assemblies : interactions with biomolecules and anticancer activity

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    Tetranuclear cationic open boxes non-covalently bind DNA major groove. By contrast, they covalently bind cysteine after ligand exchange reactions. In addition, these systems exhibit potent antitumour activity circumventing cisplatin resistance

    Influence of tip clearance on flow behavior and noise generation of centrifugal compressors in near-surge conditions

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    CFD has become an essential tool for researchers to analyze centrifugal compressors. Tip leakage flow is usually considered one of the main mechanisms that dictate compressor flow field and stability. However, it is a common practice to rely on CAD tip clearance, even though the gap between blades and shroud changes when compressor is running. In this paper, sensitivity of centrifugal compressor flow field and noise prediction to tip clearance ratio is investigated. 3D CFD simulations are performed with three different tip clearance ratios in accordance to expected operating values, extracted from shaft motion measurements and FEM predictions of temperature and rotational deformation. Near-surge operating conditions are simulated with URANS and DES. DES shows superior performance for acoustic predictions. Cases with reduced tip clearance present higher pressure ratio and isentropic efficiency, but no significant changes in compressor acoustic signature are found when varying clearance. In this working point, tip clearance is immersed in a region of strongly swirling backflow. Therefore, tip leakage cannot establish any coherent noise source mechanism.The equipment used in this work has been partially supported by FEDER project funds "Dotacion de infraestructuras cientifico tecnicas para el Centro Integral de Mejora Energetica y Medioambiental de Sistemas de Transporte (CiMeT), (FEDER-ICTS-2012-06)", framed in the operational program of unique scientific and technical infrastructure of the Ministry of Science and Innovation of Spain. The authors wish to thank Mr. Pau Raga for his worthy assistance during the meshing process.Galindo, J.; Tiseira Izaguirre, AO.; Navarro García, R.; López Hidalgo, MA. (2015). Influence of tip clearance on flow behavior and noise generation of centrifugal compressors in near-surge conditions. International Journal of Heat and Fluid Flow. 52:129-139. https://doi.org/10.1016/j.ijheatfluidflow.2014.12.004S1291395
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