Intensive monitoring of conventional and surrogate quality parameters in a highly urbanized river affected by multiple combined sewer overflows

Abstract The paper reports results of four intensive campaigns carried out on the Seveso River (Milan metropolitan area, Italy) between 2014 and 2016, during intense precipitation events. Laboratory analyses were coupled with on-site, continuous measurements to assess the impact of pollutants on water quality based on both conventional and surrogate parameters. Laboratory data included total suspended solids, caffeine, total phosphorus and nitrogen, and their dissolved forms. Screening of trace metals (Cr, Cu, Pb, Ni, Cd) and PBDEs (polybromodiphenylethers) was carried out. Continuous measurements included water level, physico-chemical variables and turbidity. Nutrient concentrations were generally high (e.g. average total phosphorus > 1,000 μg/L) indicating strong sewage contributions. Among monitored pollutants Cr, Cu, Pb, and Cd concentrations were well correlated to TSS, turbidity and discharge, being bound mostly to suspended particulate matter. A different behavior was found for Ni, that showed an early peak occurring before the flow peak, as a result of first flush events. PBDEs correlated well to nutrient concentrations, showing the highest peaks soon after activation of the combined sewer overflows, likely because of its accumulation in sewers. In addition to showing the existing correlations between quality parameters, the paper highlights the importance of surrogate parameters as indicators of anthropic pollution inputs

Experience With a Hard and Soft Participatory Modeling Framework for Social-ecological System Management in Mount Everest (Nepal) and K2 (Pakistan) Protected Areas

High mountains have sensitive social-ecological systems (SESs) characterized by fragility, complexity, and marginality. The local economies of these environments mainly rely on primary production, tourism, and leisure activities; thus human-ecosystem interactions are intricately linked. Many authors stress that this strict relationship must be assisted with a participatory approach involving interested stakeholders in the conceptualization, specification, and synthesis of knowledge and experience into useable information for the express purpose of addressing a problem complex. This paper presents experience garnered with a participatory modeling framework combining hard and soft methodology in 2 case studies: the Sagarmatha National Park and Buffer Zone (Nepal) and the Central Karakoram National Park (Pakistan). The modeling framework was developed based on local stakeholders' demands and needs; it consists of 5 modules, briefly presented here along with their conceptual background. In developing the framework, particular emphasis was given to considering the needs of decision-makers at the local level, rather than simply providing technical solutions to abstract problems. From the development of this modeling process, a need emerged to structure a management-oriented research module in order to generate management knowledge that is both stakeholder-relevant and evidence-based. The application of the framework in the 2 cases studies showed that the modeling can trigger valuable discussion among stakeholders as well as guidance for management-oriented research and feedback loops ensuring validation of knowledge. In addition, the resulting scenarios can help decision-makers in defining pathways for sustainable development in mountain areas, where people's livelihoods are closely dependent on ecosystems. The framework was developed in such a way that it can be replicated in other mountain areas with similar challenges

Future hydrological regimes and glacier cover in the Everest region: The case study of the upper Dudh Koshi basin

Assessment of future water resources under climate change is required in the Himalayas, where hydrological cycle is poorly studied and little understood. This study focuses on the upper Dudh Koshi river of Nepal (151 km2, 4200–8848 m a.s.l.) at the toe of Mt. Everest, nesting the debris covered Khumbu, and Khangri Nup glaciers (62 km2). New data gathered during three years of field campaigns (2012–2014) were used to set up a glacio-hydrological model describing stream flows, snow and ice melt, ice cover thickness and glaciers' flow dynamics. The model was validated, and used to assess changes of the hydrological cycle until 2100. Climate projections are used from three Global Climate Models used in the recent IPCC AR5 under RCP2.6, RCP4.5 and RCP8.5. Flow statistics are estimated for two reference decades 2045–2054, and 2090–2099, and compared against control run CR, 2012–2014. During CR we found a contribution of ice melt to stream flows of 55% yearly, with snow melt contributing for 19%. Future flows are predicted to increase in monsoon season, but to decrease yearly (− 4% vs CR on average) at 2045–2054. At the end of century large reduction would occur in all seasons, i.e. − 26% vs CR on average at 2090–2099. At half century yearly contribution of ice melt would be on average 45%, and snow melt 28%. At the end of century ice melt would be 31%, and snow contribution 39%. Glaciers in the area are projected to thin largely up to 6500 m a.s.l. until 2100, reducing their volume by − 50% or more, and their ice covered area by − 30% or more. According to our results, in the future water resources in the upper Dudh Koshi would decrease, and depend largely upon snow melt and rainfall, so that adaptation measures to modified water availability will be required

Atmospheric depositions of persistent pollutants: methodological aspects and values from case studies

Deposition monitoring, already in use by government control organizations of various countries, contributes to an important increase in experimental knowledge on pollutant deposition fluxes, on their environmental fate and on the possible effects on human health. At the European level, the necessity to consider with extreme attention the environmental contamination due to deposition, has brought to adopt a series of legislative measures and recommendations; this has contributed to set up environmental surveillance systems and monitoring campaigns for a series of pollutants which may accumulate in the environment as persistent organic pollutants (POPs) and for metals. More recently, with DL.vo 155/2010, the necessity to consider, in the development of monitoring stations, the possibility to detect also data on deposition rates which represent a non-direct exposure of the population through the food chain. For sampling the Decree considers only two types of depositions: for total deposition (bulk and Bergerhoff) and wet only deposition

Tracing glacier changes since the 1960s on the south slope of Mt. Everest (central Southern Himalaya) using optical satellite imagery

This contribution examines glacier changes on the south side of Mt. Everest from 1962 to 2011 considering five intermediate periods using optical satellite imagery. The investigated glaciers cover ~ 400 km2 and present among the largest debris coverage (32%) and the highest elevations (5720 m) of the world. We found an overall surface area loss of 13.0 ± 3.1% (median 0.42 ± 0.06 % a−1), an upward shift of 182 ± 22 m (3.7 ± 0.5 m a−1) in snow-line altitude (SLA), a terminus retreat of 403 ± 9 m (median 6.1 ± 0.2 m a−1), and an increase of 17.6 ± 3.1% (median 0.20 ± 0.06% a−1) in debris coverage between 1962 and 2011. The recession process of glaciers has been relentlessly continuous over the past 50 years. Moreover, we observed that (i) glaciers that have increased the debris coverage have experienced a reduced termini retreat (r = 0.87, p < 0.001). Furthermore, more negative mass balances (i.e., upward shift of SLA) induce increases of debris coverage (r = 0.79, p < 0.001); (ii) since early 1990s, we observed a slight but statistically insignificant acceleration of the surface area loss (0.35 ± 0.13% a−1 in 1962–1992 vs 0.43 ± 0.25% a−1 in 1992–2011), but an significant upward shift of SLA which increased almost three times (2.2 ± 0.8 m a−1 in 1962–1992 vs 6.1 ± 1.4 m a−1 in 1992–2011). However, the accelerated shrinkage in recent decades (both in terms of surface area loss and SLA shift) has only significantly affected glaciers with the largest sizes (> 10 km2), presenting accumulation zones at higher elevations (r = 0.61, p < 0.001) and along the preferable south–north direction of the monsoons. Moreover, the largest glaciers present median upward shifts of the SLA (220 m) that are nearly double than that of the smallest (119 m); this finding leads to a hypothesis that Mt. Everest glaciers are shrinking, not only due to warming temperatures, but also as a result of weakening Asian monsoons registered over the last few decades. We conclude that the shrinkage of the glaciers in south of Mt. Everest is less than that of others in the western and eastern Himalaya and southern and eastern Tibetan Plateau. Their position in higher elevations have likely reduced the impact of warming on these glaciers, but have not been excluded from a relentlessly continuous and slow recession process over the past 50 years

Mechanisms linking active rock glaciers and impounded surface water formation in high-mountain areas

Rock glaciers are slowly flowing mixtures of debris and ice occurring in mountains. They can represent a reservoir of water, and melting ice inside them can affect surface water hydrochemistry. Investigating the interactions between rock glaciers and water bodies is therefore necessary to better understand these mechanisms. With this goal, we elucidate the hydrology and structural setting of a rock glacier-marginal pond system, providing new insights into the mechanisms linking active rock glaciers and impounded surface waters. This was achieved through the integration of waterborne geophysical techniques (ground penetrating radar, electrical resistivity tomography and self-potentials) and heat tracing. Results of these surveys showed that rock glacier advance has progressively filled the valley depression where the pond is located, creating a dam that could have modified the level of impounded water. A sub-surface hydrological window connecting the rock glacier to the pond was also detected, where an inflow of cold and mineralised underground waters from the rock glacier was observed. Here, greater water contribution from the rock glacier occurred following intense precipitation events during the ice-free season, with concomitant increasing electrical conductivity values. The outflowing dynamic of the pond is dominated by a sub-surface seepage where a minor fault zone in bedrock was found, characterised by altered and highly-fractured rocks. The applied approach is evaluated here as a suitable technique for investigating logistically-complex hydrological settings which could be possibly transferred to wider scales of investigation