Field Ion Microscopy and Atom-Probe Mass Spectroscopy: Techniques and Selected Applications

The techniques of field ion microscopy and atom-probe mass spectroscopy are reviewed with emphasis on the general operational principles of the instruments and selected applications in the area of surface science. The single atom imaging capability of the field ion microscope is shown to make it uniquely suited to the study of detailed, atomic processes on clean metal surfaces. As examples, investigations of single-atom surface diffusion, cluster nucleation, and surface reconstructions are discussed. The ability of the atom-probe mass spectrometer to determine the chemical identity of selected atoms observed in the field ion microscope image is shown to be useful for the microanalysis of various materials. The different types of atom-probes currently in use and their application in the areas of surface catalyzed reactions and high-temperature ceramic superconductors are described

A Comparison of Skyline Harvesting Costs for Alternative Commercial Thinning Prescriptions

Harvesting production and costs were examined for three alternative silvicultural prescriptions at two sites in the Coast Range of Oregon. Thirty-three-year-old Douglas fir stands were commercially thinned to residual densities of 247,148, and 74 trees per hectare (tph) [100,60, and 30 trees per acre (tpa), respectively]. Detailed time studies were conducted on manual felling and uphill skyline yarding with small yarders. Separate regression equations were developed to predict delay-free felling cycle time and delay-free yarding cycle time. The 74 tph [30 tpa] treatment had the highest production rate and was the least costly to harvest. Total harvesting costs of the other two treatments averaged from 6.0% (148 tph [60 tpa]) to 12.3% (247 tph [100 tpa]) more than the 74 tph [30 tpa] treatment

On the Sensitivity of 3-D Thermal Convection Codes to Numerical Discretization: A Model Intercomparison

Fully 3-D numerical simulations of thermal convection in a spherical shell have become a standard for studying the dynamics of pattern formation and its stability under perturbations to various parameter values. The question arises as to how does the discretization of the governing equations affect the outcome and thus any physical interpretation. This work demonstrates the impact of numerical discretization on the observed patterns, the value at which symmetry is broken, and how stability and stationary behavior is dependent upon it. Motivated by numerical simulations of convection in the Earth\u27s mantle, we consider isoviscous Rayleigh-Bénard convection at infinite Prandtl number, where the aspect ratio between the inner and outer shell is 0.55. We show that the subtleties involved in development mantle convection models are considerably more delicate than has been previously appreciated, due to the rich dynamical behavior of the system. Two codes with different numerical discretization schemes: an established, community-developed, and benchmarked finite element code (CitcomS) and a novel spectral method that combines Chebyshev polynomials with radial basis functions (RBF) are compared. A full numerical study is investigated for the following three cases. The first case is based on the cubic (or octahedral) initial condition (spherical harmonics of degree ℓ =4). How variations in the behavior of the cubic pattern to perturbations in the initial condition and Rayleigh number between the two numerical discrezations is studied. The second case investigates the stability of the dodecahedral (or icosahedral) initial condition (spherical harmonics of degree ℓ = 6). Although both methods converge first to the same pattern, this structure is ultimately unstable and systematically degenerates to cubic or tetrahedral symmetries, depending on the code used. Lastly, a new steady state pattern is presented as a combination of order 3 and 4 spherical harmonics leading to a five cell or a hexahedral pattern and stable up to 70 times the critical Rayleigh number. This pattern can provide the basis for a new accuracy benchmark for 3-D spherical mantle convection codes

Aquaculture and eelgrass Zostera marina interactions in temperate ecosystems

This paper reviews the impacts of shellfish and finfish aquaculture on eelgrassZostera marina, the most widely distributed seagrass species in the northern hemisphere. Shellfish aquaculture can have positive, neutral, and negative effects on eelgrass. Positive interactions can be generated by the filtering activity of cultured bivalves, which may improve water quality and reduce epiphyte loads, and shellfish biodeposits may provide more nutrients to eelgrass and other vegetation. However, negative responses are more commonly reported and can be causedby shading and sedimentation. These negative effects tend to occur directly under and immediately surrounding shellfish farms and rapidly diminish with increasing distance. In contrast to shellfish aquaculture, only one field study has investigated the effects of finfish aquaculture on eelgrass in a temperate setting, and the results were inconclusive. However, many studies have investigated the effects of Mediterranean finfish farms on 2 other species of seagrass (Posidoniaoceanica and Cymodocea nodosa). These studies reported clear negative interactions, which have been linked to increased nutrient concentrations, sulphides, sedimentation, epiphyte loads, and grazing pressure. It is unknown if these studies are relevant for finfish aquaculture in temperate regions due to differences in environmental conditions, and because the studies focused on differ-ent species of seagrass. Thus, further study in a temperate setting is warranted. We conclude by highlighting key research gaps that could help regulators establish unambiguous operational and siting guidelines that minimize the potential for negative interactions between aquaculture and eelgrass

The x ray reflectivity of the AXAF VETA-I optics

The x-ray reflectivity of the VETA-I optic, the outermost shell of the AXAF x-ray telescope, with a bare Zerodur surface, is measured and compared with theoretical predictions. Measurements made at energies of 0.28, 0.9, 1.5, 2.1, and 2.3 keV are compared with predictions based on ray trace calculations. The data were obtained at the x-ray calibrations facility at Marshall Space Flight Center with an electron impact x-ray source located 528 m from the grazing incidence mirror. The source used photoelectric absorption filters to eliminate bremsstrahlung continuum. The mirror has a diameter of 1.2 m and a focal length of 10 m. The incident and reflected x-ray flux are detected using two proportional counters, one located in the incident beam of x-rays at the entrance aperture of the VETA-I, and the other in the focal plane behind an aperture of variable size. Results on the variation of the reflectivity with energy as well as the absolute value of the reflectivity are presented. We also present a synchrotron reflectivity measurement with high energy resolution over the range 0.26 to 1.8 keV on a flat Zerodur sample, done at NSLS. We present evidence for contamination of the flat by a thin layer of carbon on the surface, and the possibility of alteration of the surface composition of the VETA-I mirror perhaps by the polishing technique. The overall agreement between the measured and calculated effective area of VETA-I is between 2.6 percent and 10 percent, depending on which model for the surface composition is adopted. Measurements at individual energies deviate from the best-fitting calculation to 0.3 to 0.8 percent, averaging 0.6 percent at energies below the high energy cutoff of the mirror reflectivity, and are as high as 20.7 percent at the cutoff. We also discuss the approach to the final preflight calibration of the full AXAF flight mirror

Anisotropy of Growth of the Close-Packed Surfaces of Silver

The growth morphology of clean silver exhibits a profound anisotropy: The growing surface of Ag(111) is typically very rough while that of Ag(100) is smooth and flat. This serious and important difference is unexpected, not understood, and hitherto not observed for any other metal. Using density functional theory calculations of self-diffusion on flat and stepped Ag(100) we find, for example, that at flat regions a hopping mechanism is favored, while across step edges diffusion proceeds by an exchange process. The calculated microscopic parameters explain the experimentally reported growth properties.Comment: RevTeX, 4 pages, 3 figures in uufiles form, to appear in Phys. Rev. Let

Magnetic Surfaces in Stationary Axisymmetric General Relativity

In this paper a new method is derived for constructing electromagnetic surface sources for stationary axisymmetric electrovac spacetimes endowed with non-smooth or even discontinuous Ernst potentials. This can be viewed as a generalization of some classical potential theory results, since lack of continuity of the potential is related to dipole density and lack of smoothness, to monopole density. In particular this approach is useful for constructing the dipole source for the magnetic field. This formalism involves solving a linear elliptic differential equation with boundary conditions at infinity. As an example, two different models of surface densities for the Kerr-Newman electrovac spacetime are derived.Comment: 15 page

Surface diffusion coefficients by thermodynamic integration: Cu on Cu(100)

The rate of diffusion of a Cu adatom on the Cu(100) surface is calculated using thermodynamic integration within the transition state theory. The results are found to be in excellent agreement with the essentially exact values from molecular-dynamics simulations. The activation energy and related entropy are shown to be effectively independent of temperature, thus establishing the validity of the Arrhenius law over a wide range of temperatures. Our study demonstrates the equivalence of diffusion rates calculated using thermodynamic integration within the transition state theory and direct molecular-dynamics simulations.Comment: 4 pages (revtex), two figures (postscript

Swift Observations of Hard X-ray Emitting White Dwarfs in Symbiotic Stars

The X-ray emission from most accreting white dwarfs (WDs) in symbiotic binary stars is quite soft. Several symbiotic WDs, however, produce strong X-ray emission at energies greater than ~20 keV. The Swift BAT instrument has detected hard X-ray emission from 4 such accreting WDs in symbiotic stars: RT Cru, T CrB, CD -57 3057, and CH Cyg. In one case (RT Cru), Swift detected X-rays out to greater than 50 keV at a > 5 sigma confidence level. Combining data from the XRT and BAT detectors, we find that the 0.3-150 keV spectra of RT Cru, T CrB, and CD -57 3057 are well described by emission from a single-temperature, optically thin thermal plasma, plus an unresolved 6.4-6.9 keV Fe line complex. The X-ray spectrum of CH Cyg contains an additional bright soft component. For all 4 systems, the spectra suffer high levels of absorption from material that both fully and partially covers the source of hard X-rays. The XRT data did not show any of the rapid, periodic variations that one would expect if the X-ray emission were due to accretion onto a rotating, highly magnetized WD. The X-rays were thus more likely from the accretion-disk boundary layer around a massive, non-magnetic WD in each binary. The X-ray emission from RT Cru varied on timescales of a few days. This variability is consistent with being due to changes in the absorber that partially covers the source, suggesting localized absorption from a clumpy medium moving into the line of sight. The X-ray emission from CD -57 3057 and T CrB also varied during the 9 months of Swift observations, in a manner that was also consistent with variable absorption.Comment: Accepted for publication in ApJ. 9 pages, 6 figure

The Study of the Pioneer Anomaly: New Data and Objectives for New Investigation

Radiometric tracking data from Pioneer 10 and 11 spacecraft has consistently indicated the presence of a small, anomalous, Doppler frequency drift, uniformly changing with a rate of ~6 x 10^{-9} Hz/s; the drift can be interpreted as a constant sunward acceleration of each particular spacecraft of a_P = (8.74 \pm 1.33) x 10^{-10} m/s^2. This signal is known as the Pioneer anomaly; the nature of this anomaly remains unexplained. We discuss the efforts to retrieve the entire data sets of the Pioneer 10/11 radiometric Doppler data. We also report on the recently recovered telemetry files that may be used to reconstruct the engineering history of both spacecraft using original project documentation and newly developed software tools. We discuss possible ways to further investigate the discovered effect using these telemetry files in conjunction with the analysis of the much extended Doppler data. We present the main objectives of new upcoming study of the Pioneer anomaly, namely i) analysis of the early data that could yield the direction of the anomaly, ii) analysis of planetary encounters, that should tell more about the onset of the anomaly, iii) analysis of the entire dataset, to better determine the anomaly's temporal behavior, iv) comparative analysis of individual anomalous accelerations for the two Pioneers, v) the detailed study of on-board systematics, and vi) development of a thermal-electric-dynamical model using on-board telemetry. The outlined strategy may allow for a higher accuracy solution for a_P and, possibly, will lead to an unambiguous determination of the origin of the Pioneer anomaly.Comment: 43 pages, 40 figures, 3 tables, minor changes before publicatio