165 research outputs found
Magnetic frustration in an iron based Cairo pentagonal lattice
The Fe3+ lattice in the Bi2Fe4O9 compound is found to materialize the first
analogue of a magnetic pentagonal lattice. Due to its odd number of bonds per
elemental brick, this lattice, subject to first neighbor antiferromagnetic
interactions, is prone to geometric frustration. The Bi2Fe4O9 magnetic
properties have been investigated by macroscopic magnetic measurements and
neutron diffraction. The observed non-collinear magnetic arrangement is related
to the one stabilized on a perfect tiling as obtained from a mean field
analysis with direct space magnetic configurations calculations. The
peculiarity of this structure arises from the complex connectivity of the
pentagonal lattice, a novel feature compared to the well-known case of
triangle-based lattices
Short-Range B-site Ordering in Inverse Spinel Ferrite NiFe2O4
The Raman spectra of single crystals of NiFe2O4 were studied in various
scattering configurations in close comparison with the corresponding spectra of
Ni0.7Zn0.3Fe2O4 and Fe3O4. The number of experimentally observed Raman modes
exceeds significantly that expected for a normal spinel structure and the
polarization properties of most of the Raman lines provide evidence for a
microscopic symmetry lower than that given by the Fd-3m space group. We argue
that the experimental results can be explained by considering the short range
1:1 ordering of Ni2+ and Fe3+ at the B-sites of inverse spinel structure, most
probably of tetragonal P4_122/P4_322 symmetry.Comment: 10 pages, 5 figures, 6 table
Pressure induced enhancement of ferroelectricity in multiferroic MnO(=Tb,Dy, and Ho)
Measurements of ferroelectric polarization and dielectric constant were done
on MnO (=Tb, Dy, and Ho) with applied hydrostatic pressures of up
to 18 kbar. At ambient pressure, distinctive anomalies were observed in the
temperature profile of both physical properties at critical temperatures
marking the onset of long range AFM order (T), ferroelectricity
(T) as well as at temperatures when anomalous changes in the
polarization, dielectric constant and spin wave commensurability have been
previously reported. In particular, the step in the dielectric constant at low
temperatures (T), associated with both a drop in the ferroelectric
polarization and an incommensurate magnetic structure, was shown to be suddenly
quenched upon passing an -dependent critical pressure. This was shown to
correlate with the stabilization of the high ferroelectric polarization state
which is coincident with the commensurate magnetic structure. The observation
is suggested to be due to a pressure induced phase transition into a
commensurate magnetic structure as exemplified by the pressure-temperature
(-) phase diagrams constructed in this work. The - phase diagrams
are determined for all three compounds.Comment: 8 pages, 6 figures, submitted for review in Phys. Rev.
Metal-to-insulator transition and magnetic ordering in CaRu_{1-x}Cu_xO_3
CaRuO_3 is perovskite with an orthorhombic distortion and is believed to be
close to magnetic ordering. Magnetic studies of single crystal and
polycrystalline CaRu_{1-x}Cu_xO_3 (0\le x \le 15 at.%Cu) reveal that
spin-glass-like transition develops for x\le 7 at.%Cu and obtained value for
effective magnetic moment p_{eff}=3.55 mu_B for x=5 at.% Cu, single crystal,
indicates presence of Ru^{5+}. At higher Cu concentrations more complex
magnetic behaviors are observed. Electrical resistivity measured on
polycrystalline samples shows metal-to-insulator transition (MIT) at 51 K for
only 2 at.% Cu. Charge compensation, which is assumed to be present upon
Cu^{2+/3+} substitution, induces appearance of Ru^{5+} and/or creation of
oxygen vacancies in crystal structure. Since the observed changes in physical
properties are completely attributable to the charge compensation, they cannot
be related to behaviors of pure compound where no such mechanism is present.
This study provides the criterion for "good" chemical probes for studying
Ru-based perovskites.Comment: 12 pages, 7 figure
Raman and Infrared-Active Phonons in Hexagonal HoMnO Single Crystals: Magnetic Ordering Effects
Polarized Raman scattering and infrared reflection spectra of hexagonal
HoMnO single crystals in the temperature range 10-300 K are reported.
Group-theoretical analysis is performed and scattering selection rules for the
second order scattering processes are presented. Based on the results of
lattice dynamics calculations, performed within the shell model, the observed
lines in the spectra are assigned to definite lattice vibrations. The magnetic
ordering of Mn ions, which occurs below T=76 K, is shown to effect both
Raman- and infrared-active phonons, which modulate Mn-O-Mn bonds and,
consequently, Mn exchange interaction.Comment: 8 pages, 6 figure
Phonon and magnon scattering of antiferromagnetic Bi2Fe4O9
The phonon structure of antiferromagnetic Bi2Fe4O9 (space group Pbnm No. 55, TN≈240 K) was studied theoretically by calculations of lattice dynamics and experimentally between 10 and 300 K by polarized Raman spectroscopy. Most of the 12Ag+12B1g+9B2g+9B3g Raman modes were unambiguously identified. Strong second-order scattering was observed for ab-plane-confined incident and scattered light polarizations. In addition to the phonon-scattering, broad Raman bands with typical characteristics of magnon scattering appear below TN. The magnon bands are analyzed on the basis of magnetic structure of Bi2Fe4O9 and attributed to two- magnon excitations
Cellular Robustness Conferred by Genetic Crosstalk Underlies Resistance against Chemotherapeutic Drug Doxorubicin in Fission Yeast
10.1371/journal.pone.0055041PLoS ONE81
New national and regional bryophyte records, 69
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