Aggregation-cokriging for highly multivariate spatial data

Best linear unbiased prediction of spatially correlated multivariate random processes, often called cokriging in geostatistics, requires the solution of a large linear system based on the covariance and cross-covariance matrix of the observations. For many problems of practical interest, it is impossible to solve the linear system with direct methods. We propose an efficient linear unbiased predictor based on a linear aggregation of the covariables. The primary variable together with this single meta-covariable is used to perform cokriging. We discuss the optimality of the approach under different covariance structures, and use it to create reanalysis type high-resolution historical temperature field

Zinc Extraction potential of two common crop plants, Nicotiana tabacum and Zea mays

A field study was conducted to investigate the efficiency of Zn phytoextraction by Nicotiana tabacum and Zea mays from a soil that had been artificially contaminated by different amounts of ZnSO4 (0, 50, 150, 350, 750 and 1550 mg kg−1 soil) 10 years prior to the present cropping. Increased NaNO3-extractable Zn in soil translated well into shoot concentrations (dry matter) in plants. Zn uptake by Z. mays increased linearly with increasing NaNO3-extractable Zn in soil, while for N. tabacum the increase could be described by a Langmuir isotherm. While Z. mays showed no significant decrease in biomass production up to the highest contamination level in soil, N. tabacum responded with a reduction of plant growth of about 50% compared with control plants at the highest Zn concentrations in soil. Maximum removal of Zn was 13 kg ha−1 y−1 with Z. mays and 11 kg ha−1 y−1 with N. tabacum. Calculated time required to reduce soil Zn from 350 to 150 mg kg−1 was about 55 years for N. tabacum and about 63 years for Z. mays at a soil pH of 4.8. At higher soil pH of 6.0 calculated decontamination time was about 87 years for N. tabacum and more than 200 years for Z. mays. Only small amounts of Zn were translocated into the seeds of N. tabacum and cobs of Z. mays. Therefore, corn cobs of Z. mays could be safely used for fodder and the seeds of N. tabacum, which are rich in oil, for industrial purposes, e.g. in the paint industr

EC87-130 A 1987 Guide for Herbicide Use in Nebraska

Extension circular 87-130 is a 1987 guide for herbicide use in Nebraska

Dynamic capabilities to match multiple product generations and market rhythm

Purpose : The purpose of this paper is to provide greater insights to managers seeking to time properly the launches of innovative new products (NPs) across multiple generations. This paper aims to address the rhythm matching problem by developing a typology and a conceptual framework of the interaction between a firm’s technological readiness to launch NPs and a market’s receptivity in influencing a firm’s long-term performance. Design/methodology/approach –:Based on the new product development (NPD) and diffusion of innovation literatures, the paper develops a model explicitly to address the rhythm matching problem by highlighting the interaction between a firm’s technological readiness to launch new products and a market’s receptivity in influencing a firm’s long-term performance. The logic of this model may be described as follows: long-term performance is a function of matching: products to customer needs, marketingmix dynamics to customer segments and buying behavior dynamics, and logistics, supply chain management, and inventory to market dynamics and financial efficiency; uncertainty in: knowledge of needs, market segments and their dynamics, and market dynamics is all a function of time, as is financial efficiency. Therefore, a firm’s long-term performance is a function of these matches over time. Findings : Deriving from the proposed model and typology, it was found that in independent rhythm windows, the management focus is on a single generation and each successive generation can be planned independently. In market- imposed windows, firms aim at adapting their own NP readiness rhythm to the market receptivity rhythm. In firm-imposed windows, firms have the initiative to drive the market receptivity rhythm. In dynamically resultant windows, everything is more complicated because firms’ NP readiness rhythm and market receptivity rhythm influence each other. Originality/value : The model and typology developed in this paper are a breakthrough result of synthesizing various traditions of NPD and diffusion of innovation research. It is believed that the paper provides a rich conceptual framework drawing together extant research on the development and introduction of new products. The framework is intended both to explicitly inform managers of the importance of rhythm matching as well as to the factors that influence such matching. It is also intended to provide a lens with which further research can be directed to increase the efficiency and effectiveness of resource utilization in NPD and the long- term success of the firms

Q-dependence of the inelastic neutron scattering cross section for molecular spin clusters with high molecular symmetry

For powder samples of polynuclear metal complexes the dependence of the inelastic neutron scattering intensity on the momentum transfer Q is known to be described by a combination of so called interference terms. They reflect the interplay between the geometrical structure of the compound and the spatial properties of the wave functions involved in the transition. In this work, it is shown that the Q-dependence is strongly interrelated with the molecular symmetry of molecular nanomagnets, and, if the molecular symmetry is high enough, is actually completely determined by it. A general formalism connecting spatial symmetry and interference terms is developed. The arguments are detailed for cyclic spin clusters, as experimentally realized by e.g. the octanuclear molecular wheel Cr8, and the star like tetranuclear cluster Fe4.Comment: 8 pages, 1 figures, REVTEX

Luminescent blue emissive bis(alkynyl) borane compounds with a N,O-coordinated ligand

Five bis(alkynyl)boranes with a (imidazo[1,5-a]pyridin-3-yl)phenolate ligand have been synthesized and characterized both in solution (1H, 13C, 11B, 19F NMR) and in the solid state (X-ray). All derivatives, differing for the substituent R (H, Me, OMe, CF3, NMe2) in the para position of the phenylacetylene moieties, displayed blue fluorescence emission in solution, linearly correlated to the electronic properties of the substituent R (i.e., its σp Hammett constant). High Stokes shifts and good quantum yields were recorded. Time-Dependent Density Functional Theory (TD-DFT) calculations were performed to describe the percentage contribution of each fragment of the molecule to the frontier orbitals. Electron Density Difference Maps (EDDMs) calculated for all derivatives allowed to explain the emissive properties of the studied compounds

Heisenberg Dimer Single Molecule Magnets in a Strong Magnetic Field

We calculate the static and dynamic properties of single crystal, single molecule magnets consisting of equal spin $S=1/2$ or 5/2 dimers. The spins in each dimer interact with each other via the Heisenberg exchange interaction and with the magnetic induction ${\bf B}$ via the Zeeman interaction, and interdimer interactions are negligible. For antiferromagnetic couplings, the static magnetization and specific heat exhibit interesting low temperature $T$ and strong ${\bf B}$ quantum effects. We calculate the frequency spectrum of the Fourier transform of the real part of the time autocorrelation function ${\cal C}_{11}(t)$ for arbitrary $T, {\bf B}$, and compare our results with those obtained for classical spins. We also calculate the inelastic neutron magnetic dynamical structure factor $S({\bf q},\omega)$ at arbitrary $T, {\bf B}$.Comment: 11 pages, 14 figures, submitted to Phys. Rev.

Dynamical Structure Factors for Dimerized Spin Systems

We discuss the transition strength between the disordered ground state and the basic low-lying triplet excitation for interacting dimer materials by presenting theoretical calculations and series expansions as well as inelastic neutron scattering results for the material KCuCl_3. We describe in detail the features resulting from the presence of two differently oriented dimers per unit cell and show how energies and spectral weights of the resulting two modes are related to each other. We present results from the perturbation expansion in the interdimer interaction strength and thus demonstrate that the wave vector dependence of the simple dimer approximation is modified in higher orders. Explicit results are given in 10th order for dimers coupled in 1D, and in 2nd order for dimers coupled in 3D with application to KCuCl_3 and TlCuCl_3.Comment: 17 pages, 6 figures, part 2 is based on cond-mat/021133