Magnetic properties of a novel Pr Fe Ti phase

In a systematic study of the (Pr1−xTix)Fe5 alloy series, the (Pr0.65Ti0.35)Fe5 alloy has been found to have a dominant phase with either the rhombohedral Th2Zn17 structure or the newly discovered Nd2(Fe,Ti)19 (S. J. Collocott, R. K. Day, J. B. Dunlop, and R. L. Davis, in Proceedings of the Seventh International Symposium on Magnetic Anisotropy and Coercivity in R‐T Alloys, Canberra, July 1992, p. 437) structure, depending on the annealing procedure. Powder‐x‐ray‐diffraction patterns and scanning electron microscopy show that the sample annealed at a temperature of 850 °C followed by 1000 °C has the 2:17 structure whereas annealing at 1000 °C directly leads to the new 2:19 structure. Energy‐dispersive x‐ray analysis yields Pr:Fe:Ti ratios of 10.7:86.2:3.1 for the Pr2(Fe,Ti)17 phase and 9.2:85.9:4.9 for the Pr2(Fe,Ti)19 phase. 57 Fe Mössbauer spectroscopy (at 295 K) gives values for the average 57 Fe hyperfine field of 15.7 T for the 2:17 phase and 17.5 T for the 2:19 phase, respectively

Magnetic properties of Gd(Fe1−xCox)9Ti2 alloys

Four samples of Gd(Fe1−xCox)9Ti2 with x=0.0, 0.1, 0.2, and 0.3 were prepared by conventional arc melting followed by annealing at 1000 °C for 3 days. Powder‐x‐ray‐diffraction patterns of these samples show that all of the samples have a dominant phase with the tetragonal CeMn6Ni5 structure. Traces of TiFe2 are also present. 57 Fe Mössbauer spectra have been collected at 80 and 295 K. X‐ray‐diffraction patterns and Mössbauer spectra on magnetically aligned samples indicate that the easy axis of magnetization is the crystallographic c axis. The Curie temperature increases monotonically with increasing cobalt concentration. The average hyperfine field at 80 K reaches a maximum of 26.8(5) T for x≊0.2

Improving adherence to multiple medications in older people in primary care: Selecting intervention components to address patient-reported barriers and facilitators

Background: Medication adherence is vital to ensuring optimal patient outcomes, particularly amongst multimorbid older people prescribed multiple medications. Interventions targeting adherence often lack a theoretical underpinning and this may impact on effectiveness. The theoretical domains framework (TDF) of behaviour can aid intervention development by systematically identifying key determinants of medication adherence. Objectives: This study aimed to (i) identify determinants (barriers, facilitators) of adherence to multiple medications from older people's perspectives; (ii) identify key domains to target for behaviour change; and (iii) map key domains to intervention components [behaviour change techniques (BCTs)] that could be delivered in an intervention by community pharmacists. Method Focus groups were conducted with older people (>65 years) receiving ≥4 medications. Questions explored the 12 domains of the TDF (eg “Knowledge,” “Emotion”). Data were analysed using the framework method and content analysis. Identification of key domains and mapping to intervention components (BCTs) followed established methods. Results: Seven focus groups were convened (50 participants). A wide range of determinants were identified as barriers (eg forgetfulness, prioritization of medications) and facilitators (eg social support, personalized routines) of adherence to multiple medications. Eight domains were identified as key targets for behaviour change (eg “Social influences,” “Memory, attention and decision processes,” “Motivation and goals”) and mapped to 11 intervention components (BCTs) to include in an intervention [eg “Social support or encouragement (general),” “Self-monitoring of the behaviour,” “Goal-setting (behaviour)”]. Conclusion: This study used a theoretical underpinning to identify potential intervention components (BCTs). Future work will incorporate the selected BCTs into an intervention that will undergo feasibility testing in community pharmacies

Mineralogia e química de um Latossolo câmbico desenvolvido de rocha pelítica do grupo Bambuí, MG.

Foram realizados analises quimica e mineralogica das fracoes argila e silte de amostras de um perfil de solo com tres camadas distintas: uma superficies xantizada, uma camada de subsuperficie vermelha e um horizonte C apresentado variegados amarelos e vermelhos. Os minerais de maior ocorrencia sao caulinita, mica/vermiculita e goethita. A cor do solo esta relacionada a proporcao hematita/goethita (determinada pela espectroscopia Mossbauer). A substituicao isomorfica de ferro por aluminio na goethita aumenta uniformemente, de 20 a 40 mol%, da base para o topo de perfil; SiO2 decresce uniformemente e ha, ainda, uma tendencia de o Fe 2+ ser continuamente oxidado, na medida em que mica se transforma em vermiculita. O aparecimento de hematita na camada vermelha nao pode ser explicado quantitativamente pela hipotese de que os silicatos sejam a unica fonte de ferro, a menos que haja uma consideravel reducao de volume de camada siltosa amarela do horizonte C para as camadas vermelhas do horizonte B. Os dados sugerem uma transformacao reversivel goethita hematita, em resposta as condicoes ambientais

High Altitude Long Endurance Air Vehicle Analysis of Alternatives and Technology Requirements Development

The objective of this study was to develop a variety of High Altitude Long Endurance (HALE) Unmanned Aerial Vehicle (UAV) conceptual designs for two operationally useful missions (hurricane science and communications relay) and compare their performance and cost characteristics. Sixteen potential HALE UAV configurations were initially developed, including heavier-than-air (HTA) and lighter-than-air (LTA) concepts with both consumable fuel and solar regenerative (SR) propulsion systems. Through an Analysis of Alternatives (AoA) down select process, the two leading consumable fuel configurations (one each from the HTA and LTA alternatives) and an HTA SR configuration were selected for further analysis. Cost effectiveness analysis of the consumable fuel configurations revealed that simply maximizing vehicle endurance can lead to a sub-optimum system solution. An LTA concept with a hybrid propulsion system (solar arrays and a hydrogen-air proton exchange membrane fuel cell) was found to have the best mission performance; however, an HTA diesel-fueled wing-body-tail configuration emerged as the preferred consumable fuel concept because of the large size and technical risk of the LTA concept. The baseline missions could not be performed by even the best HTA SR concept. Mission and SR technology trade studies were conducted to enhance understanding of the potential capabilities of such a vehicle. With near-term technology SR-powered HTA vehicles are limited to operation in favorable solar conditions, such as the long days and short nights of summer at higher latitudes. Energy storage system specific energy and solar cell efficiency were found to be the key technology areas for enhancing HTA SR performance

Identifying the science and technology dimensions of emerging public policy issues through horizon scanning

Public policy requires public support, which in turn implies a need to enable the public not just to understand policy but also to be engaged in its development. Where complex science and technology issues are involved in policy making, this takes time, so it is important to identify emerging issues of this type and prepare engagement plans. In our horizon scanning exercise, we used a modified Delphi technique [1]. A wide group of people with interests in the science and policy interface (drawn from policy makers, policy adviser, practitioners, the private sector and academics) elicited a long list of emergent policy issues in which science and technology would feature strongly and which would also necessitate public engagement as policies are developed. This was then refined to a short list of top priorities for policy makers. Thirty issues were identified within broad areas of business and technology; energy and environment; government, politics and education; health, healthcare, population and aging; information, communication, infrastructure and transport; and public safety and national security.Public policy requires public support, which in turn implies a need to enable the public not just to understand policy but also to be engaged in its development. Where complex science and technology issues are involved in policy making, this takes time, so it is important to identify emerging issues of this type and prepare engagement plans. In our horizon scanning exercise, we used a modified Delphi technique [1]. A wide group of people with interests in the science and policy interface (drawn from policy makers, policy adviser, practitioners, the private sector and academics) elicited a long list of emergent policy issues in which science and technology would feature strongly and which would also necessitate public engagement as policies are developed. This was then refined to a short list of top priorities for policy makers. Thirty issues were identified within broad areas of business and technology; energy and environment; government, politics and education; health, healthcare, population and aging; information, communication, infrastructure and transport; and public safety and national security

Ruthenium-europium configuration in the Eu2Ru2O7 pyrochlore

The magnetic and electronic properties of Eu2Ru2O7 are discussed in terms of the local ruthenium and europium coordination, electronic band structure calculations, and molecular orbital energy levels. A preliminary electronic structure was calculated within the local density approximation (LDA) and local spin density approximation taking in to account on-site Hubbard U (LSDA + U). The molecular orbital energy level diagrams have been used to interpret the Eu-Ru ligand spectrum and the ensuing magnetic properties. The orbital hybridizations and bonds are discussed. © 2015 AIP Publishing LLC

Enjoyment of the shopping experience:impact on customers’ repatronage intentions and gender influence

In this paper the authors investigate enjoyment of the shopping experience, its influence on consumers’ intention to repatronise a regional shopping centre and the effect of gender differences on shopping enjoyment. Four dimensions of shopping enjoyment are proposed and a 16-item measure is developed to assess 536 consumer perceptions of the shopping experience across five counties in the United Kingdom. Findings indicate that shopping experience enjoyment has a significant positive influence upon customers’ repatronage intentions. Furthermore, men are found to have a stronger relationship of enjoyment with repatronage than women. The implications of these results are discussed, together with managerial implications, study limitations, and future research directions