4,334 research outputs found
Delimited Massively Parallel Algorithm based on Rules Elimination for Application of Active Rules in Transition P Systems
In the field of Transition P systems implementation, it has been determined that it is very important to determine in advance how long takes evolution rules application in membranes. Moreover, to have time estimations of rules application in membranes makes possible to take important decisions related to hardware/software architectures design.
The work presented here introduces an algorithm for applying active evolution rules in Transition P systems, which is based on active rules elimination. The algorithm complies the requisites of being nondeterministic, massively parallel, and what is more important, it is time delimited because it is only dependant on the number of membrane evolution rules
A Mathematical Assessment of the Isolation Tree Method for Outliers Detection in Big Data
In this paper, the mathematical analysis of the Isolation Random Forest
Method (IRF Method) for anomaly detection is presented. We show that the IRF
space can be endowed with a probability induced by the Isolation Tree algorithm
(iTree). In this setting, the convergence of the IRF method is proved using the
Law of Large Numbers. A couple of counterexamples are presented to show that
the original method is inconclusive and no quality certificate can be given,
when using it as a means to detect anomalies. Hence, an alternative version of
IRF is proposed, whose mathematical foundation, as well as its limitations, are
fully justified. Finally, numerical experiments are presented to compare the
performance of the classic IRF with the proposed one.Comment: 21 pages, 14 figures, 3 table
Objective Priors for Estimation of Extended Exponential Geometric Distribution
A Bayesian analysis was developed with different noninformative prior distributions such as Jeffreys, Maximal Data Information, and Reference. The aim was to investigate the effects of each prior distribution on the posterior estimates of the parameters of the extended exponential geometric distribution, based on simulated data and a real application
Direct Visual Servoing Framework based on Optimal Control for Redundant Joint Structures
This paper presents a new framework based on optimal control to define new dynamic visual controllers to carry out the guidance of any serial link structure. The proposed general method employs optimal control to obtain the desired behaviour in the joint space based on an indicated cost function which determines how the control effort is distributed over the joints. The proposed approach allows the development of new direct visual controllers for any mechanical joint system with redundancy. Finally, authors show experimental results and verifications on a real robotic system for some derived controllers obtained from the control framework.This work was funded by the Spanish Ministry of Economy, the European FEDER funds and the Valencia Regional Government, through the research projects DPI2012-32390 and PROMETEO/2013/085
Matter-antimatter asymmetry without departure from thermal equilibrium
We explore the possibility of baryogenesis without departure from thermal
equilibrium. A possible scenario is found, though it contains strong
constraints on the size of the violation () effects and on the role
of the (baryon number) nonconserving interactions which are needed for it.Comment: Revtex, 4page
The Effect Of 4-halogenobenzoate Ligands On Luminescent And Structural Properties Of Lanthanide Complexes: Experimental And Theoretical Approaches
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)The ligands 4-fluorobenzoate (4-fba), 4-chlorobenzoate (4-cba), 4-bromobenzoate (4-bba) and 4-iodobenzoate (4-iba) were chosen in order to synthesize europium(III), gadolinium(III) and terbium(III) complexes and compare the effect of halogens on their physical chemistry and luminescent properties. The homobimetallic complex [Eu(4-iba)(3)(H2O)(dmf)](2) crystallizes in the monoclinic P2(1)/c space group with unit cell parameters a = 8.3987(9) angstrom, b = 25.314(3) angstrom, c = 14.1255(17) angstrom, and beta = 105.347(2)degrees 1. FTIR spectroscopy indicates that the bidentate bridging mode of the carboxylato ligand was present in all complexes while bidentate chelate and a mixture of bidentate bridging and chelate modes were also found. According to emission spectra profiles and the Judd-Ofelt parameters the halogen of ligand molecules modifies the chemical environment symmetry around the europium(III) ion in their respective complexes. The complexes [Eu(4-fba)(3)(H2O)(2)] and [Eu(4-iba)(3)(H2O)(2)] have the highest symmetry around the europium(III) while the complexes [Eu(4-cba)(3)]center dot 2H(2)O, [Eu(4-bba)(3)]center dot 5/2H(2)O and [Eu(4-iba)(3)(H2O)(dmf)](2) have the lowest. The different halogens at the para position do not change the covalence degree of Eu-O bonds significantly, however they play a role in the ligand to metal charge transfer energies. The highest non-radiative energy transfer rates from ligand to europium(III) were found for the complexes [Eu(4-cba)(3)]center dot 2H(2)O and [Eu(4-bba)(3)]center dot 5/2H(2)O.39318831891Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)NSF [CHE 1363325]Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)FAPESP [2008/53868-0]FAPESP [2009/54066-7
Chemical evolution of the colour systems generated by riccionidin A, 3-deoxyanthocyanidins and anthocyanins
UIDB/50006/2020
MEX/Ref. 288188The kinetics and thermodynamics (in acidic solutions) of the five chemical species reversibly interconnected by external stimuli (a multistate), such as pH and light, generated by the liverworts colorant riccionidin A were investigated. The degradation products of the multistate formed after 10 days at neutral pH were identified. The behaviour of riccionidin A multistate was compared with previous results reported for the equivalent systems based on 3-deoxyanthocyanidins (found in mosses and ferns) and anthocyanins (ubiquitous in angiosperms). The five chemical species have mutatis mutandis similar structures in the three multistates. The most dramatic difference is the extremely slow interconversion rate between flavylium cation and trans-chalcone in riccionidin A and related compounds multistates (tens of days) when compared with deoxyanthocyanins (a few days) and anthocyanins (several hours), at room temperature. The mole fraction distribution of the five species that constitute the multistate as a function of pH is also different in the three families of compounds. Some considerations regarding the chemical evolution of the three systems are given.authorsversionpublishe
Culture conditions for zinc- and pH-regulated gene expression studies in Aspergillus fumigatus
In Aspergillus fumigatus, the regulation of zinc homeostasis is strongly influenced by environmental pH. Thus, the study of zinc-regulated gene expression in A. fumigatus requires controlling variations in culture pH, as this may affect zinc availability. However, depending on the nitrogen source, the pH of the culture can change dramatically over time. In addition, due to the ubiquitous distribution of zinc and that it is an essential micronutrient required in minute amounts for optimal fungal growth, neither buffering of the culture media to prevent pH variations nor the use of chelating agents is advisable if
mycelium is to be used for expression analyses. In this work, the growth of A. fumigatus in several culture media was examined in order to determine the conditions yielding mycelia suitable for gene expression analyses in acid and neutral media, regardless of zinc availability. Our results showed that a zinc-limiting synthetic basal medium could be readily converted into a zinc-replete one and subsequently into acid or neutral medium by using, respectively, ammonium or nitrate as nitrogen source. [Int Microbiol 2007; 10(3):187-192
Development of Prometeu autonomous robot for ball handling in Eurobot
Eurobot is a robotics European challenge for the young generation (university and technical schools) which is held annually, with a different challenge in every
edition, and participate around about 200 teams every year.
Each game comprises two teams competing against each other and does not allow draws. This work describes the design, development and building up of an autonomous mobile robot to fulfill this challenge. This paper includes the challenge description, robot design, sensors used, the strategy used and some conclusion. The team that built this robot and participated on Eurobot is made up of 4 industrial electronic undergraduate students from University of Minho
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