Mo- and W-Fiber Reinforced SiCN Ceramic Matrix Composites based on PIP process

Mo- and W-fiber reinforced CMCs can be easily manufactured via polymer infiltration and pyrolysis at 1300 °C (PIP) Mo/SiCN and W/SiCN composites are light-weight in comparison to Mo/Mo and W/W composites Mo/SiCN and W/SiCN show increased fracture strain compared to CMCs Mo/SiCN and W/SiCN can be considered as WMCs and thus need no weak interphase Microstructural and phase analyses have shown that Mo- and W-fibers are still present and thermally resistant in the SiCN matrix even at 1300 °C Thermodynamical calculations strongly recommend an additional fiber coating from C-attack! Microstructural and phase analyses have shown that Mo- and W-fibers suffer from surfacial attack, mainly by C-based materials Applying a coating as reaction barrier (e.g. Y2O3) should provide further improvement in mechanical properties New applications are feasible due to: increased fracture strain good tensile and fracture strain high stiffness high thermal conductivity low thermal expansion high thermal shock resistance anisotropic behaviour of composite according to tailor-made desig

Mo- and W-Fiber Reinforced SiCN Ceramic Matrix Composites based on PIP process

Mo- and W-fiber reinforced CMCs can be easily manufactured via polymer infiltration and pyrolysis at 1300 °C (PIP) Mo/SiCN and W/SiCN composites are light-weight in comparison to Mo/Mo and W/W composites Mo/SiCN and W/SiCN show increased fracture strain compared to CMCs Mo/SiCN and W/SiCN can be considered as WMCs and thus need no weak interphase Microstructural and phase analyses have shown that Mo- and W-fibers are still present and thermally resistant in the SiCN matrix even at 1300 °C Thermodynamical calculations strongly recommend an additional fiber coating from C-attack! Microstructural and phase analyses have shown that Mo- and W-fibers suffer from surfacial attack, mainly by C-based materials Applying a coating as reaction barrier (e.g. Y2O3) should provide further improvement in mechanical properties New applications are feasible due to: increased fracture strain good tensile and fracture strain high stiffness high thermal conductivity low thermal expansion high thermal shock resistance anisotropic behaviour of composite according to tailor-made desig

Novel ceramic matrix composites with tungsten and molybdenum fiber reinforcement

Ceramic matrix composites usually utilize carbon or ceramic fbers as reinforcements. However, such fbers often expose a low ductility during failure. In this work, we follow the idea of a reinforcement concept of a ceramic matrix reinforced by refractory metal fbers to reach pseudo ductile behavior during failure. Tungsten and molybdenum fbers were chosen as reinforcement in SiCN ceramic matrix composites manufactured by polymer infltration and pyrolysis process. The composites were investigated with respect to microstructure, flexural- and tensile strength. The single fber strengths for both tungsten and molybdenum were investigated and compared to the strength of the composites. Tensile strengths of 206 and 156 MPa as well as bending strengths of 427 and 312 MPa were achieved for W/SiCN and Mo/SiCN composites, respectively. The W fber became brittle across the entire cross section, while the Mo fber showed a superfcial, brittle reaction zone but kept ductile on the inside

Novel ceramic matrix composites with tungsten and molybdenum fiber reinforcement

Damage-tolerant ceramic matrix composites (CMC) are prone to high temperature applications under severe environmental conditions and usually utilize carbon or ceramic fibres (e.g. SiC) as reinforcements of ceramic matrices with inherent low elongation to break compared to common metals. However, CMC reveal an elongation to break and stiffness similar to the ceramic matrices, and thus need a fibre coating in order to improve the elongation to break length and thus to achieve damage tolerance of the composite. In addition, such fibers often expose a low ductility during failure. As a consequence, design criteria for components of such CMC materials are limited by the low strain of failure. In order to overcome this problem, we follow the idea of a reinforcement concept of a ceramic matrix reinforced by refractory metal fibres to reach pseudo ductile behaviour during failure. Tungsten (W) and molybdenum (Mo) fibers were chosen as reinforcement in SiCN CMC manufactured by polymer infiltration and pyrolysis process. These fibres are commercially available since they are widespread used in light bulbs, etc. , and possess an intrinsic higher elongation to break, compared to ceramic fibres, as well as high stiffness even at high temperatures. W/SiCN and Mo/SiCN composites were manufactured via filament winding and resin transfer moulding of commercially available polysilazanes, pyrolysed and re-densified by multiple reinfiltration and pyrolysis steps. These composites were investigated with respect to microstructure, flexural and tensile strength. Single fibre strengths for W and Mo were investigated and compared to the strength of the composites. Tensile strengths of 206 and 156 MPa as well as bending strengths of 427 and 312 MPa were achieved for W/SiCN and Mo/SiCN composites, respectively. W fibre became brittle across the entire cross section, while the Mo fibre showed a superficial, brittle reaction zone but kept ductile on the inside

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Ceramic matrix composites usually utilize carbon or ceramic fibers as reinforcements. However, such fibers often expose a low ductility during failure. In this work, we follow the idea of a reinforcement concept of a ceramic matrix by refractory metal fibers to reach pseudo ductile behavior during failure. Tungsten and molybdenum fibers were chosen as reinforcement in SiCN ceramic matrix composites manufactured by polymer infiltration and pyrolysis process. The composites were investigated with respect to microstructure, flexural- and tensile strength. The single fiber strengths for both tungsten and molybdenum were investigated and compared to the strength of the composites. Tensile strengths of 206 and 156 MPa as well as bending strengths of 427 and 312 were achieved for W/SiCN and Mo/SiCN composites, respectively. The W fiber became brittle across the entire cross section, while the Mo fiber showed a superficial, brittle reaction zone but kept ductile on the inside

Novel ceramic matrix composites with tungsten and molybdenum fiber reinforcement

Ceramic matrix composites usually utilize carbon or ceramic fibers as reinforcements. However, such fibers often expose a low ductility during failure. In this work, we follow the idea of a reinforcement concept of a ceramic matrix reinforced by refractory metal fibers to reach pseudo ductile behavior during failure. Tungsten and molybdenum fibers were chosen as reinforcement in SiCN ceramic matrix composites manufactured by polymer infiltration and pyrolysis process. The composites were investigated with respect to microstructure, flexuraland tensile strength. The single fiber strengths for both tungsten and molybdenum were investigated and compared to the strength of the composites. Tensile strengths of 206 and 156 MPa as well as bending strengths of 427 and 312 MPa were achieved for W/SiCN and Mo/SiCN composites, respectively. The W fiber became brittle across the entire cross section, while the Mo fiber showed a superficial, brittle reaction zone but kept ductile on the inside