Near threshold rotational excitation of molecular ions by electron-impact

New cross sections for the rotational excitation of H$_3^+$ by electrons are calculated {\it ab initio} at low impact energies. The validity of the adiabatic-nuclei-rotation (ANR) approximation, combined with $R$-matrix wavefunctions, is assessed by comparison with rovibrational quantum defect theory calculations based on the treatment of Kokoouline and Greene ({\it Phys. Rev. A} {\bf 68} 012703 2003). Pure ANR excitation cross sections are shown to be accurate down to threshold, except in the presence of large oscillating Rydberg resonances. These resonances occur for transitions with $\Delta J=1$ and are caused by closed channel effects. A simple analytic formula is derived for averaging the rotational probabilities over such resonances in a 3-channel problem. In accord with the Wigner law for an attractive Coulomb field, rotational excitation cross sections are shown to be large and finite at threshold, with a significant but moderate contribution from closed channels.Comment: 3 figures, a5 page

Quasi-classical rate coefficient calculations for the rotational (de)excitation of H2O by H2

The interpretation of water line emission from existing observations and future HIFI/Herschel data requires a detailed knowledge of collisional rate coefficients. Among all relevant collisional mechanisms, the rotational (de)excitation of H2O by H2 molecules is the process of most interest in interstellar space. To determine rate coefficients for rotational de-excitation among the lowest 45 para and 45 ortho rotational levels of H2O colliding with both para and ortho-H2 in the temperature range 20-2000 K. Rate coefficients are calculated on a recent high-accuracy H2O-H2 potential energy surface using quasi-classical trajectory calculations. Trajectories are sampled by a canonical Monte-Carlo procedure. H2 molecules are assumed to be rotationally thermalized at the kinetic temperature. By comparison with quantum calculations available for low lying levels, classical rates are found to be accurate within a factor of 1-3 for the dominant transitions, that is those with rates larger than a few 10^{-12}cm^{3}s^{-1}. Large velocity gradient modelling shows that the new rates have a significant impact on emission line fluxes and that they should be adopted in any detailed population model of water in warm and hot environments.Comment: 8 pages, 2 figures, 1 table (the online material (4 tables) can be obtained upon request to [email protected]

Upper bound on the density of Ruelle resonances for Anosov flows

Using a semiclassical approach we show that the spectrum of a smooth Anosov vector field V on a compact manifold is discrete (in suitable anisotropic Sobolev spaces) and then we provide an upper bound for the density of eigenvalues of the operator (-i)V, called Ruelle resonances, close to the real axis and for large real parts.Comment: 57 page

Collisional excitation of doubly and triply deuterated ammonia ND2_2H and ND3_3 by H2_2

The availability of collisional rate coefficients is a prerequisite for an accurate interpretation of astrophysical observations, since the observed media often harbour densities where molecules are populated under non--LTE conditions. In the current study, we present calculations of rate coefficients suitable to describe the various spin isomers of multiply deuterated ammonia, namely the ND$_2$H and ND$_3$ isotopologues. These calculations are based on the most accurate NH$_3$--H$_2$ potential energy surface available, which has been modified to describe the geometrical changes induced by the nuclear substitutions. The dynamical calculations are performed within the close--coupling formalism and are carried out in order to provide rate coefficients up to a temperature of $T$ = 50K. For the various isotopologues/symmetries, we provide rate coefficients for the energy levels below $\sim$ 100 cm$^{-1}$. Subsequently, these new rate coefficients are used in astrophysical models aimed at reproducing the NH$_2$D, ND$_2$H and ND$_3$ observations previously reported towards the prestellar cores B1b and 16293E. We thus update the estimates of the corresponding column densities and find a reasonable agreement with the previous models. In particular, the ortho--to--para ratios of NH$_2$D and NHD$_2$ are found to be consistent with the statistical ratios

Effects of nanoparticles on murine macrophages

Metallic nanoparticles are more and more widely used in an increasing number of applications. Consequently, they are more and more present in the environment, and the risk that they may represent for human health must be evaluated. This requires to increase our knowledge of the cellular responses to nanoparticles. In this context, macrophages appear as an attractive system. They play a major role in eliminating foreign matter, e.g. pathogens or infectious agents, by phagocytosis and inflammatory responses, and are thus highly likely to react to nanoparticles. We have decided to study their responses to nanoparticles by a combination of classical and wide-scope approaches such as proteomics. The long term goal of this study is the better understanding of the responses of macrophages to nanoparticles, and thus to help to assess their possible impact on human health. We chose as a model system bone marrow-derived macrophages and studied the effect of commonly used nanoparticles such as TiO2 and Cu. Classical responses of macrophage were characterized and proteomic approaches based on 2D gels of whole cell extracts were used. Preliminary proteomic data resulting from whole cell extracts showed different effects for TiO2-NPs and Cu-NPs. Modifications of the expression of several proteins involved in different pathways such as, for example, signal transduction, endosome-lysosome pathway, Krebs cycle, oxidative stress response have been underscored. These first results validate our proteomics approach and open a new wide field of investigation for NPs impact on macrophagesComment: Nanosafe2010: International Conference on Safe Production and Use of Nanomaterials 16-18 November 2010, Grenoble, France, Grenoble : France (2010

High-energy acceleration phenomena in extreme radiation-plasma interactions

We simulate, using a particle-in-cell code, the chain of acceleration processes at work during the Compton-based interaction of a dilute electron-ion plasma with an extreme-intensity, incoherent gamma-ray flux with a photon density several orders of magnitude above the particle density. The plasma electrons are initially accelerated in the radiative flux direction through Compton scattering. In turn, the charge-separation field from the induced current drives forward the plasma ions to near-relativistic speed and accelerates backwards the non-scattered electrons to energies easily exceeding those of the driving photons. The dynamics of those energized electrons is determined by the interplay of electrostatic acceleration, bulk plasma motion, inverse Compton scattering and deflections off the mobile magnetic fluctuations generated by a Weibel-type instability. The latter Fermi-like effect notably gives rise to a forward-directed suprathermal electron tail. We provide simple analytical descriptions for most of those phenomena and examine numerically their sensitivity to the parameters of the problem

Imaging of a Case of Extramedullary Solitary Plasmacytoma of the Trachea

We describe a case of extramedullary tracheal plasmacytoma that was incidentally discovered in a 73-year-old man on a PET scan performed for assessing the extent of colon cancer. CT scan showed the tumor; multiplanar reformation coupled with virtual bronchoscopy allowed proper treatment planning. The tracheal tumor was resected during rigid bronchoscopy. Relevant investigations excluded multiple myeloma. Follow-up CT showed persistent thickening of the tracheal wall, but there has been no recurrence after one-year followup

Probing the Slope of Cluster Mass Profile with Gravitational Einstein Rings: Application to Abell 1689

The strong lensing modelling of gravitational ``rings'' formed around massive galaxies is sensitive to the amplitude of the external shear and convergence produced by nearby mass condensations. In current wide field surveys, it is now possible to find out a large number of rings, typically 10 gravitational rings per square degree. We propose here, to systematically study gravitational rings around galaxy clusters to probe the cluster mass profile beyond the cluster strong lensing regions. For cluster of galaxies with multiple arc systems, we show that rings found at various distances from the cluster centre can improve the modelling by constraining the slope of the cluster mass profile. We outline the principle of the method with simple numerical simulations and we apply it to 3 rings discovered recently in Abell~1689. In particular, the lens modelling of the 3 rings confirms that the cluster is bimodal, and favours a slope of the mass profile steeper than isothermal at a cluster radius \sim 300 \kpc. These results are compared with previous lens modelling of Abell~1689 including weak lensing analysis. Because of the difficulty arising from the complex mass distribution in Abell~1689, we argue that the ring method will be better implemented on simpler and relaxed clusters.Comment: Accepted for publication in MNRAS. Substantial modification after referee's repor

Mechanical Properties and Oxidation Behaviour of Electroconductive Ceramic Composites

International audienceDense electroconductive ceramic-ceramic composites silicon carbide-hafnium diboride (SiC-HfB2) and silicon carbide-hafnium carbide (SiC-HfC) were obtained by Hot Pressing (HP). In view of the results, the high performance composite grade SiC-HfB2 has also been elaborated by Hot Isostatic Pressing (HIP). For 25 mol % HfC or HfB2 content, the resistivity was low enough to allow electrodischarged machining (EDM). The mechanical and thermal properties as well as the wear and oxidation behaviours were evaluated and compared. The electroconductive boride composite (75-25 mol% SiC-HfB2) exhibits high mechanical properties. The benefit of the diboride phase's presence is also noticed in fluent oxygen, up to 1450°C. The SiC-HfB2 composite is as resistant as silicon carbide. This behaviour may be related to the formation of a borosilicate based oxide layer containing hafnium phases, which plays the role of a coating and which limits the B2O3 evaporation

Zeta functions and Dynamical Systems

In this brief note we present a very simple strategy to investigate dynamical determinants for uniformly hyperbolic systems. The construction builds on the recent introduction of suitable functional spaces which allow to transform simple heuristic arguments in rigorous ones. Although the results so obtained are not exactly optimal the straightforwardness of the argument makes it noticeable.Comment: 7 pages, no figuer