1,893 research outputs found

    The Role of the Unconscious in the Perception of Risks

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    Dr. Fritzsche argues that our world is too rational and that the psychology of the unconscious, as developed by Jung, can be key to understanding responses to hazards and to resolving conflicts that arise in the political management of risks

    The Moral Dilemma in the Social Management of Risks

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    Dr. Fritzsche offers data seen as demonstrating that irrational fears can lead to grotesque imbalances in social efforts devoted to preventing fatalities

    Quantitative determination of the local structure of thymine on Cu(1 1 0) using scanned-energy mode photoelectron diffraction

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    The local adsorption structures of the surface species formed by interaction of thymine with a Cu(1 1 0) surface at room temperature, and after heating to not, vert, similar530 K, have been investigated. Initial characterisation by soft-X-ray photoelectron spectroscopy and O K-edge near-edge X-ray absorption fine structure (NEXAFS) indicates the effect of sequential dehydrogenation of the NH species and provides information on the molecular orientation. O 1s and N 1s scanned-energy mode photoelectron diffraction shows the species at both temperatures bond to the surface through both carbonyl O atoms and the deprotonated N atom between them, each bonding atom adopting near-atop sites on the outermost Cu surface layer. The associated bondlengths are 1.96 ± 0.03 Å for Cu–N and 1.91 ± 0.03 Å and 2.03 ± 0.03 Å for the two inequivalent Cu--O bonds. The molecular plane lies almost exactly in the close-packed View the MathML source azimuth, but with a tilt relative to the surface normal of approximately 20°. Heating to not, vert, similar530 K, or deposition at this temperature, appears to lead to dehydrogenation of the second N atom in the ring, but no significant change in the adsorption geometry

    The Implementation of the Renormalized Complex MSSM in FeynArts and FormCalc

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    We describe the implementation of the renormalized complex MSSM (cMSSM) in the diagram generator FeynArts and the calculational tool FormCalc. This extension allows to perform UV-finite one-loop calculations of cMSSM processes almost fully automatically. The Feynman rules for the cMSSM with counterterms are available as a new model file for FeynArts. Also included are default definitions of the renormalization constants; this fixes the renormalization scheme. Beyond that all model parameters are generic, e.g. we do not impose any relations to restrict the number of input parameters. The model file has been tested extensively for several non-trivial decays and scattering reactions. Our renormalization scheme has been shown to give stable results over large parts of the cMSSM parameter space.Comment: 29 pages, extended chargino/neutralino and sfermion renormalization schemes, version accepted for publication in Comp. Phys. Commu

    The local structure of SO2 and SO3 on Ni(1 1 1): a scanned-energy mode photoelectron diffraction study

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    O 1s and S 2p scanned-energy mode photoelectron diffraction (PhD) data, combined with multiple-scattering simulations, have been used to determine the local adsorption geometry of the SO2 and SO3 species on a Ni(1 1 1) surface. For SO2, the application of reasonable constraints on the molecular conformation used in the simulations leads to the conclusion that the molecule is centred over hollow sites on the surface, with the molecular plane essentially parallel to the surface, and with both S and O atoms offset from atop sites by almost the same distance of 0.65 Ă…. For SO3, the results are consistent with earlier work which concluded that surface bonding is through the O atoms, with the S atom higher above the surface and the molecular symmetry axis almost perpendicular to the surface. Based on the O 1s PhD data alone, three local adsorption geometries are comparably acceptable, but only one of these is consistent with the results of an earlier normal-incidence X-ray standing wave (NIXSW) study. This optimised structural model differs somewhat from that originally proposed in the NIXSW investigation

    Hairpins in the conformations of a confined polymer

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    If a semiflexible polymer confined to a narrow channel bends around by 180 degrees, the polymer is said to exhibit a hairpin. The equilibrium extension statistics of the confined polymer are well understood when hairpins are vanishingly rare or when they are plentiful. Here we analyze the extension statistics in the intermediate situation via experiments with DNA coated by the protein RecA, which enhances the stiffness of the DNA molecule by approximately one order of magnitude. We find that the extension distribution is highly non-Gaussian, in good agreement with Monte Carlo simulations of confined discrete wormlike chains. We develop a simple model that qualitatively explains the form of the extension distribution. The model shows that the tail of the distribution at short extensions is determined by conformations with one hairpin.Comment: Revised version. 22 pages, 7 figures, 2 tables, supplementary materia

    Klinische Bedeutung der aktivierten Thrombelastographie mit einem neuen Point-of-care-Analysegerät bei Routine-Herz-Operationen

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    Zur frühzeitigen gezielten Therapie perioperativer Blutungen bei herzchirurgischen Eingriffen ist eine point-of-care-Methode erforderlich, die Gerinnungsstörungen rasch erkennen und differenzieren lässt. In dieser Studie wurde der klinische Nutzen eines neuen Thrombelastographie-Systems zur perioperativen Gerinnungsüberwachung bei 42 konsekutiven herzchirurgischen Patienten zu fünf Messzeitpunkten evaluiert. Insbesondere interessierte die mögliche Vorhersagbarkeit und Differenzierung des postoperativen Blutverlustes. Das Thrombelastogramm (TEG) zeigte zuverlässig den bekannten charakteristischen Verlauf der operationsbedingten Gerinnungsbeeinträchtigung. Signifikante Korrelationen des Blutverlustes mit den erfassten Parametern fanden sich jedoch nicht. Trotz geringem Blutverlust war das TEG in 9 Fällen pathologisch. Ob Koagulopathien bei postoperativen Blutungen mit dieser Methode adäquat zu differenzieren sind, ließ sich aufgrund des geringen Blutverlustes nicht klären

    The local structure of OH species on the V2O3(0 0 0 1) surface: a scanned-energy mode photoelectron diffraction study

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    Scanned-energy mode photoelectron diffraction (PhD), using O 1s photoemission, together with multiple-scattering simulations, have been used to investigate the structure of the hydroxyl species, OH, adsorbed on a V2O3(0 0 0 1) surface. Surface OH species were obtained by two alternative methods; reaction with molecular water and exposure to atomic H resulted in closely similar PhD spectra. Both qualitative assessment and the results of multiple-scattering calculations are consistent with a model in which only the O atoms of outermost layer of the oxide surface are hydroxylated. These results specifically exclude significant coverage of OH species atop the outermost V atoms, i.e. in vanadyl O atom sites. Ab initio density-functional theory cluster calculations provide partial rationalisation of this result, which is discussed the context of the general understanding of this system
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