Metamorphism on Chromite Ores from the Dobromirtsi Ultramafic Massif, Rhodope Mountains (SE Bulgaria)

Podiform chromitite bodies occur in highly serpentinized peridotites at Dobromirtsi Ultramafic Massif (Rhodope Mountains, southeastern Bulgaria). The ultramafic body is believed to represent a fragment of Palaeozoic ophiolite mantle. The ophiolite sequence is associated with greenschist - lower-temperature amphibolite facies metamorphosed rocks (biotitic gneisses hosting amphibolite). This association suggests that peridotites, chromitites and metamorphic rocks underwent a common metamorphic evolution. Chromitites at Dobromirtsi have been strongly altered. Their degree of alteration depends on the chromite/silicate ratio and to a lesser extent, on the size of chromitite bodies. Alteration is recorded in individual chromite grains in the form of optical and chemical zoning. Core to rim chemical trends are expressed by MgO- and Al2O3- impoverishment, mainly compensated by FeO and/or Fe2O3 increases. Such chemical variations correspond with three main alteration events. The first one was associated with ocean-floor metamorphism and was characterized by a lizardite replacement of olivine and the absence of chromite alteration. The second event took place during greenchist facies metamorphism. During this event, MgO- and SiO2-rich fluids (derived from low temperatura serpentinization of olivine and pyroxenes) reacted with chromite to form chlorite; as a consequence, chromite became altered to a FeO- and Cr2O3-rich, Al2O3-poor chromite. The third event, mainly developed during lower temperature amphibolite facies metamorphism, caused the replacement of the primary and previously altered chromite by Fe2O3-rich chromite (ferritchromite)

Las cromititas ofiolíticas del yacimiento Mercedita (Cuba). Un ejemplo de cromitas ricas en Al en la zona de transición manto-corteza

The Mercedita deposit is located in the ophiolitic Massif of Moa-Baracoa (NE of Cuba) and is considered the most important podiform chromite deposit of America. Chromitite bodies, enclosed in hazbu rgite and residual dunites (mantle-crust transition zone). The chromite ore bodies are concordant with the main structures shown by the enclosing peridotites and also display pull-apart fractures. Chromite lenses enclose and substitute grabbro bodies (sills), that are concordant with the orientation of the host chromitite. Intergranular minerals are olivine, serpentine, and chlorite. Chromite has abundant, distributed solid inclusions of olivine and Na-rich pargasite (up 4 wt % Na2O), and minor laurite and millerite. Toward the contact with the included gabbro sills, abundant clinopy r oxene, plagioclase and rutile occur as inclusions in the chromite. The ores from Mercedita deposit are composed by refractary - grade chromite (Al-rich chromite), where A l 2 O 3 ranges between 25 and 33wt.%. The TiO2 values are relative ly high compared to the most common ophiolitic chromite, TiO2 content varies from 0.05 to 0.52 wt. %. Chromitites of the Mercedita deposit are poor in platinum-group elements (PGE), with total PGE ranging between 55.8 and 165.9 ppb and an average value of 90 ppb. From textural and geochemical data we propose a genetic model from the reaction of a back arc basin basalt, formed by melt-rock reactions, percolated through subhorizontal, porous dunitic channels and mixed with oxidized melts in suprasubduction zone mantle. Mixing of these two melts generated a hybrid melt whose bulk composition fell within the chromite liquidus field in the P-T- fO2 space (Hill and Roeder, 1974). Percolation of the hybrid melt through the dunitic channels promoted dissolution of preexisting silicate minerals and chromite crystallization

Ophiolite-Related Ultramafic Rocks (Serpentinites) in the Caribbean Region : a Review of their Occurrence, Composition, Origin, Emplacement and Ni-Laterite Soil Formation

Ultramafic rocks, mainly serpentinized peridotites of mantle origin, are mostly associated with the ophiolites of Mesozoic age that occur in belts along three of the margins of the Caribbean plate. The most extensive exposures are in Cuba. The ultramafic-mafic association (ophiolites) were formed and emplaced in several different tectonic environments. Mineralogical studies of the ultramafic rocks and the chemistry of the associated mafic rocks indicate that most of the ultramafic-mafic associations in both the northern and southern margins of the plate were formed in arc-related environments. There is little mantle peridotite exposed in the ophiolitic associations of the west coast of Central America, in the south Caribbean in Curacao and in the Andean belts in Colombia. In these occurrences the chemistry and age of the mafic rocks indicates that this association is mainly part of the 89 Ma Caribbean plateau province. The age of the mantle peridotites and associated ophiolites is probably mainly late Jurassic or Early Cretaceous. Emplacement of the ophiolites possibly began in the Early Cretaceous in Hispaniola and Puerto Rico, but most emplacement took place in the Late Cretaceous to Eocene (e.g. Cuba). Along the northern South America plate margin, in the Caribbean mountain belt, emplacement was by major thrusting and probably was not completed until the Oligocene or even the early Miocene. Caribbean mantle peridotites, before serpentinization, were mainly harzburgites, but dunites and lherzolites are also present. In detail, the mineralogical and chemical composition varies even within one ultramafic body, reflecting melting processes and peridotite/melt interaction in the upper mantle. At least for the northern Caribbean, uplift (postemplacement tectonics) exposed the ultramafic massifs as a land surface to effective laterization in the beginning of the Miocene. Tectonic factors, determining the uplift, exposing the peridotites to weathering varied. In the northern Caribbean, in Guatemala, Jamaica, and Hispaniola, uplift occurred as a result of transpresional movement along pre-existing major faults. In Cuba, uplift occurred on a regional scale, determined by isostatic adjustment. In the south Caribbean, uplift of the Cordillera de la Costa and Serrania del Interior exposing the peridotites, also appears to be related to strike-slip movement along the El Pilar fault system. In the Caribbean, Ni-laterite deposits are currently being mined in the central Dominican Republic, eastern Cuba, northern Venezuela and northwest Colombia. Although apparently formed over ultramafic rocks of similar composition and under similar climatic conditions, the composition of the lateritic soils varies. Factors that probably determined these differences in laterite composition are geomorphology, topography, drainage and tectonics. According to the mineralogy of principal ore-bearing phases, Dominican Ni-laterite deposits are classified as the hydrous silicate-type. The main Ni-bearing minerals are hydrated Mg-Ni silicates (serpentine and "garnierite") occurring deeper in the profile (saprolite horizon). In contrast, in the deposits of eastern Cuba, the Ni and Co occurs mainly in the limonite zone composed of Fe hydroxides and oxides as the dominant mineralogy in the upper part of the profile, and are classified as the oxide-type

The metallogenic evolution of the Greater Antilles

The Greater Antilles host some of the world’s most important deposits of bauxite and lateritic nickel as well as significant resources of gold and silver, copper, zinc, manganese, cobalt and chromium. Beginning in Jurassic time, sedimentary exhalative base metal deposits accumulated in marine sedimentary rift basins as North and South America drifted apart. With the onset of intraoceanic subduction during the Early Cretaceous, a primitive (tholeiitic) island arc formed above a southwesterly-dipping subduction zone. Podiform chromite deposits formed in the mantle portion of the supra-subduction zone, directly above subducted Proto-Caribbean oceanic lithosphere. Within the nascent island arc, bimodal-mafic volcanogenic massive sulfide deposits formed in a fore-arc setting; mafic volcanogenic massive sulfide deposits formed later in mature back-arc basins. The Pueblo Viejo gold district, with five million ounces in production and twenty million ounces in mineable reserves, formed at 108-112Ma, in an apical rift or back-arc setting. By Late Cretaceous time, calc-alkaline volcanism was well established along the entire length of the Greater Antilles. Volcanogenic massive sulfide deposits including shallow submarine deposits characteristic of the primitive island arc gave way to porphyry copper and epithermal precious metal deposits typical of the mature island arc. Oblique collision of the Greater Antilles with North America began in the Late Cretaceous in Cuba and migrated eastward. Orogenic gold and tungsten deposits that formed during the collision event are preserved in ophiolites and in metamorphic core complexes. Since the Eocene, regional tectonism has been dominated by strike-slip motion as the North American continent moved westward relative to the Caribbean Plate. Large nickel-cobalt laterite deposits were formed when serpentinites were exposed to weathering and erosion during the mid-Tertiary. Bauxite deposits were derived from the weathering of volcanic ash within a carbonate platform of Eocene to Miocene ag

Cromititas podiformes en la Faja Ofiolítica Mayarí-Baracoa (Cuba)

The Mayarí-Baracoa Belt occupies the easternmost part of the east-west-trending Cuban ophiolitic belt. It comprises t wo large, chromite-rich massifs: Mayarí-Cristal and Moa-Baracoa. Chromite deposits can be grouped into tree mining districts according to the chemistry of chromite ore: the Moa-Baracoa district (Al-rich chromite), the Sagua de Tánamo district (Al- and Cr-rich chromite) and the Mayarí district (Cr-rich chromite). Al-rich, Ti-rich chromites occur in the mantle crust transition (associated with harzbu rgites, dunites, plagioclase-bearing peridotites, gabbro sills and gabbro dikes), while Cr-rich, Ti-poor chromites occur in the deeper portions of the ophiolitic sequence (associated with harzbu rgites and dunites). The melts in equilibrium with the Al-rich chromites are close to the composition of the back-arc basin basalts (BABB), whereas the melts in equilibrium with the Cr-rich chromites are similar that of the boninite andesite. Chromite from Mayarí-Baracoa Ophiolite Belt formed when cal-alkaline melts (C), formed by melt-rock reactions, percolated through subhorizontal, porous dunitic channels and mixed with oxidized melts (H) in suprasubduction zone mantle. Mixing of these two melts generated a hybrid melt whose bulk composition fell within the chromite liquidus field in the P-T- fO2 space (Hill and Roeder, 1974). Percolation of the hybrid melt through the dunitic channels promoted dissolution of preexisting silicate minerals and chromite crystallization. Al-rich chromite from Moa-Baracoa should be formed in the distal parts of percolation channels at high fO2 , whereas Cr-rich chromite from Mayarí formed toward the proximal parts of the percolation channels under more reducing conditions

Serpentinites and serpentinites within a fossil subduction channel : La Corea mélange, eastern Cuba

A variety of metaultramafic (serpentinite) rocks in La Corea mélange, Sierra de Cristal, eastern Cuba, show differences in chemical, textural and mineralogical characteristics demonstrating a variety of protoliths. The mélange originated during the Cretaceous as part of the subduction channel associated with the Caribbean island arc. This mélange contains high pressure blocks in a serpentinite matrix and occurs at the base of the large tabular Mayarí-Cristal ophiolite. Two principal groups of serpentinites have been identified in the mélange: a) antigorite serpentinite, mainly composed of antigorite and b) antigorite-lizardite serpentinite, composed of mixtures of antigorite and lizardite and bearing distinctive porphyroblasts of diopsidic clinopyroxene. Antigorite serpentinites are closely related to tectonic blocks of amphibolite (representing subducted MORB) and constitute deep fragments of the serpentinitic subduction channel formed during hydration of the mantle wedge. The composition of the antigorite-lizardite serpentinites and the presence of clinopyroxene porphyroblasts in this type of rock suggest that abyssal lherzolite protoliths transformed into serpentinite before and during incorporation (as tectonic blocks) in the shallow part of the subduction channel. Although the studied rocks have different origin, mineralogical compositions and textures, they display similar PGE compositions, suggesting that these elements experienced no significant redistribution during metamorphism. Both types of serpentinites were exposed together in the La Corea mélange during the Late Cretaceous, during obduction of the overriding Mayarí-Baracoa ophiolitic belt that led to exhumation of the subduction channel (mélange)

Chromite and platinum group elements mineralization in the Santa Elena Ultramafic Nappe (Costa Rica): geodynamic implications

Chromitites associated with strongly altered peridotite from six distinct localities in the Santa Elena ultramafic nappe (Costa Rica) have been investigated for the first time. Santa Elena chromitites commonly display a compositional variation from extremely chromiferous (Cr/(Cr+Al)=0.81) to intermediate and aluminous (Cr/(Cr+Al)=0.54). This composition varies along a continuous trend, corresponding to calculated parental liquids which may have been derived from the differentiation of a single batch of boninitic magma with Cr-rich and (Al, Ti)-poor initial composition. Fractional precipitation of chromite probably occurred during differentiation of the boninitic melt and progressive metasomatic reaction with mantle peridotite. The distribution of platinum group elements (PGE) displays the high (Os+Ir+Ru)/(Rh+Pt+Pd) ratio typical of ophiolitic chromitites and, consistently, the platinum group minerals (PGM) encountered are mainly Ru-Os-Ir sulfides and arsenides. Textural relations of most of the platinum group elements suggest crystallization at magmatic temperatures, possibly under relatively high sulfur fugacity as indicated by the apparent lack of primary Os-Ir-Ru alloys. The chemical and mineralogical characteristics of chromitites from the Santa Elena ultramafic nappe have a strong affinity to podiform chromitites in the mantle section of supra-subduction-zone ophiolites. Calculated parental melts of the chromitites are consistent with the differentiation of arc-related magmas, and do not support the oceanic spreading center geodynamic setting previously proposed by some authors

Ni-sepiolita en depósitos de lateritas de República Dominicana: variaciones composicionales

Depto. de Mineralogía y PetrologíaFac. de Ciencias GeológicasTRUEpu

The Geology of Chile

6 páginas.-- Book review of "The Geology of Chile", by Teresa Moreno and Wes Gibbons (eds.) (2007). Geological Society. London (United Kingdom). 414 pages, 286 figures including maps, charts and pictures; 27, 5 x 21 cm, ISBN 978-1- 86239-219-9 (hardback) and ISBN 978-1-86239-220-5 (softback).Peer reviewe