Optimising woody-weed control

Woody weeds pose significant threats to the 12.3 billion dollar Australian grazing industry. These weeds reduce stocking rate, increase mustering effort, and impede cattle access to waterways. Two major concerns of woody-weed management are the high cost of weed management with respect to grazing gross margins, and episodic seedling recruitments due to climatic conditions. This case study uses a Stochastic Dynamic Programming (SDP) model to determine the optimal weed management decisions for chinee apple (Ziziphus mauritiana) in northern Australian rangelands to maximise grazing profits. Weed management techniques investigated include: no-control, burning, poisoning, and mechanical removal (blade ploughing). The model provides clear weed management thresholds and decision rules, with respect to weed-free gross margins and weed management costs.woody weeds, weed control, chinee apple, rangelands, grazing, stochastic dynamic programming, Livestock Production/Industries,

Levadura seca como inóculo para fermentar rones a escala de planta piloto

The use of distillers' dried yeast as inoculum for rum fermentations was studied on a pilot plant scale. Two fermentation procedures (batch and fed batch) and four levels of dry yeast (0.5, 1.0, 1.5 and 2.0 g/L) were tested. The fermentations were followed for 36 hours. Product yields at 24 hours and 36 hours were determined. The resultant fermentation rate was below the rate required by the local industry (close to completion after 30 hours). This drawback is further complicated by the fact that dried yeast is not stable and has a shelf life that can vary from 1 to 12 months, depending on ambient storage conditions.Se estudió el uso de levadura seca como inóculo para fermentaciones de ron a escala de planta piloto; se probaron dos métodos de fermentación (por tandas y semicontinuo) y cuatro cantidades de levadura seca (0.5, 1.0, 1.5 y 2.0 g./l.). Estas fermentaciones se observaron por 36 horas. Se calculó el rendimiento de etanol a las 24 y 36 horas. La fermentación fue menos rápida de lo que requiere la industria local: fermentación completa a las 30 horas. Este inconveniente se complica porque la levadura va perdiendo actividad con el tiempo, ya que su utilidad, según indicado por el fabricante, fluctúa entre 1 a 12 meses según las condiciones de almacenamiento

A dynamic explanation for the origin of the western Mediterranean organic-rich layers

The eastern Mediterranean sapropels are among the most intensively investigated phenomena in the paleoceanographic record, but relatively little has been written regarding the origin of the equivalent of the sapropels in the western Mediterranean, the organic-rich layers (ORLs). ORLs are recognized as sediment layers containing enhanced total organic carbon that extend throughout the deep basins of the western Mediterranean and are associated with enhanced total barium concentration and a reduced diversity (dysoxic but not anoxic) benthic foraminiferal assemblage. Consequently, it has been suggested that ORLs represent periods of enhanced productivity coupled with reduced deep ventilation, presumably related to increased continental runoff, in close analogy to the sapropels. We demonstrate that despite their superficial similarity, the timing of the deposition of the most recent ORL in the Alboran Sea is different than that of the approximately coincident sapropel, indicating that there are important differences between their modes of formation. We go on to demonstrate, through physical arguments, that a likely explanation for the origin of the Alboran ORLs lies in the response of the western Mediterranean basin to a strong reduction in surface water density and a shoaling of the interface between intermediate and deep water during the deglacial period. Furthermore, we provide evidence that deep convection had already slowed by the time of Heinrich Event 1 and explore this event as a potential agent for preconditioning deep convection collapse. Important differences between Heinrich-like and deglacial-like influences are highlighted, giving new insights into the response of the western Mediterranean system to external forcing

Tracking primary thermalization events in graphene with photoemission at extreme timescales

Direct and inverse Auger scattering are amongst the primary processes that mediate the thermalization of hot carriers in semiconductors. These two processes involve the annihilation or generation of an electron-hole pair by exchanging energy with a third carrier, which is either accelerated or decelerated. Inverse Auger scattering is generally suppressed, as the decelerated carriers must have excess energies higher than the band gap itself. In graphene, which is gapless, inverse Auger scattering is instead predicted to be dominant at the earliest time delays. Here, $<8$ femtosecond extreme-ultraviolet pulses are used to detect this imbalance, tracking both the number of excited electrons and their kinetic energy with time- and angle-resolved photoemission spectroscopy. Over a time window of approximately 25 fs after absorption of the pump pulse, we observe an increase in conduction band carrier density and a simultaneous decrease of the average carrier kinetic energy, revealing that relaxation is in fact dominated by inverse Auger scattering. Measurements of carrier scattering at extreme timescales by photoemission will serve as a guide to ultrafast control of electronic properties in solids for PetaHertz electronics.Comment: 16 pages, 8 figure

Evidence of reduced surface electron-phonon scattering in the conduction band of Bi_{2}Se_{3} by non-equilibrium ARPES

The nature of the Dirac quasiparticles in topological insulators calls for a direct investigation of the electron-phonon scattering at the \emph{surface}. By comparing time-resolved ARPES measurements of the TI Bi_{2}Se_{3} with different probing depths we show that the relaxation dynamics of the electronic temperature of the conduction band is much slower at the surface than in the bulk. This observation suggests that surface phonons are less effective in cooling the electron gas in the conduction band.Comment: 5 pages, 3 figure

Dynamic organization of ligand-grafted nanoparticles during adsorption and surface compression at fluid-fluid interfaces

Monolayers of ligand-grafted nanoparticles at fluid interfaces exhibit a complex response to deformation due to an interplay of particle rearrangements within the monolayer, and molecular rearrangements of the ligand brush on the surface of the particles. We use grazing-incidence small-angle X-ray scattering (GISAXS) combined with pendant drop tensiometry to probe in situ the dynamic organization of ligand-grafted nanoparticles upon adsorption at a fluid–fluid interface, and during monolayer compression. Through the simultaneous measurements of interparticle distance, obtained from GISAXS, and of surface pressure, obtained from pendant drop tensiometry, we link the interfacial stress to the monolayer microstructure. The results indicate that, during adsorption, the nanoparticles form rafts that grow while the interparticle distance remains constant. For small-amplitude, slow compression of the monolayer, the evolution of the interparticle distance bears a signature of ligand rearrangements leading to a local decrease in thickness of the ligand brush. For large-amplitude compression, the surface pressure is found to be strongly dependent on the rate of compression. Two-dimensional Brownian dynamics simulations show that the rate-dependent features are not due to jamming of the monolayer, and suggest that they may be due to out-of-plane reorganization of the particles (for instance expulsion or buckling). The corresponding GISAXS patterns are also consistent with out-of-plane reorganization of the nanoparticles

Evolution of 5-hydroxymethylfurfural (HMF) and furfural (F) in fortified wines submitted to overheating conditions

As furfural (F) and 5-hydroxymethylfurfural (HMF) are essentially formed from sugar dehydration, especially in food submitted to heat, they can be found in beverages, as well as fortified sweet wines. In order to assess the impact of temperature on Madeira winemaking, three traditional varieties of Madeira wines (Malvasia, Sercial and Tinta Negra Mole) were studied to evaluate the F and HMF contents. The wines were produced by two vinification processes, following traditional and modern methodologies, heated at standard conditions (30 °C and 45 °C, for 4 months) and compared with the same wines submitted to overheating conditions (55 °C, for 4 months). The RP-HPLC-DAD methodology used for the control of F and HMF during the process showed no significant changes in the wines maintained at 30 °C (canteiro) and a noticeable but controlled increase in the wines heated at 45 °C (estufagem) where values up to about 150 mg/L of HMF could be found in sweet wines. The strong relation of this compound with the sugar content and baking temperature stood out in the wines submitted to overheating conditions where values higher than 1 g/L could be found for sweeter wines, with HMF level being in general higher than F. The results clearly suggest that the amount of HMF in these fortified wines can be easily controlled when submitted to adequate conditions of heating during estufagem and storage. Furthermore, different temperatures for the baking of sweet and dry wines may be considered

Metal-insulator transition in Nd1−x_{1-x}Eux_{x}NiO3_{3} compounds

Polycrystalline Nd$_{1-x}$Eu$_{x}$NiO$_3$ ($0 \leq x \leq 0.5$) compounds were synthesized in order to investigate the character of the metal-insulator (MI) phase transition in this series. Samples were prepared through the sol-gel route and subjected to heat treatments at $\sim$1000 $^\circ$C under oxygen pressures as high as 80 bar. X-ray Diffraction (XRD) and Neutron Powder Diffraction (NPD), electrical resistivity $\rho(T)$, and Magnetization $M(T)$ measurements were performed on these compounds. The results of NPD and XRD indicated that the samples crystallize in an orthorhombic distorted perovskite structure, space group $Pbnm$. The analysis of the structural parameters revealed a sudden and small expansion of $\sim$0.2% of the unit cell volume when electronic localization occurs. This expansion was attributed to a small increase of $\sim$0.003 \AA{} of the average Ni-O distance and a simultaneous decrease of $\sim$$- 0.5^\circ$ of the Ni-O-Ni superexchange angle. The $\rho(T)$ measurements revealed a MI transition occurring at temperatures ranging from $T_{\rm MI}\sim 193$ to 336 K for samples with $x = 0$ and 0.50, respectively. These measurements also show a large thermal hysteresis in NdNiO$_{3}$ during heating and cooling processes suggesting a first-order character of the phase transition at $T_{\rm MI}$. The width of this thermal hysteresis was found to decrease appreciably for the sample Nd$_{0.7}$Eu$_{0.3}$NiO$_{3}$. The results indicate that cation disorder associated with increasing substitution of Nd by Eu is responsible for changing the first order character of the transition in NdNiO$_{3}$.Comment: 19 pages, 9 figure

Momentum resolved spin dynamics of bulk and surface excited states in the topological insulator Bi2Se3\mathrm{Bi_{2}Se_{3}}

The prospective of optically inducing a spin polarized current for spintronic devices has generated a vast interest in the out-of-equilibrium electronic and spin structure of topological insulators (TIs). In this Letter we prove that only by measuring the spin intensity signal over several order of magnitude in spin, time and angle resolved photoemission spectroscopy (STAR-PES) experiments is it possible to comprehensively describe the optically excited electronic states in TIs materials. The experiments performed on $\mathrm{Bi_{2}Se_{3}}$ reveal the existence of a Surface-Resonance-State in the 2nd bulk band gap interpreted on the basis of fully relativistic ab-initio spin resolved photoemission calculations. Remarkably, the spin dependent relaxation of the hot carriers is well reproduced by a spin dynamics model considering two non-interacting electronic systems, derived from the excited surface and bulk states, with different electronic temperatures.Comment: 5 pages and 4 figure

Esofagitis herpética en un paciente inmunocompetente

Herpetic esophagitis usually occurs more frequently in immunosuppressed patients, however, it has also been documented in immunocompetent patients, although infrequently. In immunocompetent patients, it is usually due to primary infection by the herpes simplex virus, usually type 1. The clinical picture is usually acute in onset and is characterized by the triad of sore throat, retrosternal pain, and fever. Diagnosis is based on the findings of the upper gastrointestinal endoscopy and the taking of biopsies for the study of pathological anatomy and immunohistochemistry. The course is usually benign and early initiation of antiviral treatment allows rapid disappearance of symptoms and limits the severity of the infection.La esofagitis herpética usualmente ocurre con mayor frecuencia en pacientes inmunodeprimidos, sin embargo, también ha sido documentada en pacientes inmunocompetentes, aunque de manera infrecuente. En pacientes inmunocompetentes suele deberse a la primoinfección por el virus del herpes simple, usualmente el tipo 1. El cuadro clínico suele ser de inicio agudo y estar caracterizado por la tríada de odinofagia, dolor retroesternal y fiebre. El diagnóstico se basa en los hallazgos de la videoendoscopia digestiva alta y en la toma de biopsias para el estudio de anatomía patológica e inmunohistoquímica. El curso usualmente es benigno y el inicio del tratamiento antiviral de manera precoz permite lograr la rápida desaparición de los síntomas y limitar la severidad de la infección