966 research outputs found
Large adiabatic temperature and magnetic entropy changes in EuTiO3
We have investigated the magnetocaloric effect in single and polycrystalline
samples of quantum paraelectric EuTiO3 by magnetization and heat capacity
measurements. Single crystalline EuTiO3 shows antiferromagnetic ordering due to
Eu2+ magnetic moments below TN = 5.6 K. This compound shows a giant
magnetocaloric effect around its Neel temperature. The isothermal magnetic
entropy change is 49 Jkg-1K-1, the adiabatic temperature change is 21 K and the
refrigeration capacity is 500 JKg-1 for a field change of 7 T at TN. The single
crystal and polycrystalline samples show similar values of the magnetic entropy
change and adiabatic temperature changes. The large magnetocaloric effect is
due to suppression of the spin entropy associated with localized 4f moment of
Eu2+ ions. The giant magnetocaloric effect together with negligible hysteresis,
suggest that EuTiO3 could be a potential material for magnetic refrigeration
below 20 K.Comment: 12 pages, 4 figure
Layered gadolinium hydroxides for low-temperature magnetic cooling
Layered gadolinium hydroxides have revealed to be excellent candidates for cryogenic magnetic refrigeration. These materials behave as pure 2D magnetic systems with a Heisenberg-Ising critical crossover, induced by dipolar interactions. This 2D character and the possibility offered by these materials to be delaminated open the possibility of rapid heat dissipation upon substrate deposition
Low field magnetotransport in strained Si/SiGe cavities
Low field magnetotransport revealing signatures of ballistic transport
effects in strained Si/SiGe cavities is investigated. We fabricated strained
Si/SiGe cavities by confining a high mobility Si/SiGe 2DEG in a bended nanowire
geometry defined by electron-beam lithography and reactive ion etching. The
main features observed in the low temperature magnetoresistance curves are the
presence of a zero-field magnetoresistance peak and of an oscillatory structure
at low fields. By adopting a simple geometrical model we explain the
oscillatory structure in terms of electron magnetic focusing. A detailed
examination of the zero-field peak lineshape clearly shows deviations from the
predictions of ballistic weak localization theory.Comment: Submitted to Physical Review B, 25 pages, 7 figure
Magnetic long-range order induced by quantum relaxation in single-molecule magnets
Can magnetic interactions between single-molecule magnets (SMMs) in a crystal
establish long-range magnetic order at low temperatures deep in the quantum
regime, where the only electron spin-fluctuations are due to incoherent
magnetic quantum tunneling (MQT)? Put inversely: can MQT provide the
temperature dependent fluctuations needed to destroy the ordered state above
some finite Tc, although it should basically itself be a T-independent process?
Our experiments on two novel Mn4 SMMs provide a positive answer to the above,
showing at the same time that MQT in the SMMs has to involve spin-lattice
coupling at a relaxation rate equaling that predicted and observed recently for
nuclear spin-mediated quantum relaxation.Comment: 4 pages, 3 figure
Conductance quantization in etched Si/SiGe quantum point contacts
We fabricated strongly confined Schottky-gated quantum point contacts by
etching Si/SiGe heterostructures and observed intriguing conductance
quantization in units of approximately 1e2/h. Non-linear conductance
measurements were performed depleting the quantum point contacts at fixed
mode-energy separation. We report evidences of the formation of a half 1e2/h
plateau, supporting the speculation that adiabatic transmission occurs through
1D modes with complete removal of valley and spin degeneracies.Comment: to appear in Physical Review
Full-Configuration-Interaction Study of the Metal-Insulator Transition in Model Systems: Li<sub>N</sub> Linear Chains (N=2,4,6,8)
International audienceThe precursor of the metal-insulator transition is studied at ab initio level in linear chains of equally spaced lithium atoms. In particular, full configuration interaction calculations (up to 1Ă109 determinants) are performed, in order to take into account the different nature of the wave function at different internuclear distances. Several indicators of the Metal-Insulator transition (minimum of the energy gap, maximum of the localization tensor or of the polarizability) are considered and discussed. It is shown that the different indicators give concordant results, showing a rapid change in the nature of the wave function at an internuclear distance of about 7bohrs
Structure and nuclear quadrupole coupling interaction in hydroxylamines: The rotational spectrum of N,N-diethyl(2H)hydroxylamine
The ground-state rotational spectrum of N,N-diethyl(2H)hydroxylamine (C2H5-NOD-C2H5) was measured by Fourier transform microwave spectroscopy. Six rotational transition lines were assigned to the most stable conformer with the alkyl chain in the trans arrangement and the hydroxyl trans to the bisector of the CNC angle, that is, with the NOD frame in the bc-symmetry plane. Rotational constants are A= 7210.938(2), B= 2018.628(1), and C= 1739.696(1) MHz. These data together with those previously determined for the parent species and 13C and 15N isotopologues, were used to determine a partial r0 structure. The hyperfine structure due to the nuclear quadrupole coupling (NQC) interaction of both 14N and D nuclei was disentangled allowing to obtain the diagonal NQC-constants. On the basis of the determined geometry, the NQC-tensor values in the electric field-gradient principal axis system were determined (ÏxxN= 0.71, ÏyyN= 5.90, ÏzzN= â6.61 MHz; ÏxxD= â0.11, ÏyyD= â0.15, ÏzzD= 0.26 MHz). Comparison with other amines shows that using ammonia as reference, ÏzzN can be estimated with an additive model: +0.4 and +1.7 MHz from hydrogen to alkyl and hydroxyl substitution, respectively. From the analysis of the available data on the 1:1 water complex of N,N-diethylhydroxylamine, a 8% electric field gradient decrease at the nitrogen nucleus due to the formation of the hydrogen bond involving the nitrogen lone pair was found
Polyvinylpyridine-supported palladium nanoparticles: An efficient catalyst for SuzukiâMiyaura coupling reactions
Palladium nanoparticles (Pd NPs) synthesized by the metal vapor synthesis technique were supported on poly(4-vinylpyridine) 2% cross-linked with divinylbenzene (Pd/PVPy). Transmission electron microscopy revealed the presence of small metal nanoparticles (dm = 2.9 nm) highly dispersed on the PVPy. The Pd/PVPy system showed high catalytic efficiency in Suzuki-Miyaura carbonâcarbon coupling reactions of both non-activated and deactivated aromatic iodides and bromides with aryl boronic acids, carried out under an air atmosphere. The high turnover of the catalyst and the ability of the PVPy resin to retain active Pd species are highlighted. By comparing the catalytic performances of Pd/PVPy with those observed by using commercially available Pd-based supported catalysts, the reported system showed higher selectivity and lower Pd leaching
The localization spread and polarizability of rings and periodic chains
The localization spread gives a criterion to decide between metallic and insulating behavior of a material. It is defined as the second moment cumulant of the many-body position operator, divided by the number of electrons. Different operators are used for systems treated with open or periodic boundary conditions. In particular, in the case of periodic systems, we use the complex position definition, which was already used in similar contexts for the treatment of both classical and quantum situations. In this study, we show that the localization spread evaluated on a finite ring system of radius R with open boundary conditions leads, in the large R limit, to the same formula derived by Resta and co-workers [C. Sgiarovello, M. Peressi, and R. Resta, Phys. Rev. B 64, 115202 (2001)] for 1D systems with periodic Born-von KĂĄrmĂĄn boundary conditions. A second formula, alternative to Restaâs, is also given based on the sum-over-state formalism, allowing for an interesting generalization to polarizability and other similar quantities
- âŠ