An analysis of Brazilian sugarcane bagasse ash behavior under thermal gasification.

Background: Ashes from sugarcane were analyzed by X-ray fluorescence, ash content, X-ray diffraction, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). FactSage 6.4 database software was used to estimate viscosity at high temperatures (900 - 1550°C) of them. Results: The results showed that although ashes from sugarcane bagasse contain silica, most of its SiO2 is from soil contamination. Higher and lower silica samples treated at 1350°C for 20 minutes showed that the fine portion of fraction of the ashes melted at this temperature. Conclusions: The melting phase could act as sticking flux for the coarse silica particles on the gasifier bottom wall, which could compromise the gasification process

Corrosion and thermal stability of multi-walled carbon nanotube–graphite–acrylonitrile–butadiene–styrene composite bipolar plates for polymer electrolyte membrane fuel cells

AbstractComposite bipolar plates based on the proper mixing of multi-walled carbon nanotubes (MWNTs), synthetic graphite particles and acrylonitrile–butadiene–styrene (ABS) powder have been produced by hot compression molding. The corrosion properties of the molded plates were assessed through electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves. Through-plane and in-plane electrical conductivities were determined. The relevance of electrochemical oxidation to the electrical conductivity of the composites was assessed by cyclic voltammetry. Thermal stability of the composites was examined by thermogravimetric analysis (TGA). The morphology of fractured surfaces of the plates was observed by scanning electron microscopy. The incorporation of MWNTs increased the in-plane and through-plane electrical conductivity of the ABS–graphite composites. There was, though, a corresponding reduction of the corrosion resistance. The thermal behavior was little affected by the addition of MWNTs