Natural hydrogen seeps or salt lakes: how to make a difference? Grass Patch example, Western Australia

Natural hydrogen exploration is picking up around the world while the geogenic hydrogen system is still a Frontier science. Natural hydrogen seepage can occur in the form of a sub-circular surface feature named by some authors “fairy circles.” Numerous hydrogen seep-alike surface features are visible from the sky in Australia but can be difficult to distinguish from the many salt lakes. In this study, we combined literature review, remote sensing, field and lab measurements (soil gas sampling, X-Ray diffraction, salinity) to uncover a potential hydrogen system and its differences with the salt lakes in the Grass Patch area in Western Australia. The local geology shows a good potential to generate hydrogen. Study of the surface geology and Digital Elevation Model showed that salt lakes are static old features influenced by the soil composition and long-term climatic trend whereas potential hydrogen seeps have recently appeared. This study soil-gas sampling method includes a monitoring procedure compatible with time series measurements via a portable gas analyser, getting rid of artificially produced hydrogen. Low hydrogen values (<30 ppm) have been measured. Those measurements are lower than measurements published along potential hydrogen seeps in Australia. Vegetation indexes are also less constructed than explored fairy circles in Namibia. Salinity and mineralogical results did not indicate any trend with the hydrogen but are coherent with what is found in salt lakes. A microbial system could be the source of the hydrogen but would also be linked to the soil behaviour, climatic parameters, and agricultural practices. This study underlines the need to monitor surface features over few weeks to better understand the evolution of the gas mix seeping above a structure and determine if the periodicity and variability of the leakage can be correlated with bacterial activity or a geogenic hydrogen source

Mariana serpentinite mud volcanism exhumes subducted seamount materials: implications for the origin of life

The subduction of seamounts and ridge features at convergent plate boundaries plays an important role in the deformation of the overriding plate and influences geochemical cycling and associated biological processes. Active serpentinization of forearc mantle and serpentinite mud volcanism on the Mariana forearc (between the trench and active volcanic arc) provides windows on subduction processes. Here, we present (1) the first observation of an extensive exposure of an undeformed Cretaceous seamount currently being subducted at the Mariana Trench inner slope; (2) vertical deformation of the forearc region related to subduction of Pacific Plate seamounts and thickened crust; (3) recovered Ocean Drilling Program and International Ocean Discovery Program cores of serpentinite mudflows that confirm exhumation of various Pacific Plate lithologies, including subducted reef limestone; (4) petrologic, geochemical and paleontological data from the cores that show that Pacific Plate seamount exhumation covers greater spatial and temporal extents; (5) the inference that microbial communities associated with serpentinite mud volcanism may also be exhumed from the subducted plate seafloor and/or seamounts; and (6) the implications for effects of these processes with regard to evolution of life.Copyright 2020 The Authors. Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/ by/4.0/, which permits unrestricted use, provided the original author and source are credited

Circulation épisodique de fluides réactifs le long de failles de l'échelle de travertins à celle de bassins, sur l'exemple du plateau du Colorado (USA)

This work aims to characterise fluid flow along faults in time and space. Multi-disciplinary and multi-scale investigations of a natural analogue have been carried out in the Colorado Plateau area (Utak, USA), from fieldwork to numerical modeling. The study of Quaternary travertine calibrated the near-surface mineralization and their relationship with the faults. Stable Isotope measurements and U/Th datings of travertine veins revealed episodic cycles of CO2-fluid circulation and related calcium carbonate precipitation (travertine). These cycles may be linked with seasonal or climatic cycles (annual and centennial) and also with seismic cycles of millennial duration. Based on the obtained data, escaping CO2 volumes from the fault zone, with time have been calibrated. Chemical bleaching of the outcropping sandstones, linked with fluids paleo-circulation at depth, has been characterized at basin scale. Two main circulation events have been distinguished: a first circulation contemporaneous to maximum burial and a second along-reservoirs and faults circulation that could be linked with later regional tectonic events, contemporaneous of Colorado Plateau rusing. Pulses of different fluids (such as brines, fluids enriched in hydrocarbons or CO2) are linked in time and space with the last circulation.Cette thèse s'attache à caractériser l'évolution dans le temps et l'espace des circulations de fluides le long des failles. Une approche multidisciplinaire et multi-échelle a été mise en place sur un exemple naturel dans la région du plateau du Colorado (Utah): du terrain à la modélisation et de la proche-surface au bassin. L'étude des minéralisations en proche surface et leur lien avec le transfert le long des failles a été effectuée sur des travertins récents. L'analyse isotopique et la datation U/Th des veines de travertins révèle des cycles de circulation de fluides enrichis en CO2 et de précipitation épisodiques de carbonates de calcium (travertin) correspondant à des cycles saisonniers ou climatiques (annuels et centennals) ainsi qu'à des cycles qui s'apparentent à des cycles sismiques de l'ordre du millier d'années. Ces données permettent de calibrer le volume de CO2 qui a fuit par la faille. Des zones de paléo-circulation, témoins de l'activité des failles sur le long-terme, sont observées sous forme de blanchiment chimique ("bleaching") des grès à l'affleurement, et ont été étudiées à l'échelle du bassin. Deux épisodes principaux de circulation de fluides le long des failles ont été distingués : une première circulation durant l'enfouissement maximum puis une seconde circulation le long des réservoirs et des failles, qui est reliée à des phénomènes tectoniques régionaux, compemporains de la remontée du Plateau du Colorado. La dernière circulation s'est découpée en plusieurs pulses avec des circulations de fluides de différente nature (tels que des saumures, des fluides riches en hydrocarbures ou en CO2) au cours du temps et le long des failles

Episodicity of structural flow in an active subduction system, new insights from mud volcano's carbonate veins – Scientific Ocean drilling expedition IODP 366

International audienceThis study's goal is to understand the structural events and episodes of fluid flow recorded in calcium carbonate precipitation sampled in Mariana forearc serpentine mud volcanoes. Those active mounts provide a unique window to deep structural and fluid flow events affecting the subduction channel mélange zone and the subducted Pacific Plate.To build a conceptual model of vein precipitations from the subduction zone to the mud volcanoes edifice, we unravelled the origin, timing, and mechanisms of those precipitations with a multidisciplinary study of calcium carbonate veins, from samples drilled in the flank of Fantangisña Seamount during the International Ocean Discovery Program (IODP) Expedition 366.Structural analysis of the carbonate vein network revealed stages of precipitation and dissolution. The most ancient calcium carbonate minerals underwent high tectonic stress and several degrees of silicification. U-Pb dates ranged from Early Cretaceous to present day, recording potential pre-convergence events and calibrating an episodic building of the Mariana mud volcanoes from the start of the convergence to present day. The UCC-normalized LREE pattern, 87Sr/86Sr ratios ranging from 0.704977 to 0.705798 and δ18O signature 18.7 to 19.8 (‰, V-SMOW) of the veins indicate a mixed origin of the precipitated fluids influenced by the serpentine mud signature.Those mud volcanoes were episodically built from the start of the subduction to present day in function of the forearc tectonic activity. They are complex systems internally composed of a fault network providing multiple circulation pathways that can be successively opened or closed

Evolution of fault permeability during episodic fluid circulation: Evidence for the effects of fluid-rock interactions from travertine studies (Utah-USA)

© 2015 Elsevier B.V.. Faults are known to be important pathways for fluid circulation within the crust. The transfer properties along faults can evolve over time and space. The Little Grand Wash and Salt Wash normal faults, located on the Colorado Plateau, are well known examples of natural CO2 leakage systems from depth to surface. Previous studies dated and established a chronology of CO2-enriched fluid source migration along the fault traces and linked the aragonite veins observed close to Crystal Geyser to CO2-pulses. However, multiple circulation events recorded along a given fault segment deserve to be studied in minute detail in order to unravel the chronology of these events, precipitation processes and associated mechanisms. A combination of structural geology, petrography, U/Th dating, oxygen and carbon isotope analysis were used to study the fault related CO2-enriched paleo-circulations in order to build a conceptual model of CO2-circulation along the faults. This study resulted in the precise descriptions of the features attesting CO2-enriched fluid circulation by a characterization of their relationship and architecture at the outcrop scale. These features are witnesses of a large range of circulation/sealing mechanisms, as well as changes in fluid chemistry and thermodynamic state of the system, providing evidence for (i) the evolution of the fluid through a pathway from depth to the surface and (ii) different cycles of fault opening and sealing. Large circulation events linked with fault opening/sealing are observed and calibrated in nature with millennial circulation and sealing time-lapses. Numerical modelling indicates that such sealing timescale can be explained by the introduction of a fault sealing factor that allows modifying permeability with time and that is calibrated by the natural observations.status: publishe

Evolution of fault permeability during episodic fluid circulation : evidence for the effects of fluid–rock interactions from travertine studies (Utah–USA).

International audienceFaults are known to be important pathways for fluid circulation within the crust. The transfer properties along faults can evolve over time and space. The Little Grand Wash and Salt Wash normal faults, located on the Colorado Plateau, are well known examples of natural CO2 leakage systems from depth to surface. Previous studies dated and established a chronology of CO2-enriched fluid source migration along the fault traces and linked the aragonite veins observed close to Crystal Geyser to CO2-pulses. However, multiple circulation events recorded along a given fault segment deserve to be studied in minute detail in order to unravel the chronology of these events, precipitation processes and associated mechanisms. A combination of structural geology, petrography, U/Th dating, oxygen and carbon isotope analysis were used to study the fault related CO2-enriched paleo-circulations in order to build a conceptual model of CO2-circulation along the faults. This study resulted in the precise descriptions of the features attesting CO2-enriched fluid circulation by a characterization of their relationship and architecture at the outcrop scale. These features are witnesses of a large range of circulation/sealing mechanisms, as well as changes in fluid chemistry and thermodynamic state of the system, providing evidence for (i) the evolution of the fluid through a pathway from depth to the surface and (ii) different cycles of fault opening and sealing. Large circulation events linked with fault opening/sealing are observed and calibrated in nature with millennial circulation and sealing time-lapses. Numerical modelling indicates that such sealing timescale can be explained by the introduction of a fault sealing factor that allows modifying permeability with time and that is calibrated by the natural observations

Fault-Related Fluid Flow Implications for Unconventional Hydrocarbon Development, Beetaloo Sub-Basin (Northern Territory, Australia)

This study assesses potential geological connections between the unconventional petroleum plays in the Beetaloo Sub-basin, regional aquifers in overlying basins, and the near surface water assets in the Beetaloo Sub-basin Northern Territory, Australia. To do so, we built an innovative multi-disciplinary toolbox including multi-physics and multi-depth imaging of the geological formations, as well as the study of potentially active tectonic surface features, which we combined with measurement of the helium content in water sampled in the aquifer systems and a comparative analysis of the surface drainage network and fault lineaments orientation. Structures, as well as potential natural active and paleo-fluid or gas leakage pathways, were imaged with a reprocessing and interpretation of existing and newly acquired Beetaloo seismic reflection 2D profiles and magnetic datasets to determine potential connections and paleo-leakages. North to north-northwest trending strike slip faults, which have been reactivated in recent geological history, are controlling the deposition at the edges of the Beetaloo Sub-basin. There are two spring complexes associated with this system, the Hot Spring Valley at the northern edge of the eastern Beetaloo Sub-basin and the Mataranka Springs 10 km north of the western sub-basin. Significant rectangular stream diversions in the Hot Spring Valley also indicates current or recently active tectonics. This suggests that those deep-rooted fault systems are likely to locally connect the shallow unconfined aquifer with a deeper gas or fluid source component, possibly without connection with the Beetaloo unconventional prospective plays. However, the origin and flux of this deeper source is unknown and needs to be further investigated to assess if deep circulation is happening through the identified stratigraphic connections. Few north-west trending post-Cambrian fault segments have been interpreted in prospective zones for dry gas plays of the Velkerri Formation. The segments located in the northern part of the eastern Beetaloo Sub-basin do not show any evidence of modern leakages. The segments located around Elliot, in the south of the eastern Beetaloo Sub-basin, as well as low-quality seismic imaging of potential faults in the central part of the western sub-basin, could have been recently reactivated. They could act as open pathways of fluid and gas leakage, sourced from the unconventional plays, deeper formations of the Beetaloo Sub-basin or even much deeper origin, excluding the mantle on the basis of low 3He/4He ratios. In those areas, the data are sparse and of poor quality; further field work is necessary to assess whether such pathways are currently active