Utilization of temperature kinetics as a method to predict treatment intensity and corresponding treated wood quality : durability and mechanical properties of thermally modified wood

Wood heat treatment is an attractive alternative to improve decay resistance of wood species with low natural durability. However, this improvement of durability is realized at the expense of the mechanical resistance. Decay resistance and mechanical properties are strongly correlated to thermal degradation of wood cells wall components. Mass loss resulting from this degradation is a good indicator of treatment intensity and final treated wood properties. However, the introduction of a fast and accurate system for measuring this mass loss on an industrial scale is very difficult. Nowadays, many studies are conducted on the determination of control parameters which could be correlated with the treatment conditions and final heat treated wood quality such as decay resistance. The aim of this study is to investigate the relations between kinetics of temperature used during thermal treatment process representing heat treatment intensity, mass losses due to thermal degradation and conferred properties to heat treated wood. It might appear that relative area of treatment temperature curves is a good indicator of treatment intensity. Heat treatment with different treatment conditions (temperature-time) have been performed under vacuum, on four wood species (one hardwood and three softwoods) in order to obtain thermal degradation mass loses of 8, 10 and 12%. For each experiment, relative areas corresponding to temperature kinetics, mass loss, decay resistance and mechanical properties have been determined. Results highlight the statement that the temperature curves’ area constitutes a good indicator in the prediction of needed treatment intensity, to obtain required wood durability and mechanical properties such as bending resistance and Brinell hardness.LERMaB is supported by the French National Research Agency through the Laboratory of Excellence ARBRE (ANR-12- LABXARBRE-01), the authors gratefully acknowledge this ai

Heat treatment of tunisian soft wood species: Effect on the durability, chemical modifications and mechanical properties

Last decades, wood was promoted as building material. Wood heat treatment by mild pyrolysis has been reported to improve biological durability and dimensional stability of the material and constitutesan attractive « non biocidal » alternative to classical preservation treatments. Previous studies have shown that conferred properties strongly depend on the heat treatment intensity. A quality control markerbased on mass loss has been developed. For several years, the increased development of Tunisian wood industry provides a significant capacity of wood production and transformation. Forests in Tunisia consistessentially of coniferous species [Aleppo pine (Pinus halepensis), Radiata pine (Pinus radiata), Maritime pine (Pinus pinaster), Stone pine (Pinus pinea)], characterised by a weak natural durability. Improveddurability and fungal resistance should allow the use of Tunisian species in the wood industry. Import limitation of European species and the use of local species allow the conservation of economic valueadded in the country and improve the economic balance. For this reason, several Tunisian softwood species (Aleppo pine, Radiata pine and Maritime pine) have been heat-treated under vacuum atmosphere at230°C to obtain a thermal degradation with mass losses of approximately 8, 10 and 12%. The oven device allows recording the dynamic Mass Loss (ML) during the treatment and following the thermodegradationkinetic. The chemical composition of the studied wood samples was determined before and after heat treatment. For each wood species and treatment intensity, wood chemical and mechanical analyses wereperformed by measuring O/C ratio, bending and hardness tests. Afterward, tests of decay resistance were performed according to the EN 113 Standard, with different fungal attacks (Poria Placenta, CoriolusVersicolor) at 22°C and 70% of humidity for 16 weeks. Results were related to the mass loss. Furthermore, intensity of thermal degradation was evaluated by TD-GC-MS. Treated and untreated wood sampleswere maintained during 15 minutes at 230 °C under nitrogen in the thermodesorption tube in order to analyse and compare resulting from the wood thermodegradation volatile compounds

Utilization of temperature kinetics as a method to predict treatment intensity and corresponding treated wood quality: Durability and mechanical properties of thermally modified wood

Wood heat treatment is an attractive alternative to improve decay resistance of wood species with low natural durability. However, this improvement of durability is realized at the expense of the mechanical resistance. Decay resistance and mechanical properties are strongly correlated to thermal degradation of wood cells wall components. Mass loss resulting from this degradation is a good indicator of treatment intensity and final treated wood properties. However, the introduction of a fast and accurate system for measuring this mass loss on an industrial scale is very difficult. Nowadays, many studies are conducted on the determination of control parameters which could be correlated with the treatment conditions and final heat treated wood quality such as decay resistance. The aim of this study is to investigate the relations between kinetics of temperature used during thermal treatment process representing heat treatment intensity, mass losses due to thermal degradation and conferred properties to heat treated wood. It might appear that relative area of treatment temperature curves is a good indicator of treatment intensity. Heat treatment with different treatment conditions (temperature-time) have been performed under vacuum, on four wood species (one hardwood and three softwoods) in order to obtain thermal degradation mass loses of 8, 10 and 12%. For each experiment, relative areas corresponding to temperature kinetics, mass loss, decay resistance and mechanical properties have been determined. Results highlight the statement that the temperature curves’ area constitutes a good indicator in the prediction of needed treatment intensity, to obtain required wood durability and mechanical properties such as bending resistance and Brinell hardness

Upper-rim monofunctionalisation in the synthesis of triazole- and disulfide-linked multicalix[4]- and -[6]arenes.

Covalently linked multiple calixarenes are valued in supramolecular chemistry. We report an easy and versatile synthetic route to covalently linked double and triple calix[4]arene and calix[6]arenes by a novel DMF‐controlled selective alkylation of a convenient and readily available upper‐rim dimethylaminomethyl‐substituted tetrahydroxy calix[4]arene and ‐[6]arenes. Synthetic routes to upper‐rim functionalised redox active disulfide‐linked double‐, tetra‐ and peptidohybrid‐calixarenes employing either redox chemistry (CH2SH) or thiolates (CH2S–) are also opened up from the same key starting material