421 research outputs found
Construction and analysis of causally dynamic hybrid bond graphs
Engineering systems are frequently abstracted to models with discontinuous behaviour (such as a switch or contact),
and a hybrid model is one which contains continuous and discontinuous behaviours. Bond graphs are an established
physical modelling method, but there are several methods for constructing switched or âhybridâ bond graphs, developed
for either qualitative âstructuralâ analysis or efficient numerical simulation of engineering systems. This article proposes a
general hybrid bond graph suitable for both. The controlled junction is adopted as an intuitive way of modelling a discontinuity in the model structure. This element gives rise to âdynamic causalityâ that is facilitated by a new bond graph notation. From this model, the junction structure and state equations are derived and compared to those obtained by
existing methods. The proposed model includes all possible modes of operation and can be represented by a single set
of equations. The controlled junctions manifest as Boolean variables in the matrices of coefficients. The method is more
compact and intuitive than existing methods and dispenses with the need to derive various modes of operation from a
given reference representation. Hence, a method has been developed, which can reach common usage and form a platform for further study
FACE TO FACE AGAIN - REPORT FROM THE DOCTORAL SYMPOSIUM IN ENGINEERING EDUCATION RESEARCH AT SEFI 2022
The 6th Doctoral Symposium at SEFI 2022 attracted 20 doctoral students and 17 senior researchers. After two years as an online event during the pandemic, it was organised as a fully in-person event. In preparation, the doctoral students wrote extended abstracts to introduce themselves and their PhD projects, while the seniorsprovided reading recommendations and advice. The intense, full-day program was based on group discussions and interactive plenary sessions. The Doctoral Symposium was concluded by a session in which each participant presented their take-home message. This paper outlines how the Doctoral Symposium was organised and summarizes some of the documentation
Teaching Excellence Programs â Lessons Learned at two Universities
Universities are seeking novel ways to strengthen the collective educational competence of their faculty and promote educational merits. In this paper we describe and compare the experiences of two recently started initiatives for teaching excellence, the Program for Future Leaders for Strategic Educational Development at KTH Royal Institute of Technology (henceforth KTH) and the Teaching Fellowship Programme at the University of Twente. Both programs have recently completed one complete round of implementation. The programmes are similar in that the participants work on a project of their own for an extended time, while also being part of a community with regular meetings and supported by coaches. The main differences are the programme duration, number of participants, and whether the projects are in a specific theme or wholly formulated by the participants. In this study, both programs are evaluated using similar themes. We analyse this data, and reflect on the context, conditions and design of the programs and our lessons learned from these first experiences.</p
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Flash Joule heating for ductilization of metallic glasses
Metallic glasses (MGs) inherit their amorphous structure from the liquid state, which predetermines their ability to withstand high loads approaching the theoretical limit. However, the absence of slip systems makes them very sensitive to the type of loading and extremely brittle in tension. The latter can be improved by precipitation of ductile crystals, which suppress a catastrophic propagation of shear bands in a glassy matrix. Here we report a novel approach to obtain MG-matrix composites with tensile ductility by flash Joule heating applied to Cu47.5Zr47.5Al5 (at.%) metallic glass. This homogeneous, volumetric and controllable rapid heat treatment allows achieving uniformly distributed metastable B2 CuZr crystals in the glassy matrix. It results in a significant tensile strain of 6.8±0.5%. Moreover, optimized adjustment of the heat-treatment conditions enables tuning of microstructure to achieve desired mechanical properties
Magnetic properties of (FeCo)B alloys and the effect of doping by 5 elements
We have explored, computationally and experimentally, the magnetic properties
of \fecob{} alloys. Calculations provide a good agreement with experiment in
terms of the saturation magnetization and the magnetocrystalline anisotropy
energy with some difficulty in describing CoB, for which it is found that
both full potential effects and electron correlations treated within dynamical
mean field theory are of importance for a correct description. The material
exhibits a uniaxial magnetic anisotropy for a range of cobalt concentrations
between and . A simple model for the temperature dependence of
magnetic anisotropy suggests that the complicated non-monotonous temperature
behaviour is mainly due to variations in the band structure as the exchange
splitting is reduced by temperature. Using density functional theory based
calculations we have explored the effect of substitutional doping the
transition metal sublattice by the whole range of 5 transition metals and
found that doping by Re or W elements should significantly enhance the
magnetocrystalline anisotropy energy. Experimentally, W doping did not succeed
in enhancing the magnetic anisotropy due to formation of other phases. On the
other hand, doping by Ir and Re was successful and resulted in magnetic
anisotropies that are in agreement with theoretical predictions. In particular,
doping by 2.5~at.\% of Re on the Fe/Co site shows a magnetocrystalline
anisotropy energy which is increased by 50\% compared to its parent
(FeCo)B compound, making this system interesting, for
example, in the context of permanent magnet replacement materials or in other
areas where a large magnetic anisotropy is of importance.Comment: 15 pages 17 figure
Rechargeable Batteries of the FutureâThe State of the Art from a BATTERY 2030+ Perspective
The development of new batteries has historically been achieved through discovery and development cycles based on the intuition of the researcher, followed by experimental trial and errorâoften helped along by serendipitous breakthroughs. Meanwhile, it is evident that new strategies are needed to master the ever-growing complexity in the development of battery systems, and to fast-track the transfer of findings from the laboratory into commercially viable products. This review gives an overview over the future needs and the current state-of-the art of five research pillars of the European Large-Scale Research Initiative BATTERY 2030+, namely 1) Battery Interface Genome in combination with a Materials Acceleration Platform (BIG-MAP), progress toward the development of 2) self-healing battery materials, and methods for operando, 3) sensing to monitor battery health. These subjects are complemented by an overview over current and up-coming strategies to optimize 4) manufacturability of batteries and efforts toward development of a circular battery economy through implementation of 5) recyclability aspects in the design of the battery
Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries
Undesired electrode-electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.ope
Understanding Battery Interfaces by Combined Characterization and Simulation Approaches: Challenges and Perspectives
Driven by the continuous search for improving performances, understanding the phenomena at the electrode/electrolyte interfaces has become an overriding factor for the success of sustainable and efficient battery technologies for mobile and stationary applications. Toward this goal, rapid advances have been made regarding simulations/modeling techniques and characterization approaches, including high-throughput electrochemical measurements coupled with spectroscopies. Focusing on Li-ion batteries, current developments are analyzed in the field as well as future challenges in order to gain a full description of interfacial processes across multiple length/timescales; from charge transfer to migration/diffusion properties and interphases formation, up to and including their stability over the entire battery lifetime. For such complex and interrelated phenomena, developing a unified workflow intimately combining the ensemble of these techniques will be critical to unlocking their full investigative potential. For this paradigm shift in battery design to become reality, it necessitates the implementation of research standards and protocols, underlining the importance of a concerted approach across the community. With this in mind, major collaborative initiatives gathering complementary strengths and skills will be fundamental if societal and environmental imperatives in this domain are to be met
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